Biodegradable polymeric material, biodegradable products and methods of manufacture and use therefor
The invention encompasses biodegradable compositions (e.g., biodegradable plastics) and methods of preparation and use thereof, and disposable products made from the claimed compositions. Raw materials for preparing the biodegradable plastic include one or more polymers, fiber, starch, a plasticizer, and a coupling agent. The biodegradable composition has the advantages of short degradation cycle, good mechanical properties, and a low manufacturing cost.
1. A biodegradable composition comprising:
(i) about 50-60% (w/w) of a polymer comprising one or more of biodegradable polyesters;
(ii) about 5-15% (w/w) of starch;
(iii) about 20-40% (w/w) of one or more of inorganic filler; and
(iv) about 0.1-10% (w/w) of fiber comprising one or more of biomass,
wherein the composition exhibits a 90% disintegration completion within about 180 to about 365 days in soil.
2. The biodegradable composition of claim 1 , further comprising one or more of the following additives: (i) a plasticizer in an amount of from about 0.1 to about 5% (w/w); (ii) a coupling agent in an amount of from about 0.1 to about 10% (w/w); (iii) a compatibilizer in an amount of from about 0.1 to about 10% (w/w); (iv) an impact modifier in an amount of about 0.1 to about 30% (w/w), (v) a chain extender in an amount of about 0.1 to about 10% (w/w), (vi) lubricant in an amount of about 0.1 to about 10% (w/w), (vii) a stabilizer in an amount of about 0.1 to about 10% (w/w), (viii) toner in an amount of about 0.1 to about 10% (w/w), or (ix) pigment in an amount of about 0.1 to about 10% (w/w), or combinations thereof.
3. The biodegradable composition of claim 1 , wherein composition exhibits a disintegration onset within 7 days, on average.
4. The biodegradable composition of claim 1 , wherein composition exhibits a bio-based carbon content of more than 50%.
5. The biodegradable composition of claim 1 , wherein composition exhibits a 1% secant flexural modulus of greater than 1000 MPa.
6. The biodegradable composition of claim 1 , wherein composition exhibits a flexural stress of greater than 30 MPa.
7. The biodegradable composition of claim 1 , wherein composition exhibits a notched Izod energy of more than 30 J/m.
8. The biodegradable composition of claim 1 , wherein composition exhibits a melt flow index or melt flow rate of greater than 10 g/10 min.
9. The biodegradable composition of claim 2 , wherein composition exhibits a melt flow index or melt flow rate of less than 10 g/10 min.
10. The biodegradable composition of claim 1 , wherein the polymer is one or more of biodegradable polyester is polylactic acid, polycaprolactone, polybutylene succinate, polybutylene succinate adipate, polybutylene succinate terephthalate, polybutylene adipate terephthalate, or polyhydroxyalkanoates.
11. The biodegradable composition of claim 1 , wherein the starch is in native form or modified form including but not limited to thermoplastic starch.
12. The biodegradable composition of claim 1 , wherein the biomass comprises vinasse, vinegar residues, wood fiber, agricultural cellulosic matter from including straw, stalk, shive, hurd, bast, leaf, seed, fruit, and perennial grass, all in a non-continuous non-woven form including chopped pieces, particulates, dust or flour.
13. The biodegradable composition of claim 1 , wherein the inorganic filler includes, but is not limited to, wollastonite, mica, clay, calcium carbonate, glass fiber, talc, aluminum silicate, zirconium oxide, and gypsum.
14. The biodegradable composition of claim 2 , wherein the plasticizer includes, but is not limited to, glycerin, ethylene glycol, xylitol, virgin or epoxidized vegetable oils and natural waxes.
15. The biodegradable composition of claim 2 , wherein the coupling agent or compatibilizer includes, but is not limited to, titanate, aluminate, γ-aminopropyltriethoxysilane, γ-(2,3)epoxy (propoxy)propyltrimethoxysilane and γ-methacryloxypropyltrimethoxysilane.
16. The biodegradable composition of claim 2 , wherein the toner or pigment is fluorescent brightener or titanium dioxide.
17. A method for preparing the biodegradable composition of claim 2 comprising the following steps:
a) plasticizing the starch with a plasticizer;
b) mixing uniformly with other raw materials of the biodegradable composition to prepare a premix;
c) mixing the premix thoroughly at higher than ambient temperatures to prepare the biodegradable composition.
18. A method for preparing the biodegradable composition of claim 1 comprising the following steps:
a) mixing uniformly all materials of the biodegradable composition to prepare a premix, and then
b) mixing the premix thoroughly at higher than ambient temperatures to prepare the biodegradable composition.
19. A method for preparing the biodegradable composition of claim 2 comprising the following steps:
a) feeding all materials of the biodegradable composition, individually or premixed with some other materials of the biodegradable composition, simultaneously into a mixer through more than one feeder
b) mixing all materials of the biodegradable composition thoroughly at higher than ambient temperatures to prepare the biodegradable composition.
20. The method of claim 19 , further comprising forming rigid parts using conventional polymer processing techniques comprising injection molding, compression molding, blow molding and extrusion molding.
21. The method of claim 19 , further comprising forming thin sheets or films using conventional polymer processing techniques comprising hot press, vacuum forming, cast extrusion, film blowing, or compression molding.
22. A disposable product, comprising the biodegradable composition of claim 1 , wherein the disposable product is packing material or a consumer product.