IP Library Granted Patent US 11,667,529
Granted Patent B2
US 11,667,529 · App. 17/467,009 · Granted Jun 6, 2023

Carbon nanotube product manufacturing system and method of manufacture thereof

Inventors: Elie Amram Bengio (Houston, TX); Alexander Joseph Marks (Houston, TX)
Assignee: Wootz, Inc.
C01B32/174B29C48/0018B29C48/022B29C48/05B29C48/88B29C48/91D01D5/06D01F1/10D01F9/12B82Y30/00B82Y40/00C01B2202/08
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Quick Facts
Patent No.
US 11,667,529
App. No.
17/467,009
Granted
Jun 6, 2023
Kind
B2
Abstract

A method of manufacturing a carbon nanotube product comprising: blending an unaligned carbon nanotube material with solid solvent particles; activating a nanotube solvent by liquefying the solid solvent particles; producing a nanotube dope solution by mixing the nanotube solvent and the unaligned carbon nanotube material; forming a carbon nanotube proto-product by extruding the nanotube dope solution; and forming an aligned carbon nanotube product by solidifying the carbon nanotube proto-product.

Claims (22)

1. A method of manufacturing a carbon nanotube product, comprising:

mixing an unaligned carbon nanotube material comprising carbon nanotube material with a solvent precursor material;

reacting the solvent precursor material with a solvent activation agent to produce a nanotube solvent;

producing a nanotube dope solution by subjecting the nanotube solvent and the unaligned carbon nanotube material to a homogenization step of mixing;

forming a carbon nanotube proto-product by extruding the nanotube dope solution, thereby imparting alignment to carbon nanotube molecules of the carbon nanotube proto-product; and

forming an aligned carbon nanotube product by solidifying the carbon nanotube proto-product.

2. The method of claim 1 , wherein forming the carbon nanotube proto-product includes extruding the nanotube dope solution as a nanotube filament.

3. The method of claim 1 , wherein forming the carbon nanotube proto-product includes extruding the nanotube dope solution as a nanotube film.

4. The method of claim 1 , wherein the nanotube solvent is chlorosulfonic acid.

5. The method of claim 1 , further comprising, prior to extruding the nanotube dope solution, adding an additional amount of the nanotube solvent in a liquid state to the nanotube dope solution.

6. The method of claim 1 , further comprising removing an amount of the nanotube solvent from the nanotube dope solution through evaporation under co-flow with gaseous hydrochloric acid to prevent degradation of the nanotube solvent.

7. The method of claim 1 , wherein producing the nanotube dope solution includes producing the nanotube dope solution at a concentration between 2% and 20% by weight of the unaligned carbon nanotube material.

8. The method of claim 1 , further comprising fractionating the nanotube dope solution to remove carbon nanotube molecules of the lowest aspect ratio in the nanotube dope solution.

9. The method of claim 1 , wherein forming the aligned carbon nanotube product includes solidifying the carbon nanotube proto-product by exposing the carbon nanotube proto-product to an infrared radiation source.

10. The method of claim 1 , wherein forming the aligned carbon nanotube product includes solidifying the carbon nanotube proto-product by exposing the carbon nanotube proto-product to a chemical coagulant.

11. The method of claim 10 , further comprising thermally annealing the aligned carbon nanotube product to remove an amount of the chemical coagulant from the aligned carbon nanotube product.

12. The method of claim 1 , further comprising drawing the carbon nanotube proto-product to impart further alignment of carbon nanotube molecules in the carbon nanotube proto-product.

13. The method of claim 1 , further comprising doping the aligned carbon nanotube product.

14. The method of claim 1 , further comprising coating the surface of the aligned carbon nanotube product.

15. The method of claim 1 , further comprising integrating of the aligned carbon nanotube product with additional instances of the aligned carbon nanotube product, other materials, or a combination thereof, to produce integrated structures selected from yarns, threads, woven fabrics, laminated films, tape, foam, composite pre-impregnated materials, and discrete length chopped fiber material.

16. The method of claim 1 , further comprising integrating of the aligned carbon nanotube product with additional instances of the aligned carbon nanotube product, other materials, or a combination thereof to produce a component selected from wire antennas, patch antennas, coil transformers, and coaxial cables.

17. The method of claim 1 , wherein the solvent precursor material is phosphorous pentachloride, the solvent activation agent is sulfuric acid, and the nanotube solvent is chlorosulfonic acid.

Assignments (3)
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Aug 15, 2023
From: WOOTZ, INC.
To: KUREHA AMERICA INC.
Reel/Frame 064587/0464 →
CHANGE OF NAME Recorded Apr 28, 2023
From: WOOTZ, LLC
To: WOOTZ, INC.
Reel/Frame 063490/0390 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 25, 2023
From: BENGIO, ELIE AMRAM; MARKS, ALEXANDER JOSEPH
To: WOOTZ, LLC
Reel/Frame 062867/0143 →
Continuity (2)
Division 16152246 · Oct 4, 2018
Related Publication 20220055903A1 · Feb 24, 2022