Silicone copolymer surface additive
An organic polymeric particle including an optional first monomer comprising a hydrophobic monomer; a second monomer comprising two or more vinyl groups; an optional third monomer comprising an amine; and a vinyl siloxane polymerizable monomer.
1. An organic polymeric particle consisting of:
an optional first monomer comprising a hydrophobic monomer;
a second monomer comprising two or more vinyl groups;
an optional third monomer comprising an amine; and
a vinyl siloxane polymerizable monomer, wherein the vinyl siloxane polymerizable monomer is vinyl terminated silicone-polyether.
2. The organic polymeric particle of claim 1 , wherein the first monomer comprising a hydrophobic monomer is present, and wherein the first monomer comprises a non-fluorinated hydrophobic monomer having a high carbon to oxygen ratio of from about 3 to about 8 or a fluorinated monomer.
3. The organic polymeric particle of claim 1 , wherein the first monomer comprising a hydrophobic monomer is present, and wherein the first monomer comprises an acrylate, a methacrylate, or a cyclohexylmethacrylate.
4. The organic polymeric particle of claim 1 , wherein the first monomer comprising a hydrophobic monomer comprises an aliphatic cycloacrylate selected from a member of the group consisting of cyclohexyl methacrylate, cyclopropyl acrylate, cyclobutyl acrylate, cyclopentyl acrylate, cyclohexyl acrylate, cyclopropyl methacrylate, cyclobutyl methacrylate, cyclopentyl methacrylate, isobornyl methacrylate, and combinations thereof.
5. The organic polymeric particle of claim 1 , wherein the first monomer comprising a hydrophobic monomer comprises a fluorinated acrylate.
6. The organic polymeric particle of claim 1 , wherein the first monomer comprises trifluoroethylmethacrylate.
7. The organic polymeric particle of claim 1 , wherein the second monomer is selected from a member of the group consisting of diethyleneglycol diacrylate, triethyleneglycol diacrylate, tetraethyleneglycol diacrylate, polyethyleneglycol diacrylate, 1,6-hexanediol diacrylate, neopentylglycol diacrylate, tripropyleneglycol diacrylate, polypropyleneglycol diacrylate, 2,2′,-bis(4-(acryloxy/diethoxy)phenyl)propane, trimethylolpropane triacrylate, tetramethylolmethane tetraacrylate, ethyleneglycol dimethacrylate, diethyleneglycol dimethacrylate, triethyleneglycol dimethacrylate, tetraethyleneglycol dimethacrylate, polyethyleneglycol dimethacrylate, 1,3-butyleneglycol dimethacrylate, 1,6-hexanediol dimethacrylate, neopentylglycol dimethacrylate, polypropyleneglycol dimethacrylate, 2,2′,-bis(4-(methacryloxy/diethoxy)phenyl)propane, 2,2′,-bis(4-(methacryloxy/polyethoxy)phenyl)propane, trimethylolpropane trimethacrylate, tetramethylolmethane tetramethacrylate, divinyl benzene, divinyl naphthalene, divinyl ether, and combinations thereof.
8. The organic polymeric particle of claim 1 , wherein the second monomer is divinyl benzene.
9. The organic polymeric particle of claim 1 , wherein the optional third monomer is present, and wherein the third monomer is selected from a member of the group consisting of dimethylaminoethyl methacrylate, diethylaminoethyl methacrylate, dipropylaminoethyl methacrylate, diisopropylaminoethyl methacrylate, dibutylaminoethyl methacrylate, and combinations thereof.
10. The organic polymeric particle of claim 1 , wherein the hydrophobic monomer is cyclohexyl methacrylate; and wherein the second monomer is divinyl benzene; and wherein the third monomer is dimethylaminoethyl methacrylate.
11. A toner composition comprising:
at least one resin, an optional colorant, an optional wax, and an organic polymeric particle toner additive on at least a portion of an external surface of the toner particles, the particulate organic polymeric particle toner additive consisting of:
an optional first monomer comprising a hydrophobic monomer;
a second monomer comprising two or more vinyl groups;
an optional third monomer comprising an amine; and
a vinyl siloxane polymerizable monomer, wherein the vinyl siloxane polymerizable monomer is vinyl terminated silicone-polyether.
12. The toner composition of claim 11 , wherein the first monomer of the particulate organic polymeric particle toner additive comprising a hydrophobic monomer is present, and wherein the first monomer comprises a non-fluorinated hydrophobic monomer having a high carbon to oxygen ratio of from about 3 to about 8 or a fluorinated monomer.
13. The toner composition of claim 11 , wherein the first monomer of the particulate organic polymeric particle toner additive comprising a hydrophobic monomer is present, and wherein the first monomer comprises an acrylate, a methacrylate, or a cyclohexylmethacrylate.
14. The toner composition of claim 11 , wherein the first monomer of the particulate organic polymeric particle toner additive comprising a hydrophobic monomer comprises an aliphatic cycloacrylate selected from the group consisting of cyclohexyl methacrylate, cyclopropyl acrylate, cyclobutyl acrylate, cyclopentyl acrylate, cyclohexyl acrylate, cyclopropyl methacrylate, cyclobutyl methacrylate, cyclopentyl methacrylate, isobornyl methacrylate, and combinations thereof.
15. The toner composition of claim 11 , wherein the second monomer of the particulate organic polymeric particle toner additive is divinyl benzene.
16. The toner composition of claim 11 , wherein the optional third monomer of the particulate organic polymeric particle toner additive is present, and wherein the third monomer is selected from a member of the group consisting of dimethylaminoethyl methacrylate, diethylaminoethyl methacrylate, dipropylaminoethyl methacrylate, diisopropylaminoethyl methacrylate, dibutylaminoethyl methacrylate, and combinations thereof.
17. The toner composition of claim 11 , wherein the hydrophobic monomer of the particulate organic polymeric particle toner additive is cyclohexyl methacrylate; and wherein the second monomer of the particulate organic polymeric particle toner additive is divinyl benzene; and wherein the third monomer of the particulate organic polymeric particle toner additive is dimethylaminoethyl methacrylate.
18. A developer comprising:
a toner composition, and a toner carrier;
wherein the toner composition comprises:
toner particles comprising at least one resin, an optional colorant, an optional wax, and an organic polymeric particle toner additive on at least a portion of an external surface of the toner particles, the organic polymeric particle toner additive consisting of:
an optional first monomer comprising a hydrophobic monomer;
a second monomer comprising two or more vinyl groups;
an optional third monomer comprising an amine; and
a vinyl siloxane polymerizable monomer, wherein the vinyl siloxane polymerizable monomer is vinyl terminated silicone-polyether.
19. The toner composition of claim 11 , wherein the vinyl siloxane polymerizable monomer comprises 1% polydimethylsiloxane with vinyl termination.