Composite substrate for fabricating III-V photodetector arrays
A method for forming a composite substrate containing layers of dissimilar materials is provided. The method includes a step of disposing a release layer over a base substrate where the base substrate is composed of a first material. A template layer is attached to the release layer. Characteristically, the template layer is composed of a second material and adapted to form a compound semiconductor device thereon.
1. A method for forming a composite substrate containing layers of dissimilar materials, the method comprising:
forming a release layer over a base substrate having a buffer layer, the base substrate being composed of a first material;
attaching a metal template layer to the release layer, the metal template layer being composed of a Group III metal;
depositing a capping layer over the metal template layer, the capping layer being composed of a dielectric material;
patterning the metal template layer and the capping layer to form a first composite substrate including a first plurality of separated template units separated by a first plurality of trenches;
annealing the first composite substrate in an ambient gas to form a second composite substrate wherein metal template layer is converted to a first crystalline semiconductor layer which is interposed between the buffer layer and the capping layer; and
removing the capping layer to form a third composite substrate such that the first crystalline semiconductor layer is exposed.
2. The method of claim 1 , wherein the base substrate is a silicon wafer.
3. The method of claim 1 , wherein the ambient gas includes a Group V atom and the first crystalline semiconductor layer is composed of a III-V compound semiconductor.
4. The method of claim 3 , wherein the III-V compound semiconductor is selected from the group consisting of InP, GaAs, InGaAs, AlAs, AlSb, InAs, InN, GaP, GaAs, GaN, AlP, and AlN.
5. The method of claim 3 , wherein the III-V compound semiconductor is grown on the base substrate by templated liquid phase growth.
6. The method of claim 5 , wherein the III-V compound semiconductor is a single crystal.
7. The method of claim 5 , wherein the III-V compound semiconductor is grown in a plurality of regions on the base substrate.
8. The method of claim 7 , wherein the regions all have the same crystal orientation.
9. The method of claim 1 , further comprising selectively growing a second semiconductor layer over the first crystalline semiconductor layer to form a fourth composite substrate.
10. The method of claim 9 , further comprising:
forming a fifth composite substrate by depositing an oxide layer over the second semiconductor layer and which the trenches and then planarization the oxide layer;
forming a sixth composite substrate by selectively removing a portion of oxide layer to form a second set of trenches and growing metal contacts in the second set of trenches; and
forming a seventh composite substrate by singularizing a plurality of compound semiconductor devices wherein the oxide layer, release layer, and buffer layer are etched to a substrate surface of the base substrate.
11. The method of claim 10 , aligning and attaching readout integrated circuits to the seventh composite substrate.
12. The method of claim 9 , wherein at least one compound semiconductor device including the first crystalline semiconductor layer and the second semiconductor layer is formed.
13. The method of claim 12 , wherein a plurality of compound semiconductor devices are formed in different regions on the base substrate.
14. The method of claim 12 , wherein the at least one compound semiconductor device is sensitive to photons.
15. The method of claim 12 , wherein the at least one compound semiconductor device is a photodetector.
16. The method of claim 12 , wherein the compound semiconductor device is a SWIR detector.
17. The method of claim 12 , wherein the compound semiconductor device is designed for LIDAR applications.
18. A composite substrate comprising:
a base substrate;
a buffer layer disposed over the base substrate;
a release layer disposed over the buffer layer;
a first crystalline semiconductor layer disposed over the release layer;
a second semiconductor layer disposed over the first crystalline semiconductor layer; and
an oxide layer is disposed over the first crystalline semiconductor layer and the second semiconductor layer.
19. The composite substrate of claim 18 wherein the base substrate is a silicon wafer.
20. The composite substrate of claim 19 wherein the release layer is composed of a component selected from the group consisting of Mo, NbN, and TiN.
21. The composite substrate of claim 18 , the buffer layer has a thickness from about 100 to 200 nm and the release layer has a thickness from about 10 to 50 nm.
22. The composite substrate of claim 18 , wherein the first crystalline semiconductor layer is composed of InP, GaAs, InGaAs, AlAs, AlSb, InAs, InN, GaP, GaAs, GaN, AlP, or AlN.
23. The composite substrate of claim 18 , wherein the second semiconductor layer is composed of InGaAs.
24. The composite substrate of claim 23 , wherein a compound semiconductor device includes the first crystalline semiconductor layer and the second semiconductor layer.
25. The composite substrate of claim 24 , wherein the compound semiconductor device is a photodetector.
26. The composite substrate of claim 18 further comprising metal contacts embedded in the oxide layer.
27. The composite substrate of claim 26 , wherein an ROIC wafer having metal interconnect pads embedded in oxide is bonded to the composite substrate.
28. The composite substrate of claim 27 , wherein the release layer is configured to be removable to release photodetectors bonded to the ROIC wafer.