Granted Patent B2

US 12,269,202 · App. 17/041,487 · Granted Apr 8, 2025

Inventors: Jan-Bernd Kues (Muenster, DE); Susanne Piontek (Muenster, DE); Joerg Exner (Muenster, DE); Joerg Lenz (Muenster, DE); Birgit Kleine-Bley (Muenster, DE); Wilfried Schipper (Dortmund, DE); Robert von der AA (Borsdorf/OT Panitsch, DE); Frank Bergmann (Halle, DE); Michael Lorenz (Halle, DE); Sven Olle Krabbenborg (Leipzig, DE); Joerg Duennewald (Muenster, DE)

Assignee: BASF COATINGS GMBH

B29C59/046B29C59/022B44B5/026B44C1/24C09D4/06C09D133/08C09D133/12C09J7/29B29C2059/023B29K2667/003B29L2007/001B29L2031/7562C09J2301/122

Abstract

Claims (59)

1. A method for transferring an embossed structure to at least a part of a surface of a coating (B2), using a composite (F1B1) composed of a substrate (F1) and of an at least partially embossed and at least partially cured coating (B1), where the coating (B2) and the coating (B1) of the composite (F1B1) have embossed structures which are mirror images of one another, the method comprising:

(1) applying a coating composition (B2a) to at least a part of an at least partially embossed surface of a composite (B1F1) comprising the substrate (F1), and the at least partially embossed and at least partially cured coating (B1), to give a composite (B2aB1F1), and

(2) (2) at least partially curing the applied coating composition (B2a) to give a composite (B2B1F1) comprising the substrate (F1), the at least partially embossed and at least partially cured coating (B1), and the at least partially cured coating (B2), and

(3) removing the coating (B2) from the composite (B2B1F1) to restore the composite (B1F1) used in step (1), where the coating (B2), on its surface previously facing the coating (B1) within the composite (B2B1F1), has a negative image of the at least partially embossed surface of the coating (B1) of the composite (B1F1) used in step (1) and restored in that step,

wherein:

the coating (B2) in step (3) is obtained as a free film by peeling from the composite (B2B1F1) with additional restoration of the composite (B1F1), or

the coating (B2) is obtained in step (3) in three stages in a form of a composite (B2KF2), the method further comprising:

(3a) applying an adhesive (K) to at least a part of a surface of the composite (B2B1F1), on its side having the coating (B2), to give a composite (KB2B1F1),

(3b) applying a substrate (F2) to the composite (KB2B1F1) obtained after stage (3a), to at least a part of its surface having the adhesive (K), or vice-versa, to give a composite (F2KB2B1F1), and

(3c) peeling the composite (B1F1) from the composite (F2KB2B1F1) to give a composite (F2KB2), where the coating (B2) of this composite has on its surface at least partially the negative image of the at least partially embossed surface of the coating (B1) of the composite (B1F1),

where the coating composition (B1a) used for producing the coating (B1) of the composite (B1F1) used in step (1) and restored in step (3) is a radiation-curable coating composition,

wherein the radiation-curable coating composition (B1a) comprises

at least one component (a) in an amount in a range from 40 to 95 wt %,

at least one additive as component (b) in an amount in a range from 0.01 to 5 wt %,

at least one photoinitiator as component (c) in an amount in a range from 0.01 to 15 wt %, and

at least one component (d), comprising at least one carbon double bond, in an amount in a range from 0 to 45 wt %,

where (i) the components (a), (b), (c), and (d) are each different from one another, (ii) the stated amounts of the components (a), (b), (c), and (d) are each based on a total weight of the coating composition (B1a), and (iii) the amounts of all components present in the coating composition (B1a) add up to 100 wt %,

and where component (a) comprises at least three structural units, each different from one another or at least partially identical, of formula (I)

in which

radicals R 1 in each case independently of one another are a C 2 -C 8 alkylene group, radicals R 2 in each case independently of one another are H or methyl, and

m each independently of one another are an integral parameter in a range from 1 to 15, but with proviso that m is at least 2 in at least one of the structural units of the formula (I) within the component (a).

2. The method as claimed in claim 1 , wherein the coating (B2) is obtained as a free film by peeling from the composite (F2KB2) obtained after stage (3c).

3. The method as claimed in claim 1 , wherein the at least partially embossed and at least partially cured coating (B1) of the composite (F1B1) used in step (1) has embossments in a micrometer and/or nanometer range.

4. The method as claimed in claim 1 , wherein the composite (B1F1) used in step (1) is a composite composed of a film web (F1) and of a coating (B1) which is applied thereto and is at least partially embossed and at least partially cured.

5. The method as claimed in claim 1 , wherein the composite (B1F1) used in step (1) and restored after step (3) is reusable and can be used repeatedly for transferring at least one embossed structure.

