Nanodiamond dispersion composition
Provided is a nanodiamond dispersion composition having excellent dispersibility of nanodiamond particles in an organic dispersion medium even when the organic dispersion medium has a small SP value. The nanodiamond dispersion composition according to an embodiment of the present invention includes an organic dispersion medium, nanodiamond particles dispersed in the organic dispersion medium, and a fatty acid ester dispersing agent. The fatty acid ester dispersing agent preferably has a mass loss rate of 20% or less when held in an air atmosphere at a temperature of 200° C. for 180 minutes. The fatty acid ester dispersing agent preferably has an acid value of 40 mgKOH/g or less.
1. A nanodiamond dispersion composition comprising:
an organic dispersion medium;
a nanodiamond particle dispersed in the organic dispersion medium; and
a fatty acid ester dispersing agent, wherein an average molecular weight Mp of the fatty acid ester dispersing agent is from 5,100 to 8,200, wherein the nanodiamond particle includes a surface-modified nanodiamond.
2. The nanodiamond dispersion composition according to claim 1 , wherein the fatty acid ester dispersing agent has a mass loss rate of 20% or less when the fatty acid ester dispersing agent is held in an air atmosphere at a temperature of 200° C. for 180 minutes.
3. The nanodiamond dispersion composition according to claim 1 , wherein the fatty acid ester dispersing agent has an acid value of 40 mgKOH/g or less.
4. The nanodiamond dispersion composition according to claim 1 , wherein the nanodiamond particle has an average dispersed particle size from 2 to 240 nm.
5. The nanodiamond dispersion composition according to claim 1 , having a haze value of 5 or less.
6. The nanodiamond dispersion composition according to claim 1 , wherein the organic dispersion medium has a SP value from 6.0 to 12.0 (cal/cm 3 ) 1/2 .
7. The nanodiamond dispersion composition according to claim 1 , having a viscosity from 0.2 to 120 mPa's at 25° C.
8. The nanodiamond dispersion composition according to claim 1 , wherein a content ratio of the nanodiamond particles is from 0.01 to 5.0 mass %.
9. The nanodiamond dispersion composition according to claim 1 , wherein the surface-modified nanodiamond is a nanodiamond particle of which surface is modified by a group represented by Formula (I):
—X—R (I)
where in Formula (I), X represents —Si—, —NH—, —O—, —O—C(═O)—, —C(═O)—O—, —NH—C(═O)—, —C(═O)—NH—, or —S—, and a bond extending left from X binds to the nanodiamond particle; and
R represents a monovalent organic group, and an atom that binds to X is a carbon atom.
10. The nanodiamond dispersion composition according to claim 9 , wherein X in Formula (I) represents —Si—, —NH—, —O—, or —O—C(═O)—.
11. The nanodiamond dispersion composition according to claim 9 , wherein a number of carbon atoms in the monovalent organic group is from 4 to 25.
12. The nanodiamond dispersion composition according to claim 9 , wherein in Formula (I), X is —NH—, and R is a monovalent organic group containing from 8 to 20 carbon atoms.
13. The nanodiamond dispersion composition according to claim 9 , wherein in Formula (I), X is —NH—, and R is a monovalent organic group containing a hydrocarbon group having 4 or more carbon atoms in a straight chain.
14. The nanodiamond dispersion composition according to claim 9 , wherein in Formula (I), R includes a hydrocarbon group having 4 or more carbon atoms in a straight chain.
15. The nanodiamond dispersion composition according to claim 9 , wherein the surface-modified nanodiamond particle is surface-modified by a compound containing an organic group or a functional group containing an organic group.
16. The nanodiamond dispersion composition according to claim 9 , wherein the organic group is an organic group having 4 or more carbons.
17. The nanodiamond dispersion composition according to claim 1 , wherein the fatty acid ester dispersing agent has an amine value of 5 mgKOH/g or less.
18. The nanodiamond dispersion composition according to claim 1 , wherein a content of the fatty acid ester dispersing agent with respect to 100 parts by mass of a total amount of the nanodiamond particle in the nanodiamond dispersion composition is from 10 to 10000 parts by mass.
19. The nanodiamond dispersion composition according to claim 1 , wherein a content ratio of the fatty acid ester dispersing agent with respect to a total amount of a dispersing agent contained in the nanodiamond dispersion composition is 90 mass % or greater.