IP Library Granted Patent US 11,911,728
Granted Patent B2
US 11,911,728 · App. 17/466,206 · Granted Feb 27, 2024

Reactor for reducing nitrogen oxides

Inventors: Wassim Klink (Houston, TX); Guido Seng (The Woodlands, TX); Wenzhong Zhang (Houston, TX); Andreas Klemt (Leuna, DE); Paul Benjerman Himelfarb (Katy, TX)
Assignee: SHELL USA, INC.
B01D53/8631B01D53/8625B01D53/9409B01D53/9431B01J21/16B01J23/22B01J23/28B01J23/30B01J35/04F01N3/2828B01D2255/90B01D2255/9155B01D2255/9205B01D2257/402B01D2257/404
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Quick Facts
Patent No.
US 11,911,728
App. No.
17/466,206
Granted
Feb 27, 2024
Kind
B2
Abstract

A reactor for reducing the concentration of NO x in a stream comprising: an inlet for the stream; an outlet for a stream containing a reduced concentration of NO x ; one or more catalyst beds comprising a ceramic or metallic foam with a NO x reduction catalyst; one or more flow paths from the inlet to the outlet that passes through at least one catalyst bed wherein the catalyst beds are closed at the top and bottom so that the flow path through the catalyst bed passes through the sides of the catalyst bed in a lateral flow is described.

Claims (9)

1. A catalyst for reducing NOx in an exhaust gas comprising:

a ceramic or metallic foam support; and

one or more NOx reduction catalysts disposed on the ceramic or metallic foam support, wherein the one or more NOx reduction catalysts comprises a carrier material and one or more metal compounds disposed on the carrier material, wherein the NOx reduction catalyst has a bimodal pore distribution with more than 90% of a pore volume present in pores having a diameter of at most 100 nanometers (nm), and wherein the pore volume is present in pores having a diameter between approximately 1 nm and approximately 104 nm.

2. The catalyst of claim 1 , wherein a surface area of the one or more NOx reduction catalysts is between 70 square meters/gram (m 2 /g) and 150 m 2 /g as measured by nitrogen adsorption.

3. The catalyst of claim 1 , wherein the ceramic or metallic foam has a void space of at least 60%.

4. The catalyst of claim 1 , wherein the ceramic or metallic foam has from approximately 5 to approximately 50 pores per inch.

5. The catalyst of claim 1 , wherein the ceramic or metallic foam has a density of from approximately 0.4 to approximately 0.75 grams/cubic centimeter (g/cm 3 ).

6. The catalyst of claim 1 , wherein the one or more metal compounds comprises vanadium, molybdenum, tungsten, or mixtures thereof.

7. The catalyst of claim 1 , wherein the carrier material is titania, alumina, silicon-alumina, magnesia-alumina, calcium oxide-alumina, chromium oxide-alumina, or silica-chromium oxide-alumina.

Assignments (2)
CHANGE OF NAME Recorded Nov 20, 2023
From: SHELL OIL COMPANY
To: SHELL USA, INC.
Reel/Frame 065629/0285 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 29, 2021
From: KLINK, WASSIM; SENG, GUIDO; ZHANG, WENZHONG; KLEMT, ANDREAS; HIMELFARB, PAUL BENJERMAN
To: SHELL OIL COMPANY
Reel/Frame 057959/0377 →
Continuity (3)
Continuation 16064200
Provisional Application 62270853 · Dec 22, 2015
Related Publication 20220111334A1 · Apr 14, 2022