IP Library Granted Patent US 10,703,891
Granted Patent B2
US 10,703,891 · App. 16/078,099 · Granted Jul 7, 2020

Composition comprising heterophasic propylene copolymer

Inventors: Marc Herklots (Roermond, NL); Désirée Marie Louise Seegers (Geleen, NL); Ralf Kleppinger (Selfkant, DE); Timo Olavi Latvakangas (Maastricht, NL); Eddy Jozef Agnes van de Gaar (Urmond, NL)
Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
C08L23/142C08F110/06C08F210/16C08J3/201C08K3/34C08K5/06C08K5/098C08K5/20C08L23/12C08L23/16C08L2205/025C08L2205/24C08L2207/02
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Quick Facts
Patent No.
US 10,703,891
App. No.
16/078,099
Granted
Jul 7, 2020
Kind
B2
Abstract

The invention relates to a composition comprising a heterophasic propylene copolymer and a C10-C30 aliphatic carboxylic acid amide, wherein the heterophasic propylene copolymer consists of a propylene-based matrix consisting of a propylene homopolymer and/or a propylene-α-olefin copolymer consisting of at least 70 wt % of propylene and at most 30 wt % of α-olefin and wherein the propylene-based matrix is present in an amount of 76 to 90 wt % based on the total heterophasic propylene copolymer and a dispersed ethylene-α-olefin copolymer, wherein the dispersed ethylene-α-olefin copolymer is present in an amount of 24 to 10 wt % based on the total heterophasic propylene copolymer and wherein the sum of the total amount of propylene-based matrix and total amount of the dispersed ethylene-α-olefin copolymer in the heterophasic propylene copolymer is 100 wt %, wherein the amount of ethylene in the ethylene-α-olefin copolymer is 30 to 38 wt %.

Claims (38)

1. A composition comprising (A) a heterophasic propylene copolymer and (B) a C10-C30 aliphatic carboxylic acid amide, wherein the heterophasic propylene copolymer consists of:

(a) a propylene-based matrix,

wherein the propylene-based matrix consists of a propylene homopolymer and/or a propylene-α-olefin copolymer consisting of at least 70 wt % of propylene and at most 30 wt % of α-olefin, based on the total weight of the propylene-based matrix, and

wherein the propylene-based matrix is present in an amount of 76 to 90 wt % based on the total heterophasic propylene copolymer, and

(b) a dispersed ethylene-α-olefin copolymer,

wherein the dispersed ethylene-α-olefin copolymer is present in an amount of 24 to 10 wt % based on the total heterophasic propylene copolymer,

wherein the sum of the total amount of propylene-based matrix and total amount of the dispersed ethylene-α-olefin copolymer in the heterophasic propylene copolymer is 100 wt %,

wherein the amount of ethylene in the ethylene-α-olefin copolymer is 30 to 38 wt %,

wherein the propylene-based matrix has a melt flow index MFI PP as determined according to ISO1133 at 230° C. and 2.16 kg and the dispersed ethylene-α-olefin copolymer has a melt flow index MFI EPR as determined according to ISO1133 at 230° C. and 2.16 kg, wherein the ratio of MFI PP /MFI EPR is 0.5-15, and

wherein the heterophasic propylene copolymer has a MFI of 10 to 100 dg/min as determined according to ISO1133 at 230° C. and 2.16 kg.

2. The composition according to claim 1 , wherein (B) is an unsaturated C10-C30 aliphatic carboxylic acid amide.

3. The composition according to claim 1 , wherein the amount of (B) in the composition is 0.01-1 wt % based on the total weight of the composition.

4. The composition according to claim 1 , wherein the propylene-based matrix consists of a propylene homopolymer.

5. The composition according to claim 1 , wherein the α-olefin in the ethylene-α-olefin copolymer is chosen from the group of α-olefins having 3 to 8 carbon atoms and any mixtures thereof.

