Polyimide-polyarylene polymers
Disclosed is a bis-imide compound comprising two or more aryl moieties substituted with ethynyl moieties and the two or more aryl moieties each having one or more polar substituents. Further disclosed is a polymer composition comprising a copolymer polymerized from a monomer mixture of (a) one or more first monomers comprising a bis-imide compound comprising two or more aryl moieties substituted with ethynyl moieties and the two or more aryl moieties each having one or more polar substituents; and (b) one or more second monomers comprising two or more cyclopentadienone moieties. The polymer compositions exhibit favorable properties for use in electronics and displays applications.
1. A polymer composition comprising a copolymer polymerized from a monomer mixture of (a) one or more first monomers comprising a bis-imide compound comprising two or more aryl moieties substituted with ethynyl moieties and the two or more aryl moieties each having one or more polar substituents; and (b) one or more second monomers comprising two or more cyclopentadienone moieties;
wherein the one or more first monomers is a compound having Formula 1a,
wherein:
L 1 is a divalent aromatic linking group substituted with (Z 2 ) v ;
Z 1 and Z 2 are the same or different at each occurrence and are polar groups;
x1 is 0; and
y is 1.
2. The polymer composition of claim 1 , wherein the one or more second monomers has Formula 3,
wherein:
R 7 is the same or different at each occurrence and is a substituted or unsubstituted C 6-20 aryl,
and:
Ar 2 is a substituted or unsubstituted C 6-20 aryl group.
3. The polymer composition of claim 2 , wherein Ar 2 has Formula 4,
wherein:
q is 1;
r is 1;
Ar 3 is Formula 5,
wherein:
R 8 is the same or different at each occurrence and is selected from the group consisting of halogen, substituted or unsubstituted C 1-6 alkyl, aryl, and aryloxy;
c is 0; and
Z is O.
4. The polymer composition of claim 1 , wherein the one or more second monomers is
5. The polymer composition of claim 1 , wherein the copolymer is
wherein 15<n<50.