Method for forming diamond having a desirable color by chemical vapor deposition comprising growing a doped diamond layer on a single crystal substrate
A diamond includes a first dopant configured to cause the diamond to have a first color. The diamond also includes a second dopant configured to cause the diamond to have a second color. Furthermore, the diamond includes a third dopant configured to cause the diamond to have a third color. The combined color of the first, second, and third dopants in the diamond mitigate the detrimental effect of the first and second dopant on the color of the diamond.
1 . A method of forming a CVD diamond, the method comprising:
providing a single-crystal substrate; and
growing a first doped diamond layer directly or indirectly on the substrate, the first doped diamond layer including a first dopant, a second dopant, and a third dopant, each of the dopants being introduced into the CVD growth environment at non-trivial prescribed concentrations to produce a desired color that is closer to colorless on a diamond color scale relative to a diamond with any two of the three dopants, each of the three dopants being different from one another and being selected from the list of: boron, silicon, nitrogen, sulfur, phosphorous, chromium arsenic, nickel, germanium, cobalt, and aluminum.
2 . The method of forming a CVD diamond of claim 1 , wherein one of the first dopant, the second dopant, and the third dopant is a primary dopant, and another one of the first dopant, the second dopant, and the third dopant is a secondary dopant.
3 . The method of forming a CVD diamond of claim 2 , further comprising: adjusting the prescribed concentration of the first dopant, the second dopant, and/or the third dopant.
4 . The method of forming a CVD diamond of claim 3 , further comprising:
growing a second doped diamond layer directly or indirectly on the first diamond layer after adjusting the prescribed concentration.
5 . The method of forming a CVD diamond of claim 4 , wherein the second doped diamond layer has a different color from the first doped diamond layer.
6 . The method of forming a CVD diamond of claim 3 , wherein adjusting the prescribed concentration of the first dopant, the second dopant, and/or the third dopant defines a new primary dopant.
7 . The method of forming a CVD diamond of claim 4 , further comprising:
adjusting the prescribed concentration of the first dopant, the second dopant, and/or the third dopant; and
growing a third doped diamond layer directly or indirectly on the second diamond layer after adjusting the prescribed concentration.
8 . A method of forming a CVD diamond, the method comprising:
providing a single-crystal substrate;
providing a CVD growth environment in which there exists a gas comprising nitrogen;
adding boron and silicon into the CVD diamond growth environment, wherein the boron and the silicon are added in a controlled manner into the CVD diamond growth environment to reduce a detrimental effect on color of the single crystal CVD diamond.
9 . The method of forming a CVD diamond of claim 8 , wherein the boron is removed from the CVD growth environment before the silicon is added.
10 . The method of forming a CVD diamond of claim 8 , further comprising growing a first diamond layer;
reducing a concentration of the boron in the CVD growth environment prior to growing a second diamond layer; increasing a concentration of the silicon in the growth environment prior to growing the second diamond layer.
11 . The method of forming a CVD diamond of claim 8 , wherein the silicon is removed from the CVD growth environment before the boron is added.
12 . The method of forming a CVD diamond of claim 8 , wherein a concentration of the silicon in the CVD growth environment is reduced as a concentration of the boron is increased.
13 . The method of forming a CVD diamond of claim 8 , wherein the silicon and the boron are simultaneously present in the CVD growth environment.
14 . The method of forming a CVD diamond of claim 8 , further comprising growing alternating layers of primarily boron-doped diamond and primarily silicon-doped diamond.
15 . The method of forming a CVD diamond of claim 14 , wherein the primarily boron-doped diamond layer and the primarily silicon-doped diamond layer both include a secondary nitrogen dopant.
16 . A method of forming a CVD diamond, the method comprising:
providing a single-crystal substrate; and
growing, by chemical vapor deposition, a doped diamond directly or indirectly on the single-crystal substrate, the doped diamond including a first dopant, a second dopant, and a third dopant, each of the dopants selected from the list of: boron, silicon, nitrogen, sulfur, chromium, phosphorous, arsenic, nickel, germanium, cobalt, and aluminum, the three dopants causing a color of the diamond to appear closer to colorless on a diamond color scale relative to a diamond with two of the three dopants.
17 . The method of claim 16 , wherein the doped diamond comprises a plurality of layers, each layer having at least one of the first dopant, the second dopant, and the third dopant.
18 . The method of claim 16 , wherein the doped diamond comprises a plurality of layers, each of the plurality of layers including a different primary dopant.
19 . The method of claim 16 , wherein the doped diamond comprises a plurality of layers, each of the plurality of layers including a different concentration of dopants.
20 . The method of claim 16 , wherein the dopants are added in a controlled manner into the CVD diamond growth environment.