IP Library › Granted Patent US 12,214,334
Granted Patent B2
US 12,214,334 · App. 17/435,007 · Granted Feb 4, 2025

Supported catalyst particles

Inventors: Hiroki Nihashi (Kakegawa, JP); Shogo Kawamura (Kakegawa, JP); Tomomasa Aikawa (Kakegawa, JP); Isao Naito (Kakegawa, JP); Shogo Shirakawa (Toyota, JP); Masahide Miura (Toyota, JP); Nobuyuki Takagi (Toyota, JP); Norimichi Shimano (Toyota, JP)
Assignees: CATALER CORPORATION; TOYOTA JIDOSHA KABUSHIKI KAISHA
B01J23/464B01J21/04B01J21/066B01J35/40B01J37/04B01J37/08
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Quick Facts
Patent No.
US 12,214,334
App. No.
17/435,007
Granted
Feb 4, 2025
Kind
B2
Abstract

A supported catalyst particles include oxide carrier particles and noble metal particles supported on the oxide carrier particles, wherein the mass of the noble metal particles is less than or equal to 5 mass % based on the mass of the oxide carrier particles, and the average particle size of the noble metal particles measured by transmission electron microscopy is 1.0-2.0 nm, with the standard deviation σ less than or equal to 0.8 nm.

Claims (11)

1. A supported catalyst particle, comprising

an oxide carrier particle and noble metal particles supported on the oxide carrier particle,

wherein a noble metal constituting the noble metal particles is rhodium,

the noble metal particles have a mass of 5% by mass or less based on the mass of the oxide carrier particle,

the noble metal particles have an average particle size of 1.0 nm to 2.0 nm with a particle size standard deviation σ of 0.8 nm or less, as measured by observation with a transmission electron microscope, and

a presence ratio of noble metal particles having a particle size of less than 1.0 nm is 5% by mass or less with respect to the total mass of the noble metal particles.

2. The supported catalyst particle according to claim 1 , wherein the noble metal particles have a particle size standard deviation σ of 0.6 nm or less.

3. The supported catalyst particle according to claim 1 , wherein the noble metal particles have an average particle size of 1.2 nm to 1.8 nm.

4. The supported catalyst particle according to claim 1 ,

wherein the noble metal particles have a mass of 1.0% by mass or less based on the mass of the oxide carrier particle.

5. The supported catalyst particle according to claim 1 , wherein the oxide carrier particle is a particle of an oxide of one or more metals selected from titanium, zirconium, cerium, and aluminum.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 28, 2021
From: NIHASHI, HIROKI; KAWAMURA, SHOGO; AIKAWA, TOMOMASA; NAITO, ISAO; SHIRAKAWA, SHOGO; MIURA, MASAHIDE; TAKAGI, NOBUYUKI; SHIMANO, NORIMICHI
To: CATALER CORPORATION; TOYOTA JIDOSHA KABUSHIKI KAISHA
Reel/Frame 057630/0701 →
Priority Claims (1)
JP 2019-035818 · Feb 28, 2019 · national
Continuity (1)
Related Publication 20220134313A1 · May 5, 2022
References Cited (21)
US 20090317289A1 · Ito et al. · 2009 [cited by applicant]
US 20100234623A1 · Haruta · 2010 [cited by examiner]
US 20110005473A1 · Ishikawa · 2011 [cited by examiner]
US 20140323785A1 · Lande · 2014 [cited by examiner]
US 20190193065A1 · Shirakawa et al. · 2019 [cited by applicant]
CN 102728356A · 2012 [cited by applicant]
CN 104801316A · 2015 [cited by applicant]
DE 19852547A1 · 2000 [cited by applicant]
JP 2007038085A · 2007 [cited by applicant]
JP 2008031554A · 2008 [cited by applicant]
JP 2010215534A · 2010 [cited by applicant]
JP 2016147256A · 2016 [cited by applicant]
JP 2017164735A · 2017 [cited by applicant]
JP 2019111511A · 2019 [cited by applicant]
Feb. 1, 2022 Office Action issued in Japanese Patent Application 2021-501891. [cited by applicant]
Vlaic, G. et al., “Morphology of Rhodium Particles in Ex-chloride Rh/Ce0.5Zr0.5O2 Catalyst”, Journal of Catalysis, Feb. 15, 2000, vol. 190, pp. 182-190. [cited by applicant]
Mar. 24, 2020 International Search Report issued in International Patent Application No. PCT/JP2020/005392. [cited by applicant]
Mar. 24, 2020 Written Opinion issued in International Patent Application No. PCT/JP2020/005392. [cited by applicant]
Oct. 26, 2022 Search Report issued in European Patent Application No. 20762311.7. [cited by applicant]
B. Didillon et al. “From Colloidal Particles to Supported Catalysts: A Comprehensive Study of Palladium Oxide Hydrosols Deposited on Alumina”. Zeolites and Related Materials: Trends, Targets, and Challenges, [Studies in… [cited by applicant]
Irene E. Beck et al. “Platinum Nanoparticles on Al2O3: Correlation Between The Particle Size and Activity in Total Methane Oxidation”. Journal of Catalysis, Academic Press, Duluth, MN, US, vol. 268, No. 1, Nov. 15, 2009… [cited by applicant]