IP Library › Granted Patent US 12,747,412
Granted Patent B2
US 12,747,412 · App. 18/415,040 · Granted Sep 29, 2026

Efficient surfactant system on plastic and all types of ware

Inventors: Janel Marie Van Vleet (Saint Paul, MN); Terrence P. Everson (Saint Paul, MN); James S. Dailey (Grosse Ile, MI); Thomas Gessner (Ypsilanti, MI); Juergen Tropsch (Ludwigshafen, DE)
Assignee: ECOLAB USA INC.
C11D1/825A47L15/0007C11D1/72C11D1/79
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,747,412
App. No.
18/415,040
Granted
Sep 29, 2026
Kind
B2
Abstract

Surfactant systems and compositions incorporating the same are disclosed for use as rinse aids on plastics and other wares. The surfactant systems and compositions include both liquid and solid formulations, along with methods of use for treating plastics and other wares. The surfactant systems and compositions provide synergistic combinations allowing lower actives in composition formulations of the plastic-compatible surfactant systems providing good sheeting, wetting and drying properties.

Claims (37)

1 . A method of rinsing a surface comprising:

applying a rinse aid composition to a surface in need of rinsing;

wherein the rinse aid composition comprises a surfactant system comprising:

(i) at least two surfactants according to the following formulas:

wherein R 1 is a straight-chain C 10 -C 16 alkyl, wherein x 3 is from 5 to 8, and

wherein y 3 is from 2 to 5,

wherein R 1 is a straight-chain C 10 -C 16 alkyl, wherein x 4 is from 4 to 6, and

wherein y 4 is from 3 to 5,

wherein R 2 is a C 10 -C 14 alkyl with an average of at least 2 branches per residue, and

wherein x 1 is from 5 to 10,

wherein R 7 is a branched C 8 -C 16 Guerbet alcohol, x 5 is from 5 to 30, y 5 is from 1 to 4, and y 6 is from 10 to 20,

wherein x is from 88 to 108, y is from 57 to 77, and z is from 88 to 108, and

wherein x is from 15 to 25, y is from 10 to 25, and z is from 15 to 25; and

(ii) optionally an additional surfactant according to the following formulas:

wherein R 2 is a C 10 -C 14 alkyl with an average of at least 2 branches per residue, and

wherein x 2 is from 2 to 4,

wherein R 6 is a C 8 -C 16 Guerbet alcohol, wherein x 4 is from 2 to 10, and wherein y 4 is from 1 to 2, and

wherein x is from 12 to 20, y is from 120 to 220, and z is from 12 to 20.

2 . The method of claim 1 , wherein the rinse aid composition further comprises an additional functional ingredient.

3 . The method of claim 2 , wherein the additional functional ingredient is a solidification aid, carrier, chelating agent, bleaching agent, sanitizer, defoaming agent, anti-redeposition agent, optical brightener, dye, odorant, stabilizing agent, dispersant, enzyme, corrosion inhibitor, thickener, solubility modifier, or a combination thereof.

4 . The method of claim 1 , wherein the surfactant system comprises surfactant (A) or surfactant (A2), and surfactant (B), and optionally surfactant (C).

5 . The method of claim 1 , wherein the surfactant system comprises surfactant (A), surfactant (B), and surfactant (D), or wherein the surfactant system comprises surfactant (A2), surfactant (B), and surfactant (D).

6 . The method of claim 1 , wherein the surfactant system comprises surfactant (H) or surfactant (D), and surfactant (G), and optionally surfactant (A).

7 . The method of claim 1 , wherein the surfactant system comprises surfactant (B) and surfactant (D), and optionally surfactant (F).

8 . The method of claim 1 , wherein the surfactant system comprises surfactant (A) or surfactant (A2), and surfactant (D) or surfactant (H).

9 . The method of claim 1 , wherein the rinse aid composition is a liquid concentrate or a solid.

10 . The method of claim 9 , wherein the rinse aid composition is a pressed solid or an extruded solid.

11 . The method of claim 1 , further comprising a first step of contacting the rinse aid composition with water to dilute the rinse aid composition.

12 . The method of claim 11 , wherein the rinse aid composition diluted with water has an actives concentration of less than 5 wt. %.

13 . The method of claim 11 , wherein the rinse aid composition diluted with water has about 1 ppm to about 125 ppm of the surfactant system.

