IP Library › Granted Patent US 11,912,960
Granted Patent B2
US 11,912,960 · App. 17/453,798 · Granted Feb 27, 2024

Efficient surfactant system on plastic and all types of ware

Inventors: Janel Marie Kieffer (Saint Paul, MN); Terrence P. Everson (Saint Paul, MN); James S. Dailey (Grosse Ile, MI); Thomas Gessner (Ypsilanti, MI); Juergen Tropsch (Ludwigshafen, DE)
Assignee: Ecolab USA Inc.
C11D1/825A47L15/0007C11D1/72C11D1/79
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Quick Facts
Patent No.
US 11,912,960
App. No.
17/453,798
Granted
Feb 27, 2024
Kind
B2
Abstract

Surfactant systems and compositions incorporating the same are disclosed for use as rinse aids on plastics and other wares. The surfactant systems and compositions include both liquid and solid formulations, along with methods of use for treating plastics and other wares. The surfactant systems and compositions provide synergistic combinations allowing lower actives in composition formulations of the plastic-compatible surfactant systems providing good sheeting, wetting and drying properties.

Claims (43)

1. A method of rinsing a surface comprising:

applying a rinse aid composition to a ware in need of rinsing;

wherein the rinse aid composition comprises a surfactant system comprising:

(i) at least two surfactants according to the following formulas:

R 1 —O-(EO) x3 (PO) y3 —H  (A)

wherein R 1 is a straight-chain C 10 -C 16 alkyl, wherein x 3 is from 5 to 8, and

wherein y 3 is from 2 to 5,

R 1 —O-(EO) x4 (PO) y4 —H  (A2)

wherein R 1 is a straight-chain C 10 -C 16 alkyl, wherein x 4 is from 4 to 6, and

wherein y 4 is from 3 to 5,

R 2 —O-(EO) x1 —H  (B)

wherein R 2 is a C 10 -C 14 alkyl with an average of at least 2 branches per residue, and

wherein x 1 is from 5 to 10,

R 7 —O—(PO) y5 (EO) x5 (PO) y6 —H  (D)

wherein R 7 is a branched C 8 -C 16 Guerbet alcohol, x 5 is from 5 to 30, y 5 is from 1 to 4,

and y 6 is from 10 to 20,

wherein x is from 88 to 108, y is from 57 to 77, and z is from 88 to 108, and

wherein x is from 15 to 25, y is from 10 to 25, and z is from 15 to 25; and

(ii) optionally an additional surfactant according to the following formulas:

R 2 —O-(EO) x2 —H  (C)

wherein R 2 is a C 10 -C 14 alkyl with an average of at least 2 branches per residue, and wherein x 2 is from 2 to 4,

R 6 —O—(PO) y4 (EO) x4 —H  (E)

wherein R 6 is a C 8 -C 16 Guerbet alcohol, wherein x 4 is from 2 to 10, and wherein y 4 is

wherein x is from 12 to 20, y is from 120 to 220, and z is from 12 to 20.

2. The method of claim 1 , wherein the rinse aid composition further comprises an additional functional ingredient.

3. The method of claim 2 , wherein the additional functional ingredient is an additional functional ingredient is a solidification aid, carrier, chelating agent, bleaching agent, sanitizer, defoaming agent, anti-redeposition agent, optical brightener, dye, odorant, stabilizing agent, dispersant, enzyme, corrosion inhibitor, thickener, solubility modifier, or a combination thereof.

4. The method of claim 1 , wherein the surfactant system comprises surfactant (A) or surfactant (A2), and surfactant (B), and optionally surfactant (C).

5. The method of claim 1 , wherein the surfactant system comprises surfactant (A), surfactant (B), and surfactant (D), or wherein the surfactant system comprises surfactant (A2), surfactant (B), and surfactant (D).

6. The method of claim 1 , wherein the surfactant system comprises surfactant (H) or surfactant (D), and surfactant (G), and optionally surfactant (A).

7. The method of claim 1 , wherein the surfactant system comprises surfactant (B) and surfactant (D), and optionally surfactant (F).

8. The method of claim 1 , wherein the surfactant system comprises surfactant (A) or surfactant (A2), and surfactant (D) or surfactant (H).

9. The method of claim 1 , wherein the rinse aid composition is a liquid concentrate or a solid.

10. The method of claim 9 , wherein the rinse aid composition is a pressed solid or an extruded solid.

11. The method of claim 1 , further comprising a first step of contacting the rinse aid composition with water to dilute the rinse aid composition.

12. The method of claim 11 , wherein the rinse aid composition diluted with water has a pH of about 8.5 or below.

13. The method of claim 11 , wherein the rinse aid composition diluted with water has about 1 ppm to about 125 ppm of the surfactant system.

14. The method of claim 1 , further comprising a step of reducing the contact angle of the surfactant system composition by at least about 5° compared to the contact angle of a commercially-available rinse aid composition to induce sheeting and result in a faster drying time of the surface.

15. The method of claim 1 , wherein the method is used in a warewashing system.

16. The method of claim 15 , wherein the warewashing system includes one or more rinse cycles in a commercial warewashing machine.

17. The method of claim 15 , wherein the one or more rinse cycles include a hot water sanitizing rinse cycle, a chemical sanitizing rinse cycle, or a combination thereof.

18. The method of claim 15 , wherein the warewashing system is a low temperature warewash system, and wherein the method is performed at a temperature of 140° F. or less.

19. The method of claim 1 , wherein the ware is a cookware, dishware, flatware, glass, cups a hard ware surface, glass ware surface, plastic ware surface, or a combination thereof.

20. The method of claim 1 , wherein the method reduces spotting and filming on the ware.

Assignments (5)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 9, 2021
From: DAILEY, JAMES S.; GESSNER, THOMAS
To: BASF CORPORATION
Reel/Frame 058350/0813 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 9, 2021
From: KIEFFER, JANEL M.; EVERSON, TERRENCE P.
To: ECOLAB USA INC.
Reel/Frame 058350/0886 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 9, 2021
From: BASF CORPORATION
To: BASF SE
Reel/Frame 058351/0678 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 9, 2021
From: BASF SE
To: ECOLAB USA INC.
Reel/Frame 058352/0019 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 9, 2021
From: TROPSCH, JUERGEN
To: BASF SE
Reel/Frame 058439/0041 →
Continuity (6)
Continuation 16848003 · Apr 14, 2020
Continuation 15966172 · Apr 30, 2018
Continuation 15157124 · May 17, 2016
Continuation 15157194 · May 17, 2016
Provisional Application 62163454 · May 19, 2015
Related Publication 20220056369A1 · Feb 24, 2022
Cited By (1)
US 12,747,412