Film forming method and film forming apparatus
There is provided a film forming method including: adsorbing fluorine onto a substrate on which a region in which a nitride film is exposed and a region in which an oxide film is exposed are provided adjacent to each other by supplying a fluorine-containing gas to the substrate, and forming a stepped surface on a side surface of the oxide film by selectively etching the nitride film, among the nitride film and the oxide film, so as to cause a surface of the nitride film to be more deeply recessed than a surface of the oxide film; and after the adsorbing the fluorine onto the substrate and forming the stepped surface, selectively forming a semiconductor film on the nitride film, among the nitride film and the oxide film, by supplying a raw material gas including a semiconductor material to the substrate.
1. A film forming method comprising:
adsorbing fluorine onto a substrate on which a region in which a nitride film is exposed and a region in which an oxide film is exposed are provided adjacent to each other by supplying a fluorine-containing gas to the substrate, and forming a stepped surface on a side surface of the oxide film by selectively etching the nitride film, so as to cause a surface of the nitride film to be more deeply recessed than a surface of the oxide film; and
after the adsorbing the fluorine onto the substrate and forming the stepped surface, selectively forming a semiconductor film on the nitride film, by supplying a raw material gas including a semiconductor material to the substrate.
2. The film forming method of claim 1 , wherein the adsorbing the fluorine onto the substrate and forming the stepped surface is performed at a temperature lower than a temperature during the selectively forming the semiconductor film on the nitride film.
3. The film forming method of claim 1 , wherein the fluorine-containing gas is a F 2 gas or a HF gas used together with a NH 3 gas.
4. The film forming method of claim 1 , wherein the raw material gas includes at least one of Si and Ge.
5. The film forming method of claim 1 , wherein the nitride film is a silicon nitride film, and the oxide film is a silicon oxide film.
6. The film forming method of claim 1 , further comprising: before the adsorbing the fluorine onto the substrate and forming the stepped surface, removing a natural oxide film of the nitride film so as to expose the nitride film.
7. The film forming method of claim 6 , wherein a NH 3 gas and a HF gas are used to remove the natural oxide film.
8. The film forming method of claim 1 , further comprising: after the selectively forming the semiconductor film on the nitride film, removing the semiconductor material formed on the oxide film by supplying a halogen-containing gas to the substrate.
9. The film forming method of claim 8 , wherein the halogen-containing gas does not contain the fluorine.
10. The film forming method of claim 8 , further comprising: repeating the selectively forming the semiconductor film on the nitride film and the removing the semiconductor material formed on the oxide film.