High molecular weight polyacrylates for aluminum protection in warewash applications
A warewashing detergent composition is provided for use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorous containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, high molecular weight polyacrylates (polyacrylic acid homopolymers) with a molecular weight of at least about 5000 are used as corrosion inhibitors and can be included for aluminum protection in a number of different detergent compositions.
1. A detergent composition comprising:
(a) an alkaline source in an amount effective to provide a use composition having a pH of at least about 8 and obtained by diluting the detergent composition with water; and
(b) from about 10 wt. % to about 50 wt. % of a corrosion inhibitor component capable of reducing corrosion of aluminum or aluminum containing alloys, the corrosion inhibitor component comprising one or more polyacrylic acid homopolymers having a molecular weight of at least about 10,000 daltons;
(c) from about 0.5 wt. % to about 20 wt. % of a surfactant;
wherein the composition comprises less than 0.1 wt. % phosphorous, sodium tripolyphosphate, or 1-hydroxy ethylidene 1-1-diphosphonic acid; and
wherein the composition does not include sodium carbonate, and wherein the composition is substantially free of calcium salts.
2. The detergent composition according to claim 1 , wherein the corrosion inhibitor component comprises one or more polyacrylic acid homopolymers having a molecular weight of greater than 50,000 daltons.
3. The detergent composition according to claim 2 , wherein the corrosion inhibitor component comprises one or more polyacrylic acid homopolymers having a molecular weight of 70,000 daltons or greater.
4. The detergent composition according to claim 2 , wherein the corrosion inhibitor component comprises one or more polyacrylic acid homopolymers having a molecular weight of 100,000 daltons or greater.
5. The detergent composition according to claim 1 , wherein the surfactant comprises at least one of an anionic surfactant, a nonionic surfactant, a cationic surfactant, or a zwitterionic surfactant.
6. The detergent composition according to claim 1 , wherein the alkaline source comprises a metal silicate.
7. A method for protecting aluminum or aluminum-containing alloys from corrosion comprising:
(a) providing aluminum or aluminum-containing alloys; and
(b) contacting a surface of the alloys with a use solution of a composition, wherein the composition comprises from about 10 wt. % to about 50 wt. % of a corrosion inhibitor, from about 0.5 wt. % to about 20 wt. % of a surfactant, and an alkaline source in an amount effective to provide a use composition having a pH of at least about 8; wherein the corrosion inhibitor comprises one or more polyacrylic acid homopolymers having a molecular weight of at least about 10,000 daltons, and having less than 0.1 wt. % phosphorous, sodium tripolyphosphate, and 1-hydroxy ethylidene 1-1-diphosphonic acid, and
wherein the composition does not include sodium carbonate and wherein the composition is substantially free of calcium salts.
8. The detergent composition according to claim 1 , further comprising from about 0.01 wt. % to about 60 wt. % of a builder, wherein the builder comprises a polycarboxylate.
9. The detergent composition according to claim 1 , further comprising from about 0.01 wt. % to about 20 wt. % of a stabilizer, wherein the stabilizer comprises primary aliphatic amines, betaines, borate, calcium ions, sodium citrate, citric acid, sodium formate, glycerine, maleonic acid, organic diacids, polyols, and/or propylene glycol.
10. The detergent composition according to claim 1 , further comprising from about 0.01 wt. % to about 20 wt. % of a dispersant, wherein the dispersant comprises maleic acid, olefin copolymers, and/or polyacrylic acid.
11. The detergent composition according to claim 1 , further comprising from about 0.01 wt. % to about 15 wt. % of an enzyme, wherein the enzyme comprises proteases and/or alpha-amylases.
12. The detergent composition according to claim 1 , further comprising from about 0.01 wt. % to about 80 wt. % of one or more additives, wherein the additives comprise chelating/sequestering agents, bleaching agents, hardening agents, solubility modifiers, defoamers, anti-redeposition agents, threshold agents, dyes, and/or perfumes.
13. The detergent composition according to claim 1 , wherein the water is present from about 5 wt. % to about 95 wt. % and the composition is provided in the form of a gel and/or paste.
14. The detergent composition according to claim 1 , wherein the water is present from about 5 wt. % to about 60 wt. % and the composition is provided in the form of a solid.