Multilayer films, methods of manufacture thereof and articles comprising the same
Disclosed herein is a multilayered article comprising a core layer comprising a thermoplastic polymer; where the thermoplastic polymer comprises a polyolefin, thermoplastic starch, and a compatibilizer; where the compatibilizer does not contain ethylene acrylic acid; where the polyolefin is not polypropylene and where the polyolefin present in an amount of greater than 40 wt %, based on a total weight of the core layer; a first layer comprising a thermoplastic resin; and a second layer comprising a thermoplastic resin; where the first layer and the second layer are devoid of fillers; where the first layer is disposed on a side of the core layer that is opposed to the side that contacts the second layer; where the multilayered article has an optical clarity of greater than 80% when measured as per ASTM D 1746 and a total haze less than 8% when measured as per ASTM D 1003.
1. A multilayered article comprising:
a core layer comprising a thermoplastic polymer; where the thermoplastic polymer comprises a polyolefin, thermoplastic starch, and a compatibilizer; where the compatibilizer does not contain ethylene acrylic acid; where the polyolefin is not polypropylene and where the polyolefin is present in an amount of greater than 40 wt %, based on a total weight of the core layer;
a first layer comprising a thermoplastic resin; and
a second layer comprising a thermoplastic resin; where the first layer and the second layer are devoid of fillers; where the first layer is disposed on a side of the core layer that is opposed to the side that contacts the second layer; where the multilayered article has an optical clarity of greater than 80% when measured as per ASTM D 1746 and a total haze less than 10% when measured as per ASTM D 1003; where the article displays a machine direction Elmendorf tear strength of 400 to 900 grams when measured as per ASTM D1922; a cross machine direction Elmendorf tear strength of 750 to 1200 grams when measured as per ASTM D1922; and a dart impact strength measured as per ASTM D1709 is 200 to 450 grams.
2. The multilayered article of claim 1 , where the thermoplastic starch comprises wheat starch.
3. The multilayered article of claim 1 , where the polyolefin is linear low density polyethylene having a density of 0.905 g/cm 3 to 0.940 g/cm 3 .
4. The multilayered article of claim 3 , where the linear low density polyethylene is present in an amount of 50 to 75 wt %, based on the total weight of the core layer.
5. The multilayered article of claim 1 , where the compatibilizer is present in an amount of less than 10 wt %, based on the total weight of the core layer.
6. The multilayered article of claim 1 , where the first layer and the second layer comprise a linear low density polyethylene.
7. The multilayered article of claim 1 , where the core layer comprises 2 to 20 wt % of the thermoplastic starch.
8. The multilayered article of claim 1 , where the article displays a 1% secant modulus of 135 to 200 MPa when measured in the machine direction and a 1% secant modulus of 130 to 190 MPa when measured in the transverse direction, when measured as per ASTM D882.