14 . The method of claim 1 , further comprising a step of reducing the contact angle of the rinse aid composition by at least about 5° compared to the contact angle of a commercially-available rinse aid composition to induce sheeting and result in a faster drying time of the surface.

15 . The method of claim 1 , wherein the surface is in a warewashing application.

16 . The method of claim 15 , wherein the warewashing system includes one or more rinse cycles in a commercial warewashing machine.

17 . The method of claim 15 , wherein the one or more rinse cycles include a hot water sanitizing rinse cycle, a chemical sanitizing rinse cycle, or a combination thereof.

18 . The method of claim 15 , wherein the warewashing system is a low temperature warewash application, wherein the method is performed at a temperature of 140° F. or less.

19 . The method of claim 1 , wherein the ware is a cookware, dishware, flatware, glass, cup, a hard ware surface, glass ware surface, plastic ware surface, or a combination thereof.

20 . The method of claim 1 , wherein the method reduces spotting and filming on the ware.

Assignments (5)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 19, 2024
From: TROPSCH, JUERGEN
To: BASF SE
Reel/Frame 066180/0564 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 19, 2024
From: KIEFFER, JANEL M.; EVERSON, TERRENCE P.
To: ECOLAB USA INC.
Reel/Frame 066180/0614 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 19, 2024
From: BASF SE
To: ECOLAB USA INC.
Reel/Frame 066180/0625 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 19, 2024
From: DAILEY, JAMES S.; GESSNER, THOMAS
To: BASF CORPORATION
Reel/Frame 066180/0682 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 19, 2024
From: BASF CORPORATION
To: BASF SE
Reel/Frame 066180/0697 →
Continuity (7)
Continuation 17453798 · Nov 5, 2021
Continuation 16848003 · Apr 14, 2020
Continuation 15966172 · Apr 30, 2018
Continuation 15157124 · May 17, 2016
Continuation 15157194 · May 17, 2016
Provisional Application 62163454 · May 19, 2015
Related Publication 20240218288A1 · Jul 4, 2024
References Cited (182)
US 4426362A · Copeland et al. · 1984 [cited by applicant]
US 4492646A · Welch · 1985 [cited by applicant]
US 4618914A · Sato et al. · 1986 [cited by applicant]
US 4647258A · Massarsch · 1987 [cited by applicant]
US 4654161A · Kollmeier et al. · 1987 [cited by applicant]
US 4687121A · Copeland · 1987 [cited by applicant]
US 4690305A · Copeland · 1987 [cited by applicant]
US RE32763E · Fernholtz et al. · 1988 [cited by applicant]
US RE32818E · Fernholtz et al. · 1989 [cited by applicant]
US 4826661A · Copeland et al. · 1989 [cited by applicant]
US 4830769A · O'Lenick, Jr. et al. · 1989 [cited by applicant]
US 4830773A · Olson · 1989 [cited by applicant]
US 4844744A · Leiter et al. · 1989 [cited by applicant]
US 5114607A · Deck et al. · 1992 [cited by applicant]
US 5137694A · Copeland et al. · 1992 [cited by applicant]
US 5264147A · Houghton et al. · 1993 [cited by applicant]
US 5286300A · Hnatin et al. · 1994 [cited by applicant]
US 5397506A · Groth et al. · 1995 [cited by applicant]
US 5447648A · Steindorf · 1995 [cited by applicant]
US 5474698A · Rolando et al. · 1995 [cited by applicant]
US 5501815A · Man · 1996 [cited by applicant]
US 5589099A · Baum · 1996 [cited by applicant]
US 5603776A · Lentsch et al. · 1997 [cited by applicant]
US 5674831A · Schulz et al. · 1997 [cited by applicant]
US 5709852A · Gopalkrishnan et al. · 1998 [cited by applicant]
US 5767056A · Lenoir · 1998 [cited by applicant]
US 5876514A · Rolando et al. · 1999 [cited by applicant]
US 5880089A · Lentsch et al. · 1999 [cited by applicant]
US H1818H · Potgieter et al. · 1999 [cited by applicant]
