Photocurable ink composition for ink jet recording and ink jet recording method
The present invention provides a photocurable ink composition for ink jet recording with excellent curability. The photocurable ink composition for ink jet recording includes polymerizable compounds, a photopolymerization initiator, and a colorant, wherein the polymerizable compounds include a vinyl ether group-containing (meth)acrylate represented by general formula (I): CH 2 ═CR 1 —COOR 2 —O—CH═CH—R 3 (I) (wherein R 1 is a hydrogen atom or a methyl group, R 2 is a divalent organic residue having 2 to 20 carbon atoms, and R 3 is a hydrogen atom or a monovalent organic residue having 1 to 11 carbon atoms) and phenoxyethyl (meth)acrylate.
1. A photocurable ink composition for ink jet recording, comprising:
polymerizable compounds;
a photopolymerization initiator; and
a colorant,
wherein the polymerizable compounds include a vinyl ether group-containing (meth)acrylate represented by general formula (I):
CH 2 ═CR 1 —COOR 2 —O—CH═CH—R 3 (I)
(wherein R 1 is a hydrogen atom or a methyl group, R 2 is a divalent organic residue having 2 to 20 carbon atoms, and R 3 is a hydrogen atom or a monovalent organic residue having 1 to 11 carbon atoms) and phenoxyethyl (meth)acrylate, polyfunctional (meth)acrylate,
wherein the content of the phenoxyethyl (meth)acrylate is 9 to 60% by mass relative to the total mass of the ink composition,
wherein the photopolymerization initiator contains 15% by mass or less of an acylphosphine oxide compound relative to the total mass of the ink composition.
2. The photocurable ink composition for ink jet recording according to claim 1 , wherein the photopolymerization initiator contains 7% by mass or more of an acylphosphine oxide compound relative to the total mass of the ink composition.
3. The photocurable ink composition for ink jet recording according to claim 1 , wherein the vinyl ether group-containing (meth)acrylate is 2-(vinyloxyethoxy)ethyl (meth)acrylate.
4. The photocurable ink composition for ink jet recording according to claim 1 , wherein the content of the vinyl ether group-containing (meth)acrylate is 10 to 60% by mass relative to the total mass of the ink composition.
5. The photocurable ink composition for ink jet recording according to claim 1 , wherein the ink composition is cured by irradiation with ultraviolet light with an emission peak wavelength in a range of 350 to 420 nm and an irradiation energy of 300 mJ/cm 2 or less.
6. The photocurable ink composition for ink jet recording according to claim 1 , wherein the content of the vinyl ether group-containing (meth)acrylate represented by general formula (I) is no more than 40% by mass relative to the total mass of the ink composition.