Granted Patent
B2
US 12,218,348 · App. 17/606,354 · Granted Feb 4, 2025
Expanded hydrated vanadate
Assignee:
University of Washington
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Abstract
The present disclosure generally relates to cation-stabilized expanded hydrated vanadates, electrodes made therefrom, and batteries incorporating cathodes made from the cation-stabilized expanded hydrated vanadate.
Claims (22)
1. A composition comprising a cationically stabilized vanadate hydrate having the chemical formula M x V 2 O 5 ·nH 2 O, wherein M is a cation and having a structure defined by layers of vanadium oxide separated by the cation and water, which provide spacing and stabilization between the layers, wherein the cationically stabilized vanadate hydrate has a greater interplanar spacing when compared to a vanadate hydrate formed by the same method but without the cation, and wherein the interplanar spacing is about 12.9 Å.
2. The composition of claim 1 , wherein the cationically stabilized vanadate hydrate is present predominantly in a single phase.
3. The composition of claim 1 , wherein the cationically stabilized vanadate hydrate is structurally and thermally more stable when compared to a vanadate hydrate formed by the same method but without the cation.
4. The composition of claim 1 , wherein the cationic stabilization results from an inclusion of a cation of optimal ionic radius selected from the group of manganese, chromium, titanium, scandium, iron, copper, nickel, cobalt, zinc, yttrium, zirconium, niobium, cadmium, aluminum, magnesium, potassium, calcium, sodium, and combinations thereof.
5. The composition of claim 1 , wherein the cationic stabilization results from an inclusion of a cation selected from the group of calcium, magnesium, potassium, aluminum, manganese, iron, cobalt, nickel, copper, zinc, and combinations thereof.
6. The composition of claim 1 , wherein M is a Mn (II) cation.
7. The composition of claim 1 , wherein the cation is bonded to the vanadium oxide.
8. An electrode comprising a composition according to claim 1 .
9. The electrode of claim 8 , wherein the electrode is configured for use in a battery.
10. The electrode of claim 9 , wherein the battery is multivalent-ion battery.
11. The electrode of claim 10 , wherein the battery is an aqueous zinc-ion battery.
12. The electrode of claim 8 , wherein the specific capacity is 250 mAh/g at a current density of 0.5 A/g or greater.
13. The electrode of claim 8 , wherein the electrode is configured for use in a supercapacitor.
14. An aqueous battery comprising a cathode, the cathode comprising:
a cationically stabilized vanadate hydrate having a structure defined by layers of vanadium oxide separated by a cation and water, which provide spacing and stabilization between the layers,
wherein the cathode comprises the chemical formula M x V 2 O 5 ·nH 2 O, wherein M is Mn (II),
wherein the specific capacity is 400 mAh/g at a current density of 0.05 A/g or greater, and
wherein the battery has a capacity retention of 80% or greater.
15. The aqueous battery of claim 14 , wherein the aqueous battery is multivalent-ion battery.
16. The aqueous battery of claim 15 , wherein the battery is an aqueous zinc-ion battery.
17. The aqueous battery of claim 14 , wherein the battery has a shelf life of 50 days or greater.
18. The aqueous battery of claim 14 , wherein the battery has an energy efficiency of 70% or greater.
Assignments (2)
CONFIRMATORY LICENSE
Recorded Jun 18, 2025
From: UNIVERSITY OF WASHINGTON
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 071679/0638 →
ASSIGNMENT OF ASSIGNOR'S INTEREST
Recorded Dec 28, 2021
From: CAO, GUOZHONG; LIU, CHAOFENG
To: UNIVERSITY OF WASHINGTON
Reel/Frame 058489/0492 →
Continuity (2)
Provisional Application
62848458
· May 15, 2019
References Cited (248)
US 5225297A
· Garcia-Alvarado
· 1993
[cited by applicant]
US 5336572A
· Koksbang
· 1994
[cited by applicant]
US 6322927B1
· Pistoia
· 2001
[cited by applicant]
US 9077032B2
· Doe
· 2015
[cited by applicant]
US 9997778B2
· Cao
· 2018
[cited by applicant]
CN 103730630A
· 2014
[cited by applicant]
CN 107221716A
· 2017
[cited by applicant]
WO 2002030824A1
· 2002
[cited by applicant]
WO 2012051280A2
· 2012
[cited by applicant]
WO 2016197236A1
· 2016
[cited by applicant]
Liu et al. “Expanded hydrated vanadate for high-performance aqueous zinc-ion batteries” Energy Environ. Sci., 2019, 12, 2273 (Year: 2019).
[cited by examiner]
Maitra et al. “A Mesoporous High-Performance Supercapacitor Electrode . . . ” Ind. Eng. Chem. Res. 2017, 56, 2444-2457. (Year: 2017).