US 6258765B1 · Wei et al. · 2001 [cited by applicant]
US 6294515B1 · Baum · 2001 [cited by applicant]
US 6398820B1 · Merz et al. · 2002 [cited by applicant]
US 6530383B1 · Rogmann et al. · 2003 [cited by applicant]
US 6537961B1 · Koch · 2003 [cited by applicant]
US RE38262E · Rolando et al. · 2003 [cited by applicant]
US 6838422B2 · Man et al. · 2005 [cited by applicant]
US 6866888B2 · Baker · 2005 [cited by applicant]
US 6956019B2 · Lentsch et al. · 2005 [cited by applicant]
US 7279455B2 · Kiefer et al. · 2007 [cited by applicant]
US 7592301B2 · Smith et al. · 2009 [cited by applicant]
US 7906474B2 · Varineau et al. · 2011 [cited by applicant]
US 7960333B2 · Kieffer et al. · 2011 [cited by applicant]
US 8211851B2 · Kieffer et al. · 2012 [cited by applicant]
US 8324147B2 · Kieffer et al. · 2012 [cited by applicant]
US 8395118B2 · Kryskowski et al. · 2013 [cited by applicant]
US 8450264B1 · Kieffer et al. · 2013 [cited by applicant]
US 8567161B2 · Man et al. · 2013 [cited by applicant]
US 8642530B2 · Kieffer et al. · 2014 [cited by applicant]
US 8957011B2 · Kieffer et al. · 2015 [cited by applicant]
US 9982220B2 · Kieffer · 2018 [cited by examiner]
US 10017714B2 · Kieffer · 2018 [cited by examiner]
US 10550354B2 · Kieffer · 2020 [cited by examiner]
US 10683466B2 · Kieffer · 2020 [cited by examiner]
US 11155769B2 · Ellingson · 2021 [cited by examiner]
US 11198836B2 · Kieffer · 2021 [cited by examiner]
US 11274265B2 · Kieffer · 2022 [cited by examiner]
US 11746306B2 · Ellingson et al. · 2023 [cited by applicant]
US 11912960B2 · Kieffer · 2024 [cited by examiner]
US 20020147124A1 · Klos et al. · 2002 [cited by applicant]
US 20020165115A1 · Daniels et al. · 2002 [cited by applicant]
US 20020192340A1 · Swart et al. · 2002 [cited by applicant]
US 20030109403A1 · Man et al. · 2003 [cited by applicant]
US 20030171243A1 · Kischkel et al. · 2003 [cited by applicant]
US 20040033269A1 · Hei et al. · 2004 [cited by applicant]
US 20040110657A1 · Strothoff · 2004 [cited by applicant]
US 20040157760A1 · Man et al. · 2004 [cited by applicant]
US 20040200511A1 · Klos et al. · 2004 [cited by applicant]
US 20040235703A1 · Kerobo et al. · 2004 [cited by applicant]
US 20060246242A1 · Siegel et al. · 2006 [cited by applicant]
US 20070034606A1 · Dietsche et al. · 2007 [cited by applicant]
US 20070138401A1 · Tokhtuev et al. · 2007 [cited by applicant]
US 20070253926A1 · Tadrowski et al. · 2007 [cited by applicant]
US 20080234164A1 · Tyborski · 2008 [cited by applicant]
US 20080293615A1 · Kieffer et al. · 2008 [cited by applicant]
US 20090023820A1 · Dailey et al. · 2009 [cited by applicant]
US 20090035339A1 · Istvan et al. · 2009 [cited by applicant]
US 20090196897A1 · Gladfelter et al. · 2009 [cited by applicant]
US 20090320214A1 · Shamayeli et al. · 2009 [cited by applicant]
US 20100009886A1 · Smith et al. · 2010 [cited by applicant]
US 20100144581A1 · Nekmard · 2010 [cited by applicant]
US 20100242997A1 · Smith et al. · 2010 [cited by applicant]
US 20100292127A1 · Kieffer et al. · 2010 [cited by applicant]
US 20100294309A1 · Tropsch · 2010 [cited by applicant]
US 20100300044A1 · Man et al. · 2010 [cited by applicant]
US 20110039754A1 · DeDominicis et al. · 2011 [cited by applicant]
US 20110094044A1 · Shamayeli et al. · 2011 [cited by applicant]
US 20110112003A1 · Mohs et al. · 2011 [cited by applicant]
US 20110112006A1 · Cobb et al. · 2011 [cited by applicant]
US 20110160116A1 · Mckechnie et al. · 2011 [cited by applicant]
US 20110247657A1 · Bauer et al. · 2011 [cited by applicant]
US 20110277786A1 · Zhu · 2011 [cited by applicant]
US 20110319669A1 · Yu et al. · 2011 [cited by applicant]