6. The method as claimed in claim 1 , wherein the composite (F1B1) which is used in step (1) and which is composed of the substrate (F1) and of an at least partially embossed and at least partially cured coating (B1) is at least obtainable by

(4) applying the radiation-curable coating composition (B1a) to at least a part of a surface of the substrate (F1),

(5) at least partially embossing the radiation-curable coating composition (B1a), applied at least partially to the surface of the substrate (F1), by means of at least one embossing tool (P1) having at least one embossing die (p1),

(6) at least partially curing the radiation-curable coating composition (B1a), applied to at least a part of the surface of the substrate (F1) and at least partially embossed, by radiation curing, to give a composite (F1B1) composed of substrate (F1) and of at least partially embossed and at least partially cured coating (B1), where throughout a duration of the at least partial curing the coating composition (B1a) is in contact with the at least one embossing die (p1) of the at least one embossing tool (P1), and

(7) removing the composite (F1B1) from the embossing tool (P1).

7. The method as claimed in claim 1 , wherein a solids content of the coating composition (B1a) is >90 wt %, based on a total weight of the coating composition (B1a).

8. The method as claimed in claim 1 , wherein m is at least 2 in each of the at least three structural units of the formula (I) of component (a).

9. The method as claimed in claim 1 , wherein a fraction of ether segments —[O—R 1 ] m — present in the structural units of formula (I) in the component (a) is at least 35 wt %, based on a total weight of component (a).

10. A method for producing a coating (B2), embossed at least partially on one of its surfaces, in the form of a free film, using a composite (B2B1F1) comprising:

a substrate (F1),

an at least partially embossed and at least partially cured coating (B1), and

an at least partially cured coating (B2) applied to (B1),

where the coating (B1) is producible by at least partially curing a coating composition (B1a), applied to at least a part of a surface of the substrate (F1) and at least partially embossed, by radiation curing, where the coating composition (B1a) is a radiation-curable coating composition,

wherein the coating composition (B1a) comprises:

at least one component (a) in an amount in a range from 40 to 95 wt %,

at least one additive as component (b) in an amount in a range from 0.01 to 5 wt %,

at least one photoinitiator as component (c) in an amount in a range from 0.01 to 15 wt %, and

at least one component (d), comprising at least one carbon double bond, in an amount in a range from 0 to 45 wt %,

where (i) the components (a), (b), (c), and (d) are each different from one another, (ii) the stated amounts of the components (a), (b), (c), and (d) are each based on a total weight of the coating composition (B1a), and (iii) the amounts of all components present in the coating composition (B1a) add up to 100 wt %,

and where component (a) comprises at least three structural units, each different from one another or at least partially identical, of formula (I)

wherein radicals R 1 in each case independently of one another are a C 2 -C 8 alkylene group, radicals R 2 in each case independently of one another are H or methyl, and m each independently of one another are an integral parameter in a range from 1 to 15, but with proviso that m is at least 2 in at least one of the structural units of the formula (I) within the component (a).

11. A method for producing a composite (B2KF2) comprising a substrate (F2), at least one adhesive (K), and the coating (B2), using a composite (B2B1F1) comprising:

a substrate (F1),

an at least partially embossed and at least partially cured coating (B1), and

an at least partially cured coating (B2) applied to (B1),

where the coating (B1) is producible by at least partially curing a coating composition (B1a), applied to at least a part of a surface of the substrate (F1) and at least partially embossed, by radiation curing, where the coating composition (B1a) is a radiation-curable coating composition,

wherein the coating composition (B1a) comprises:

at least one component (a) in an amount in a range from 40 to 95 wt %,

at least one additive as component (b) in an amount in a range from 0.01 to 5 wt %,

at least one photoinitiator as component (c) in an amount in a range from 0.01 to 15 wt %, and

at least one component (d), comprising at least one carbon double bond, in an amount in a range from 0 to 45 wt %,

where (i) the components (a), (b), (c), and (d) are each different from one another, (ii) the stated amounts of the components (a), (b), (c) and (d) are each based on a total weight of the coating composition (B1a), and (iii) the amounts of all components present in the coating composition (B1a) add up to 100 wt %,

and where component (a) comprises at least three structural units, each different f rom one another or at least partially identical, of formula (I)

wherein radicals R 1 in each case independently of one another are a C 2 -C 8 alkylene group, radicals R 2 in each case independently of one another are H or methyl, and m each independently of one another are an integral parameter in a range from 1 to 15, but with proviso that m is at least 2 in at least one of the structural units of the formula (I) within the component (a).

Assignments (5)

Priority Claims (1)

Continuity (1)

References Cited (17)