IP Library › Granted Patent US 12,202,959
Granted Patent B2
US 12,202,959 · App. 17/431,651 · Granted Jan 21, 2025

Composition comprising heterophasic propylene copolymer

Inventors: Marc Herklots (Geleen, NL); Daniel Bande (Geleen, NL); Ginger De La Croix (Geleen, NL); Dimphna Johanna Maria Van Beek (Geleen, NL)
Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
C08L23/16C08K3/34C08K5/098C08K5/20C08L23/0815C08L23/12C08L2205/03C08L2205/22C08L2207/02
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Quick Facts
Patent No.
US 12,202,959
App. No.
17/431,651
Granted
Jan 21, 2025
Kind
B2
Abstract

The invention relates to a composition comprising (A) a heterophasic propylene copolymer and (B) an ethylene copolymer of ethylene and an alpha-olefin comonomer units having 4 to 10 carbon atoms, wherein (A) the heterophasic propylene copolymer consists of (a) a propylene-based matrix, wherein the propylene-based matrix consists of a propylene homopolymer and/or a propylene copolymer consisting of at least 70 wt % of propylene monomer units and at most 30 wt % of ethylene and/or α-olefin monomer units, based on the total weight of the propylene-based matrix and wherein the propylene-based matrix is present in an amount of 80 to 95 wt % based on the total heterophasic propylene copolymer and (b) a dispersed ethylene-α-olefin copolymer, wherein the dispersed O ethylene-α-olefin copolymer is present in an amount of 5 to 20 wt %, preferably 8 to 15 wt %, based on the total heterophasic propylene copolymer and wherein the sum of the total amount of propylene-based matrix and total amount of the dispersed ethylene-α-olefin copolymer in the heterophasic propylene copolymer is 100 wt %, wherein the amount of ethylene in the ethylene-α-olefin copolymer of the heterophasic propylene copolymer is 10 to 45 wt %, preferably 30 to 38 wt %, and wherein (B) the ethylene copolymer has a density of to 0.850 to 0.910 g/cm3 and a melt flow index of 10.0 to 50.0 dg/min, preferably 30.0 dg/min, measured in accordance with ASTM D1238 (2.16 kg/190° C.), wherein the composition comprises less than 5 wt % of talc with respect to the total composition.

Claims (29)

1. A composition comprising (A) a heterophasic propylene copolymer and (B) an ethylene copolymer of ethylene and an alpha-olefin comonomer units having 4 to 10 carbon atoms,

wherein (A) the heterophasic propylene copolymer consists of

(a) a propylene-based matrix,

wherein the propylene-based matrix consists of a propylene homopolymer and

wherein the propylene-based matrix is present in an amount of 80 to 95 wt % based on a total weight of the heterophasic propylene copolymer and

(b) a dispersed ethylene-α-olefin copolymer which is an ethylene-propylene copolymer,

wherein the dispersed ethylene-α-olefin copolymer is present in an amount of 5 to 20 wt %, based on the total weight of the heterophasic propylene copolymer and

wherein a sum of a total amount of propylene-based matrix and a total amount of the dispersed ethylene-α-olefin copolymer in the heterophasic propylene copolymer is 100 wt %,

wherein an amount of ethylene in the ethylene-α-olefin copolymer of the heterophasic propylene copolymer is 10 to 45 wt %, with respect to the ethylene-α-olefin copolymer and

wherein (B) the ethylene copolymer has a density of to 0.850 to 0.910 g/cm 3 and a melt flow index of 10.0 to 50.0 dg/min, measured in accordance with ASTM D1238 (2.16 kg/190° C.),

wherein the composition comprises less than 5 wt % of talc with respect to the total composition, and

wherein the composition further comprises (C) a C10-C30 aliphatic carboxylic acid amide, and

wherein a total amount of (A) and (B) is at least 95 wt %, with respect to the total composition.

2. The composition of claim 1 , wherein the propylene-based matrix has a melt flow of 1.5 to 10 dg/min, measured according to ISO1133-1:2011 at 2.16 kg and 230° C.

3. The composition according to claim 1 , wherein (B) has a density of 0.850 to 0.890 g/cm 3 .

4. The composition according to claim 1 , wherein (B) is selected from the group consisting of ethylene-1-butene copolymer, ethylene-1-hexene copolymer, ethylene-1-octene copolymer and mixtures thereof.

5. The composition according to claim 1 , wherein the C10-C30 aliphatic carboxylic acid amide is an unsaturated C10-C30 aliphatic carboxylic acid amide.

6. The composition according to claim 1 , wherein the C10-C30 aliphatic carboxylic acid amide is selected from the group consisting of erucamide and oleamide.

7. The composition according to claim 1 , wherein an amount of (C) in the composition is to 100 to 10000 ppm, with respect to an amount of (A) in the total composition.

8. The composition according to claim 1 , wherein the composition further comprises (D) a nucleating agent.

9. The composition according to claim 8 , wherein the nucleating agent comprises a first nucleating agent, which comprises a cyclic dicarboxylate salt compound; and a second nucleating agent, which comprises talc, wherein the cyclic dicarboxylate salt compound has the formula (I):

10. The composition of claim 9 , wherein an amount of the first nucleating agent is 25 to 1000 ppm with respect to an amount of (A) in the total composition and an amount of talc in the composition is 1000 to 50000 ppm with respect to the amount of (A) in the total composition.

11. The composition according to claim 1 , wherein the composition further comprises (E) additives comprising a UV stabilizer.

12. The composition according to claim 1 , wherein the composition comprises less than 5 wt % of an inorganic filler with respect to the total composition.

13. The composition according to claim 1 , wherein the composition has a gloss as determined according to ISO 2813 and DIN67530 at a measurement angle of 20° of at least 65 GU.

14. A process for the preparation of the composition according to claim 1 , comprising melt mixing (A) and (B) and optional components.

15. An article comprising the composition of claim 1 .

16. The article according to claim 15 , wherein the article is an automotive part or a home appliance.

17. The article according to claim 15 , wherein the article is an automotive interior part.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 15, 2022
From: HERKLOTS, MARC; BANDE, DANIEL; DE LA CROIX, GINGER; VAN BEEK, DIMPHNA JOHANNA MARIA
To: SABIC GLOBAL TECHNOLOGIES B.V.
Reel/Frame 059272/0036 →
Priority Claims (1)
EP 19157835 · Feb 18, 2019 · regional
Continuity (1)
Related Publication 20220251359A1 · Aug 11, 2022
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