Catalyst for olefin polymerization and method for producing polar group—containing olefin polymer
The present invention provides: a catalyst which has high activity and enables the production of an olefin polymer that has a polar group; and a method for producing the polymer. A catalyst for olefin polymerization, which contains a metal complex represented by general formula (C1); and a method for producing an ethylene (co)polymer, wherein (1) ethylene is polymerized, (2) ethylene and an olefin having a polar group represented by general formula (1) are copolymerized, or (3) ethylene, an olefin having a polar group represented by general formula (1) and another monomer are copolymerized, with use of the above-described catalyst. (In the formulae, the symbols are as defined in the description; and at least one of R 6 and R 7 represents a 9-fluorenyl analogous group represented by general formula (2).
1. A catalyst for olefin polymerization comprising a metal complex represented by formula (C1)
wherein, in the formula, M represents an element of Group 10 of the Periodic Table; X represents a phosphorus atom (P) or an arsenic atom (As); R 5 represents a substituent selected from the group consisting of a hydrogen atom, the group consisting of a halogen atom, a hydrocarbon group having 1 to 30 carbon atoms, a hydrocarbon group having 1 to 30 carbon atoms substituted with a halogen atom, a hydrocarbon group having 2 to 30 carbon atoms substituted with an alkoxy group having 1 to 10 carbon atoms, a hydrocarbon group having 7 to 30 carbon atoms substituted with an aryloxy group having 6 to 20 carbon atoms, a hydrocarbon group having 3 to 30 carbon atoms substituted with an amido group having 2 to 10 carbon atoms, an alkoxy group having 1 to 30 carbon atoms, an aryloxy group having 6 to 30 carbon atoms, and an acyloxy group having 2 to 10 carbon atoms; R 6 and R 7 each independently represent an alkoxy group, an aryloxy group, a silyl group, an amino group, or a hydrocarbon group having 1 to 180 carbon atoms which may be substituted with one or more groups selected from a halogen atom, an alkoxy group, and an aryloxy group, and at least one of R 6 and R 7 represents a 9-fluorenyl analogous group represented by formula (2)
wherein, in the formula, R 12 , R 13 , R 14 , R 15 , R 16 , R 17 , R 18 and R 19 each independently represent a substituent selected from the group consisting of a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 10 carbon atoms, a hydrocarbon group having 1 to 10 carbon atoms substituted with a halogen atom, a hydrocarbon group having 2 to 20 carbon atoms substituted with an alkoxy group having 1 to 10 carbon atoms, a hydrocarbon group having 7 to 20 carbon atoms substituted with an aryloxy group having 6 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an aryloxy group having 6 to 10 carbon atoms, and an acyloxy group having 2 to 10 carbon atoms; and R 12 , R 13 , R 14 , R 15 , R 16 , R 17 , R 18 and R 19 may be bonded to each other to form a ring structure; wherein, in formula (2), a bond between a carbon atom and X in formula (C1) is depicted; R 8 , R 9 , R 10 and R 11 each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, an aryloxy group having 6 to 20 carbon atoms, a silyl group substituted with a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms, or a hydrocarbon group having 1 to 20 carbon atoms substituted with a halogen atom; L represents an electron-donating ligand; and q is 0, ½, 1 or 2.
2. The catalyst for olefin polymerization according to claim 1 , wherein the 9-fluorenyl analogous group represented by formula (2) is a 9-fluorenyl group or a 2,7-di-t-butyl-9-fluorenyl group.
3. The catalyst for olefin polymerization according to claim 1 , wherein all of R 8 , R 9 , R 10 and R 11 in formula (C1) are a hydrogen atom.
4. A method for producing polyethylene; or a copolymer of ethylene and an olefin having a polar group represented by formula (1)
wherein, in the formula, R 1 represents a substituent selected from the group consisting of a hydroxy group, an alkoxy group having 1 to 10 carbon atoms, an aryloxy group having 6 to 20 carbon atoms, an acyl group having 2 to 10 carbon atoms, an ester group (oxycarbonyl group; R—O—(C═O)—, R is an organic group) having 2 to 10 carbon atoms, an acyloxy group having 2 to 10 carbon atoms, an amino group, a substituted amino group having 1 to 12 carbon atoms, a substituted amido group having 2 to 12 carbon atoms, a substituted pyridyl group having 5 to 10 carbon atoms, a substituted pyrrolidyl group having 4 to 10 carbon atoms, a substituted piperidyl group having 5 to 10 carbon atoms, a substituted hydrofuryl group having 4 to 10 carbon atoms, a substituted imidazolyl group having 4 to 10 carbon atoms, a mercapto group, an alkylthio group having 1 to 10 carbon atoms, an arylthio group having 6 to 10 carbon atoms, an epoxy group, and a halogen atom; and n is 0, or an integer selected from 1 to 6; or a copolymer of ethylene, the olefin having a polar group represented by formula (1) and an additional monomer, the method comprising, by using a metal catalyst represented by formula (C1)
wherein symbols in the formula have the same meanings as described in claim 1 , as a polymerization catalyst, polymerizing ethylene alone; or copolymerizing ethylene and the olefin having a polar group represented by formula (1); or copolymerizing ethylene, the olefin having a polar group represented by formula (1) and the additional monomer.
5. The method for producing a polymer according to claim 4 , wherein n in formula (1) is 0.
6. The method for producing a polymer according to claim 4 , wherein n in formula (1) is 1.
7. The method for producing a polymer according to claim 4 , wherein the 9-fluorenyl analogous group represented by formula (2) is a 9-fluorenyl group or a 2,7-di-t-butyl-9-fluorenyl group.
8. The method for producing a polymer according to claim 4 , wherein all of R 8 , R 9 , R 10 and R 11 in formula (C1) are a hydrogen atom.