Donor-acceptor interfaces for excitonic semiconductors
Provided is a thin film semiconductor device that exploits excitonic characteristics of various organic semiconductor materials. The device may include an anode ( 120 ), a cathode ( 170 ), and a donor-acceptor heterojunction ( 150 ) disposed between the anode and the cathode. The donor-acceptor heterojunction may further include an acceptor material ( 404 ) having a highest occupied molecular orbital (HOMO) and a lowest unoccupied molecular orbital (LUMO), and a donor material ( 402 ) comprising a hybrid organic-inorganic metal halide perovskite semiconductor. Other embodiments are disclosed and additional embodiments are also possible.
1. An organic semiconductor device, comprising:
an anode;
a cathode; and
a donor-acceptor heterojunction disposed between the anode and the cathode,
wherein the donor-acceptor heterojunction comprises:
an acceptor material having a highest occupied molecular orbital (HOMO) and a lowest unoccupied molecular orbital (LUMO); and
a donor material comprising an excitonic low-dimensional hybrid organic-inorganic metal halide perovskite semiconductor.
2. The organic semiconductor device of claim 1 , wherein the excitonic low-dimensional hybrid organic-inorganic metal halide perovskite semiconductor is a two-dimensional (2D) perovskite.
3. The organic semiconductor device of claim 2 , wherein the 2D perovskite is represented by a general formula B 2 (SMX 3 ) n-1 MX 4 , wherein:
B and S represent bulky and small organic cations, respectively;
M represents divalent metal cations;
X represents halide anions; and
n represents a number of [MX 4 ] 2− monolayer sheets sandwiched between bulky organic cation layers.
4. The organic semiconductor device of claim 3 , wherein n is equal to or less than 5.
5. The organic semiconductor device of claim 3 , wherein the 2D perovskite is at least one of butylammonium lead iodide (BA 2 PbI 4 ), butylammonium lead bromide (BA 2 PbBr 4 ), and ethylammonium lead bromide (EA 2 PbBr 4 ).
6. The organic semiconductor device of claim 2 , wherein the 2D perovskite is a Ruddlesden-Popper phase or a Dion-Jacobson phase.
7. The organic semiconductor device of claim 6 , wherein the Dion-Jacobson phase is butyldiammonium lead iodide (BDAPbI 4 ).
8. The organic semiconductor device of claim 1 , wherein the donor-acceptor heterojunction is a planar heterojunction or a bulk heterojunction.
9. The organic semiconductor device of claim 8 , wherein when the donor-acceptor heterojunction is the bulk heterojunction, a bulky organic cation in the hybrid organic-inorganic metal halide perovskite semiconductor is phenethylammonium (PEA).
10. The organic semiconductor device of claim 1 , wherein an excitonic binding energy of the donor material is greater than a thermal energy of the donor material represented by kT, wherein k represents the Boltzmann constant and T represents temperature.
11. The organic semiconductor device of claim 1 , wherein a difference between the LUMO of the acceptor material and a LUMO of the donor material is less than 2.1 eV.
12. The organic semiconductor device of claim 1 , wherein the hybrid organic-inorganic metal halide perovskite semiconductor is a one-dimensional (1D) perovskite or a zero-dimensional (0D) perovskite.
13. An organic excitonic optoelectronic device comprising a donor-acceptor heterojunction, wherein the donor-acceptor heterojunction further comprises:
an acceptor material having a highest occupied molecular orbital (HOMO) and a lowest unoccupied molecular orbital (LUMO); and
a donor material comprising a two-dimensional (2D) perovskite represented by a general formula B 2 (SMX 3 ) n-1 MX 4 , wherein:
B and S represent bulky and small organic cations, respectively;
M represents divalent metal cations;
X represents halide anions; and
n represents a number of [MX 4 ] 2− monolayer sheets sandwiched between bulky organic cation layers.
14. The organic excitonic optoelectronic device of claim 13 , wherein n is equal to or less than 5.
15. The organic excitonic optoelectronic device of claim 13 , wherein the 2D perovskite is a Ruddlesden-Popper phase or a Dion-Jacobson phase.
16. The organic excitonic optoelectronic device of claim 13 , wherein an excitonic binding energy of the donor material is greater than a thermal energy of the donor material represented by kT, wherein k represents the Boltzmann constant and T represents temperature.
17. The organic excitonic optoelectronic device of claim 13 , wherein the donor-acceptor heterojunction is a planar heterojunction or a bulk heterojunction.