Method for producing exhaust gas purifying catalyst and exhaust gas purifying catalyst
The present disclosure provides a method for producing an exhaust gas purifying catalyst, in which fine Rh—Pd particles exhibiting high catalytic activity are produced such that a variation in the Pd composition can be reduced. The present disclosure relates to a method for producing an exhaust gas purifying catalyst having fine composite metal particles containing Rh and Pd, comprising: preparing a starting material solution containing Rh and Pd, in which the atomic percentage of Pd to the total of Rh and Pd is 1 atomic % to 15 atomic %; and allowing the prepared starting material solution to react with a neutralizer by a super agitation reactor having a rotation number of 500 rpm or more, to generate fine composite metal particles.
1. A method for producing an exhaust gas purifying catalyst having fine composite metal particles containing Rh and Pd, comprising:
preparing a starting material solution containing a homogenous mixture of Rh and Pd, in which an atomic percentage of Pd to a total of Rh and Pd (=(number of Pd atoms/(total number of Rh and Pd atoms))×100) is 1 atomic % to 15 atomic %;
allowing the prepared starting material solution to react with a neutralizer by a super agitation reactor having a rotation number of 1,000 rpm to 40,000 rpm, to generate fine composite metal particles in which Rh and Pd are homogeneously dispersed; and
mixing the fine composite metal particles with a powder carrier to obtain the exhaust gas purifying catalyst.
2. The method according to claim 1 , wherein the atomic percentage of Pd to the total of Rh and Pd is 2 atomic % to 5 atomic %.
3. The method according to claim 1 , wherein the rotation number of the super agitation reactor is 5,000 rpm to 10,000 rpm.
4. The method according to claim 2 , wherein the rotation number of the super agitation reactor is 7,000 rpm to 9,000 rpm.
5. The method according to claim 1 , wherein the neutralizer is an organic base.
6. The method according to claim 2 , wherein the neutralizer is an organic base.
7. The method according to claim 3 , wherein the neutralizer is an organic base.
8. The method according to claim 1 , wherein the starting material solution is a mixed solution of an Rh nitrate solution and a Pd nitrate solution, and the neutralizer is tetramethylammonium hydroxide.
9. The method according to claim 2 , wherein the starting material solution is a mixed solution of an Rh nitrate solution and a Pd nitrate solution, and the neutralizer is tetramethylammonium hydroxide.
10. The method according to claim 3 , wherein the starting material solution is a mixed solution of an Rh nitrate solution and a Pd nitrate solution, and the neutralizer is tetramethylammonium hydroxide.
11. The method according to claim 4 , wherein the starting material solution is a mixed solution of an Rh nitrate solution and a Pd nitrate solution, and the neutralizer is tetramethylammonium hydroxide.
12. The method according to claim 1 , wherein
when the fine composite metal particles containing Rh and Pd in the exhaust gas purifying catalyst are analyzed according to STEM-EDX, an average of an atomic percentage of Pd to a total of Rh and Pd is 2 atomic % to 5 atomic % (wherein the average of the atomic percentage of Pd to the total of Rh and Pd is a value calculated by randomly selecting 10 or more fine composite metal particles containing Rh and Pd from the exhaust gas purifying catalyst, measuring all of the selected fine composite metal particles containing Rh and Pd according to STEM-EDX, totalizing all values of the atomic percentage of Pd to the total of Rh and Pd in each fine composite metal particle containing Rh and Pd, and dividing the obtained sum by a total number of all of the selected fine composite metal particles containing Rh and Pd), and
a standard deviation regarding a variation in the atomic percentage of Pd to the total of Rh and Pd is less than 5 (wherein the standard deviation regarding the variation in the atomic percentage of Pd to the total of Rh and Pd is calculated by randomly selecting 20 or more fine composite metal particles containing Rh and Pd from the exhaust gas purifying catalyst, measuring all of the selected fine composite metal particles containing Rh and Pd according to STEM-EDX, calculating the atomic percentage of Pd to the total of Rh and Pd in each fine composite metal particle containing Rh and Pd, defining the number of all of the selected fine composite metal particles containing Rh and Pd as a total number, and calculating based on the atomic percentage of Pd to the total of Rh and Pd in each fine composite metal particle containing Rh and Pd).
13. The method according to claim 1 , wherein the powder carrier comprises one or more selected from the group consisting of silica (SiO 2 ), magnesium oxide (MgO), zirconia (ZrO 2 ), ceria (CeO 2 ), alumina (Al 2 O 3 ), and titania (TiO 2 ), or a solid solution thereof.
14. The method according to claim 1 , wherein a concentration of Rh ions in the starting material solution is 0.01 mol/L (M) to 1 M, and a concentration of Pd ions in the starting material solution is 0.1 mM to 50 mM.
15. The method according to claim 1 , wherein a concentration of Rh ions in the starting material solution is 0.03 mol/L (M) to 0.5 M, and a concentration of Pd ions in the starting material solution is 0.5 mM to 25 mM.