US 20120220512A1 · Snodgrass et al. · 2012 [cited by applicant]
US 20120225805A1 · Kieffer et al. · 2012 [cited by applicant]
US 20120291818A1 · Monsrud et al. · 2012 [cited by applicant]
US 20130172228A1 · Bartelme et al. · 2013 [cited by applicant]
US 20130225471A1 · Taneja et al. · 2013 [cited by applicant]
US 20140121151A1 · Kieffer · 2014 [cited by applicant]
US 20140261567A1 · Miralles · 2014 [cited by applicant]
US 20150284663A1 · Miralles · 2015 [cited by applicant]
US 20150337149A1 · Wakabayashi et al. · 2015 [cited by applicant]
US 20160340612A1 · Kieffer et al. · 2016 [cited by applicant]
US 20160340613A1 · Kieffer et al. · 2016 [cited by applicant]
US 20160340614A1 · Kieffer et al. · 2016 [cited by applicant]
US 20170044467A1 · Monsrud et al. · 2017 [cited by applicant]
US 20170107314A1 · Olson et al. · 2017 [cited by applicant]
US 20170121200A1 · Brozell · 2017 [cited by applicant]
US 20170198240A1 · Fast · 2017 [cited by applicant]
US 20180015509A1 · Carter et al. · 2018 [cited by applicant]
US 20180023037A1 · Silvernail et al. · 2018 [cited by applicant]
US 20180208876A1 · Man et al. · 2018 [cited by applicant]
US 20180245019A1 · Kieffer et al. · 2018 [cited by applicant]
US 20190093050A1 · Man et al. · 2019 [cited by applicant]
US 20200123467A1 · Kieffer et al. · 2020 [cited by applicant]
US 20210071108A1 · Kieffer et al. · 2021 [cited by applicant]
US 20220154103A1 · Kieffer et al. · 2022 [cited by applicant]
US 20220266263A1 · Michailovski et al. · 2022 [cited by applicant]
CA 2369064A1 · 2000 [cited by applicant]
CA 2431925C · 2002 [cited by applicant]
CN 104862716A · 2015 [cited by applicant]
CN 107675227A · 2018 [cited by applicant]
CN 107761116A · 2018 [cited by applicant]
DE 2547389A1 · 1977 [cited by applicant]
DE 10100338A1 · 2002 [cited by applicant]
DE 69918694T2 · 2005 [cited by applicant]
EP 1102834B1 · 2004 [cited by applicant]
EP 1550710A1 · 2005 [cited by applicant]
EP 2939263A · 2015 [cited by applicant]
GB 1462134A · 1977 [cited by applicant]
JP S51120050A · 1976 [cited by applicant]
JP 6505044A · 1994 [cited by applicant]
JP H0961349A · 1997 [cited by applicant]
JP 2003336092A · 2003 [cited by applicant]
JP 200491686A · 2004 [cited by applicant]
JP 200716246A · 2007 [cited by applicant]
JP 2009111294A · 2009 [cited by applicant]
JP 2010532240A · 2010 [cited by applicant]
JP 2011208130A · 2011 [cited by applicant]
JP 2012512925A · 2012 [cited by applicant]
JP 2012526890A · 2012 [cited by applicant]
JP 2014156612A · 2014 [cited by applicant]
JP 2014526586A · 2014 [cited by applicant]
JP 2015532337A · 2015 [cited by applicant]
RU 2632874C2 · 2017 [cited by applicant]
WO 8911525A1 · 1989 [cited by applicant]
WO 9103540A1 · 1991 [cited by applicant]
WO 2000008125A1 · 2000 [cited by applicant]
WO 0046327A1 · 2000 [cited by applicant]
WO 2001083879A1 · 2001 [cited by applicant]
WO 2005085321A1 · 2005 [cited by applicant]
WO 2008148420A1 · 2008 [cited by applicant]
WO 2009026956A1 · 2009 [cited by applicant]
WO 2014105765A1 · 2014 [cited by applicant]
WO 2014134826A1 · 2014 [cited by applicant]
WO 2016187293A1 · 2016 [cited by applicant]
WO 2017035006A1 · 2017 [cited by applicant]
BASF, “BASF Industrial Formulators,” BASF Aktiengesellschaft, Data sheet [online], Oct. 6, 2021, 22 pages. [cited by applicant]
BASF, “Lutensol® Surfactants Product Guide,” BASF Aktiengesellschaft, Data sheet [online], 2020, 33 pages. [cited by applicant]
BASF, “Lutensol® TO types,” BASF Aktiengesellschaft, Data sheet [online], Feb. 1997, 15 pages. [cited by applicant]
BASF, “Lutensol® TO types,” BASF Aktiengesellschaft, Data sheet [online], Nov. 2014, Retrieved from the Internet: <URL:www.homecare-and-i-and-i.basf.com>, 9 pages. [cited by applicant]
