IP Library Granted Patent US 12,589,578
Granted Patent B2
US 12,589,578 · App. 17/518,410 · Granted Mar 31, 2026

Ultrathin graphene/polymer laminate films

Inventors: Michael Stadermann (Pleasanton, CA); Patrick Campbell (Oakland, CA); Philip E. Miller (Livermore, CA); Chantel Aracne-Ruddle (Livermore, CA); Sung Ho Kim (Livermore, CA); Francisco J. Espinosa-Loza (Bellevue, WA)
Assignee: Lawrence Livermore National Security, LLC
B32B27/06B05D1/20B29D99/005B32B9/007B32B18/00B32B37/14C01B32/184C01B32/194B05D2201/02B05D2401/20B32B2037/246B32B2309/105B32B2313/04Y10T428/30
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Quick Facts
Patent No.
US 12,589,578
App. No.
17/518,410
Granted
Mar 31, 2026
Kind
B2
Abstract

A process includes layering a graphene layer onto a polymer layer to form a composite film.

Claims (23)

1 . A process, comprising:

layering a graphene layer onto a first side of a preexisting polymer layer; and

layering a second graphene layer directly onto a second side of the preexisting polymer layer for forming a composite structure consisting of the graphene layer, the second graphene layer, and the preexisting polymer layer.

2 . A process, comprising:

layering a graphene layer onto a first side of a polymer layer; and

layering a second graphene layer directly onto a second side of the polymer layer for forming a composite structure consisting of the graphene layer, the second graphene layer, and the polymer layer,

wherein the layering is performed in a solution.

3 . The process of claim 2 , wherein the graphene layer floats on the solution, wherein the layering includes causing the polymer layer to lift the graphene layer from the solution.

4 . The process of claim 2 , wherein the solution has a neutral pH.

5 . The process of claim 1 , further comprising, layering a third graphene layer onto the graphene layer or the second graphene layer of the composite structure.

6 . The process of claim 1 , further comprising coupling a third graphene layer to the composite structure.

7 . The process of claim 1 , further comprising coupling a second polymer layer to the composite structure.

8 . The process of claim 1 , wherein the graphene layer includes several layers of graphene.

9 . The process of claim 1 , wherein the graphene layer is a single layer of graphene.

10 . The process of claim 1 , wherein the graphene layer includes islands of graphene held together by van der Waals forces.

11 . The process of claim 1 , wherein the graphene layer covers an entire side of the preexisting polymer layer.

12 . The process of claim 2 , wherein the solution forms a meniscus around the graphene layer.

13 . The process of claim 2 , wherein the solution includes water.

14 . The process of claim 2 , wherein the solution is water.

15 . The process of claim 1 , wherein a method of forming the graphene layer comprises:

forming the graphene layer on a substrate, and

separating the graphene layer from the substrate.

16 . The process of claim 15 , wherein the graphene layer is formed with a metal catalyst, wherein the separating includes adding a metal etchant to the graphene layer on the substrate for separating the graphene layer from the substrate.

Assignments (2)
CONFIRMATORY LICENSE Recorded Dec 8, 2021
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC.
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 058382/0479 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 11, 2021
From: STADERMANN, MICHAEL; CAMPBELL, PATRICK; MILLER, PHILIP E.; ARACNE-RUDDLE, CHANTEL; KIM, SUNG HO; ESPINOSA-LOZA, FRANCISCO J.
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 058089/0535 →
Continuity (2)
Continuation 15698473 · Sep 7, 2017
Related Publication 20220055356A1 · Feb 24, 2022
References Cited (7)
US 20120070612A1 · Lee · 2012 [cited by examiner]
US 20120255899A1 · Choi · 2012 [cited by examiner]
US 20120301707A1 · Kinloch · 2012 [cited by examiner]
US 20180342586A1 · Kireev · 2018 [cited by examiner]
Vlassiouk et al. (ACS Appl Mater Interfaces 2015, 7, 10702-10709) (Year: 2015). [cited by examiner]
Narayan et al. (Nano Convergence 2015, 2:20 (Year: 2015). [cited by examiner]
Martins et al. PNAS Oct. 29, 2013, vol. 110, No. 44, pp. 17762-17767. (Year: 2013). [cited by examiner]