Coated steel strips, coated stamped products and methods
A pre-coated steel strip is provided. The steel strip includes a strip of base steel having a length, a width, a first side, and a second side. The length of the strip is at least 100 m and the width is at least 600 mm. An aluminum or an aluminum alloy pre-coating is on at least part of at least one of the first or second sides of the strip of base steel. A thickness t p of the pre-coating is from 20 to 33 micrometers at every location on at least one of the first or second sides. Processes, coated stamped products and land motor vehicles are also provided.
1. A method of forming a hot stamped coated steel product, comprising:
providing a precoated steel strip, the precoated steel strip including a base steel having a first side and a second side, and a precoating on at least one of the first side and the second side, the precoating being made of aluminum or an aluminum alloy;
heating the precoated steel strip for 3 to 13 minutes in a furnace pre-heated to between 880° C. and 940° C., wherein the precoated strip experiences a temperature rise at a heating rate (Vc) between 4° and 12° C./s, wherein Vc is a mean heating rate between 20 and 700 C;
removing the heated precoated steel strip from the furnace; and then
hot stamping the precoated strip to deform the precoated steel strip into a hot stamped coated steel product, the hot stamped coated steel product having a coating comprising, proceeding from the base steel outwards:
(a) an Interdiffusion layer,
(b) an Intermediate layer,
(c) an Intermetallic layer, and
(d) a Superficial layer,
wherein layers (a), (b), (c), and (d) each have a different mean composition from one another,
wherein the coating on the hot stamped coated steel product has a thickness greater than 30 micrometers;
wherein the interdiffusion layer has a first mean iron composition, the intermediate layer has a second mean iron composition less than the first mean iron composition; wherein the intermetallic layer has a third mean iron composition, the third mean iron composition less than the first mean iron composition and greater than the second mean iron composition, and the superficial layer has a fourth mean iron composition, the fourth mean iron composition being less than the third mean iron concentration.
2. The method according to claim 1 , further comprising cooling at a rate of more than 30° C./s, wherein the cooling rate is defined as the mean rate between the exit of the heated blank from the furnace, down to 400° C.
3. The method according to claim 2 , wherein an elapsed time between said removing of the heated precoated strip from the furnace and said hot stamping is less than 10 seconds.
4. The method according to claim 2 , wherein the hot stamping includes hot stamping at a strain higher than 10% and wherein the cooling is cooling at a rate higher than 50° C./s to form a fully martensitic hot stamped coated steel product.
5. The method according to claim 4 , wherein an elapsed time between said removing of the heated precoated strip from the furnace and said hot stamping is less than 10 seconds.
6. The method according to claim 1 , wherein less than 10% of layer (c) is present at an extreme surface of the hot stamped coated steel product.
7. The method according to claim 1 , wherein the layers (c) and (d) are quasi continuous by occupying at least 90% of a level corresponding to each said layer.
8. The method according to claim 1 , wherein said layer (a) has a thickness that is less than half of said thickness of the coating.
9. The method according to claim 1 , wherein layer (a) has an HV50g hardness between 290 and 410; layer (b) has an HV50g hardness between 900 and 1000, +/−10%; layer (c) has an HV50g hardness between 580 and 650, +/−10%; and layer (d) has an HV50g harness between 900 and 1000, +/−10%.
10. The method according to claim 1 , wherein said layer (a) has a thickness of 17 micrometers or less.
11. The method according to claim 1 , wherein said layer (a) has a thickness of 15 micrometers or less.
12. The method according to claim 10 , wherein the coating is 40 micrometers thick.
13. The method according to claim 1 , wherein said layer (a) has a thickness less than 10 micrometers.
14. The method according to claim 1 , wherein the base steel of the precoated steel strip consists of the following components by weight based on total weight:
0.15%<carbon<0.5%;
0.5%<manganese<3%;
0.1%<silicon<0.5%;
0.01%<chromium<1%;
titanium<0.2%;
aluminum<0.1%;
phosphorus<0.1%;
sulfur<0.05%;
0.0005%<boron<0.08%;
a remainder being iron and impurities inherent in processing.
15. The method according to claim 1 , wherein the base steel of the precoated steel strip consists of the following components by weight based on total weight:
0.15%<carbon<0.25%,
0.8%<manganese<1.8%,
0.1%<silicon<0.35%,
0.01%<chromium<0.5%,
titanium<0.1%
aluminum<0.1%
phosphorus<0.1%
sulfur<0.05%
0.002%<boron<0.005%,
a remainder being iron and impurities inherent in processing.
16. The method according to claim 1 , wherein a thickness t p of said precoating on the provided precoated steel strip is from 20 to 33 micrometers at every location on at least one of said first and second sides.
17. The method according to claim 1 , wherein a thickness t p of said precoating on the provided precoated steel strip is from 20 to 33 micrometers at every location on both said first and second sides.
18. The method according to claim 1 , wherein said aluminum or aluminum alloy precoating on the provided precoated steel strip is an aluminum alloy precoating comprising from 8% to 11% silicon by weight, from 2% to 4% iron by weight, a remainder being aluminum and impurities inherent in processing.
19. The method according to claim 18 , wherein the aluminum alloy precoating comprises from 9% to 10% silicon by weight.
20. The method according to claim 18 , wherein the aluminum alloy precoating comprises 9.3% silicon by weight.
21. The method according to claim 1 , wherein the Interdiffusion layer comprises the following components by weight based on total weight: 86 to 95% Fe, 4 to 10% Al, and 0 to 5% Si.
22. The method according to claim 21 , wherein the Intermediate layer comprises the following components by weight based on total weight: 39 to 47% Fe, 53 to 61% Al, and 0 to 2% Si.
23. The method according to claim 22 , wherein the Intermetallic layer comprises the following components by weight based on total weight: 62 to 67% Fe, 30 to 34% Al, and 2 to 6% Si.
24. The method according to claim 23 , wherein the Superficial layer comprises the following components by weight based on total weight: 39 to 47% Fe, 53 to 61% Al, and 0 to 2% Si.
25. The method according to claim 1 , wherein the Intermediate layer comprises the following components by weight based on total weight: 39 to 47% Fe, 53 to 61% Al, and 0 to 2% Si.
26. The method according to claim 25 , wherein the Intermetallic layer comprises the following components by weight based on total weight: 62 to 67% Fe, 30 to 34% Al, and 2 to 6% Si.
27. The method according to claim 1 , wherein the hot stamped coated steel product has a mechanical strength in excess of 1000 MPa.
28. The method according to claim 1 , wherein the hot stamped coated steel product has a mechanical strength in excess of 1500 MPa.
29. The method according to claim 1 , wherein the hot stamped coated steel product has a yield strength in excess of 1200 MPa.