Dishwasher User Instructions, Datasheet [online], Whirlpool, 2014, 56 pages. [cited by applicant]
Genova C, Schoenkaes U, Smith D, Stolz M. Effect of hydrophobe structure on performance of alcohol ethoxylates. Journal of surfactants and detergents. Oct. 2003; 6:365-72. [cited by applicant]
Varadaraj R, Bock J, Zushma S, Brons N. Relationships between dynamic contact angle and dynamic surface tension properties for linear and branched ethoxylate, ethoxysulfate, and sulfate surfactants. Journal of colloid a… [cited by applicant]
Wikipedia, “Dodecanol,” Wikipedia the Free Encyclopedia, Retrieved from the Internet: <URL:https://en.wikipedia.org/w/index.php?title=Dodecanol&oldid=1216558083>, 3 pages. [cited by applicant]
BASF, “Plurafac LF-221 Alcohol Alkoxylate, Technical Bulletin”, published on Jan. 30, 2002. [cited by applicant]
Dow Personal Care, Kathon CG, “A Safe, Effective, Globally Approved Preservative for Rinse-Off Products” 9 pages, Jun. 2006. [cited by applicant]
International Searching Authority “Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority, or the Declaration” issued in connection with Internati… [cited by applicant]
International Searching Authority “Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority, or the Declaration” issued in connection with Internati… [cited by applicant]
Written Opinion of the International Preliminary Examining Authority, issued in connection with International Application No. PCT/US2016/033067, mailed on May 21, 2017, 4 pages. 2017. [cited by applicant]
European Search Report, “Supplementary European Search Report”, issued in connection to European Application No. 16797217.3, 6 pages mailed Oct. 23, 2018. [cited by applicant]
Ecolab USA Inc., PCT/US2016/033067 filed May 18, 2016, “Written Opinion of the International Preliminary Examining Authority” mailed May 18, 2016. [cited by applicant]
Examiner's search strategy and results for U.S. Appl. No. 16/718,870, 125 pages, entered on Dec. 29, 2020. [cited by applicant]
Lutensol® AO types, Technical Information [online], BASF: The Chemical Company, 2004. Retrieved from the Internet: <URL:https://chemagent.su/prodavtsy/download/176/187/19>, 12 pages. [cited by applicant]
Lutensol® AO types, Technical Information [online], BASF: The Chemical Company, 2014. Retrieved from the Internet: <URL:https://chemical.carytrad.com.tw/uploads/1/2/3/8/123848866/tds_lutensol_ao_types_en.pdf>, 7 pages. [cited by applicant]
Plurafac® LF types, Technical Information [online], BASF: The Chemical Company, 1995. Retrieved from the Internet: <URL:http://www.timing-ouhan.com/images/plurafaclftypes.pdf>, 19 pages. [cited by applicant]
Communication of Notices of Opposition to a European Patent, Patent EP3313967, Application EP16797209.0, Apr. 18, 2024, 1 page. [cited by applicant]
Grounds of Opposition to a European Patent, Patent EP3313967, Application EP16797209.0, Apr. 18, 2024, 24 pages. [cited by applicant]
Communication of Notices of Opposition to a European Patent, Patent EP3298118, Application EP16797217.3, May 17, 2024, 1 page. [cited by applicant]
Grounds of Opposition to a European Patent, Patent EP3298118, Application EP16797217.3, Jun. 5, 2024, 32 pages. [cited by applicant]
Summons to attend oral proceedings pursuant to Rule 115(1) EPC, Patent EP3313967, Application EP16797209.0, Mar. 6, 2025, 13 pages. [cited by applicant]
Summons to attend oral proceedings pursuant to Rule 115(1) EPC, Patent EP3298118, Application EP16797217.3, Mar. 6, 2025, 14 pages. [cited by applicant]
New Summons to attend oral proceedings pursuant to Rule 115(1) EPC, Patent EP3298118, Application EP16797217.3, Apr. 16, 2025, 15 pages. [cited by applicant]