6. The composition according to claim 1 , wherein MFI PP is 1.5 to 10 dg/min.

7. The composition according to claim 1 , wherein MFI EPR is 1 to 3 dg/min.

8. The composition according to claim 1 , wherein the amount of ethylene in the heterophasic propylene copolymer is in the range of 3-8 wt % based on the heterophasic propylene copolymer.

9. The composition according to claim 1 , wherein the composition comprises at most 4 wt % of glass materials.

10. The composition according to claim 1 , wherein the composition comprises a nucleating agent.

11. A process for the preparation of the composition according to claim 1 , comprising melt mixing (A) and (B).

12. An article comprising the composition of claim 1 .

13. The article according to claim 12 , wherein the article is a consumer appliance.

14. The article according to claim 12 , wherein the article is made by injection moulding.

15. The composition according to claim 2 , the unsaturated C10-C30 aliphatic carboxylic acid amide is selected from the group consisting of erucamide and oleamide.

16. The composition according to claim 5 , wherein the α-olefin in the ethylene-α-olefin copolymer is propylene.

17. The composition according to claim 1 , wherein the amount of ethylene in the heterophasic propylene copolymer is in the range of 3-7 wt % based on the heterophasic propylene copolymer.

18. The composition according to claim 1 , wherein the composition comprises a nucleating composition comprising a first nucleating agent, which comprises a cyclic dicarboxylate salt compound; and a second nucleating agent, which comprises talc, wherein the cyclic dicarboxylate salt compound has the formula (I):

19. The composition according to claim 13 , wherein the consumer appliance is selected from the group consisting of household appliances, electrical appliances, and garden power tools.

20. A composition comprising (A) a heterophasic propylene copolymer, (B) 0.01-1 wt % of a C10-C30 aliphatic carboxylic acid amide based on the total weight of the composition, and (C) a nucleating agent, wherein the heterophasic propylene copolymer consists of:

(a) a propylene-based matrix,

wherein the propylene-based matrix consists of a propylene homopolymer and/or a propylene-α-olefin copolymer consisting of at least 70 wt % of propylene and at most 30 wt % of α-olefin, based on the total weight of the propylene-based matrix, and

wherein the propylene-based matrix is present in an amount of 76 to 90 wt % based on the total heterophasic propylene copolymer, and

(b) a dispersed ethylene-α-olefin copolymer,

wherein the dispersed ethylene-α-olefin copolymer is present in an amount of 24 to 10 wt % based on the total heterophasic propylene copolymer,

wherein the sum of the total amount of propylene-based matrix and total amount of the dispersed ethylene-α-olefin copolymer in the heterophasic propylene copolymer is 100 wt %,

wherein the amount of ethylene in the ethylene-α-olefin copolymer is 30 to 38 wt %,

wherein the propylene-based matrix has a melt flow index MFI PP as determined according to ISO1133 at 230° C. and 2.16 kg is 1.5 to 10 dg/min and the dispersed ethylene-α-olefin copolymer has a melt flow index MFI EPR as determined according to ISO1133 at 230° C. and 2.16 kg is 1 to 3 dg/min, wherein the ratio of MFI PP /MFI EPR is 0.5-15, and

wherein the heterophasic propylene copolymer has a MFI of 10 to 100 dg/min as determined according to ISO1133 at 230° C. and 2.16 kg.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 25, 2018
From: HERKLOTS, MARC; SEEGERS, DESIREE MARIE LOUISE; KLEPPINGER, RALF; LATVAKANGAS, TIMO OLAVI; VAN DE GAAR, EDDY JOZEF AGNES
To: SABIC GLOBAL TECHNOLOGIES B.V.
Reel/Frame 046959/0553 →
Priority Claims (4)
EP 16156712 · Feb 22, 2016 · regional
EP 16156714 · Feb 22, 2016 · regional
EP 16156715 · Feb 22, 2016 · regional
EP 16199022 · Nov 16, 2016 · regional
Continuity (1)
Related Publication 20190062542A1 · Feb 28, 2019
Cited By (1)
US 12,202,959