[cited by examiner]
Deng et al. “Manganese ion pre-intercalated hydrated vanadium oxide as high-performance cathode for magnesium ion batteries” J. Mater. Chem. A, 2019,7, 10644-10650. . (Year: 2019).
[cited by examiner]
Abundance of Elements in Earth's Crust. Wikipedia. <https://en.wikipedia.org/wiki/Abundance_of_elements_in_Earth%27s_crust.> [Retrieved Nov. 2, 2021], 4 pages.
[cited by applicant]
Al Salem, Hesham, et al. “Electrocatalytic polysulfide traps for controlling redox shuttle process of Li—S batteries.” Journal of the American Chemical Society 137.36 (2015): 11542-11545.
[cited by applicant]
Alfaruqi, Muhammad H., et al. “Electrochemical zinc intercalation in lithium vanadium oxide: a high-capacity zinc-ion battery cathode.” Chemistry of Materials 29.4 (2017): 1684-1694.
[cited by applicant]
Aminzadeh, A., and H. Sarikhani-Fard. “Raman spectroscopic study of Ni/Al2O3 catalyst.” Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 55.7-8 (1999): 1421-1425.
[cited by applicant]
An, Q. et al., Graphene decorated vanadium oxide nanowire aerogel for long-cycle-life magnesium battery cathodes, Nano Energy 18 (2015) 265-272.
[cited by applicant]
Armand, Michel, and J-M. Tarascon. “Building better batteries.” nature 451.7179 (2008): 652-657.
[cited by applicant]
Augustyn, Veronica, et al. “High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance.” Nature materials 12.6 (2013): 518-522.
[cited by applicant]
Augustyn, Veronica, Patrice Simon, and Bruce Dunn. “Pseudocapacitive oxide materials for high-rate electrochemical energy storage.” Energy & Environmental Science 7.5 (2014): 1597-1614.
[cited by applicant]
Avansi, W. et al., Local structure study of vanadium pentoxide, J Nanopart Res 13 (2011) 4937-4946.
[cited by applicant]
Bacewicz, R. et al., A XANES study of the valence state of vanadium in lithium vanadate phosphate glasses, J. Mater. Sci. 40 (2005) 4267-4270.
[cited by applicant]
Baddour-Hadjean, Rita, et al. “The Raman spectrum of the γ′-V2O5 polymorph: a combined experimental and DFT study.” Journal of Raman Spectroscopy 46.4 (2015): 406-412.
[cited by applicant]
Bai, M.-H. et al., Electrochemical codeposition of vanadium oxide and polypyrrole for high-performance supercapacitor with high working voltage, ACS Appl. Mater. Interfaces, 6(15) (2014) 12656-12664.
[cited by applicant]
Barreca, Davide, Alberto Gasparotto, and Eugenio Tondello. “CVD Cu2O and CuO nanosystems characterized by XPS.” Surface Science Spectra 14.1 (2007): 41-51.
[cited by applicant]
Bi, Wenchao, et al. “Gradient oxygen vacancies in V2O5/PEDOT nanocables for high-performance supercapacitors.” ACS Applied Energy Materials 2.1 (2019): 668-677.
[cited by applicant]
Bi, Wenchao, et al. “Tailoring energy and power density through controlling the concentration of oxygen vacancies in V2O5/PEDOT nanocable-based supercapacitors.” ACS applied materials & interfaces 11.18 (2019): 16647-16…
[cited by applicant]
Bose, S. et al., Carbon-based nanostructured materials and their composites as supercapacitor electrodes, Journal of Materials Chemistry, (2012) 767-784. doi:10.1039/c1jm14468e.
[cited by applicant]
Boukhalfa, Sofiane, Kara Evanoff, and Gleb Yushin. “Atomic layer deposition of vanadium oxide on carbon nanotubes for high-power supercapacitor electrodes.” Energy & Environmental Science 5.5 (2012): 6872-6879.
[cited by applicant]
Burdyukh, S. V., et al. “Effect of hydrogenation on the optical properties and internal electrochromism in vanadium bentoxide xerogel films.” Thin Solid Films 656 (2018): 22-29.
[cited by applicant]
Cai, Yangsheng, et al. “Pilotaxitic Na1. 1V3O7. 9 nanoribbons/graphene as high-performance sodium ion battery and aqueous zinc ion battery cathode.” Energy Storage Materials 13 (2018): 168-174.
[cited by applicant]
Callister, W. D., Fundamentals of Materials Science and Engineering, John Wiley & Sons, Inc, 2001.
[cited by applicant]
Canepa, Pieremanuele, et al. “Odyssey of multivalent cathode materials: open questions and future challenges.” Chemical reviews 117.5 (2017): 4287-4341.
[cited by applicant]
Cano, Zachary P., et al. “Batteries and fuel cells for emerging electric vehicle markets.” Nature Energy 3.4 (2018): 279-289.
[cited by applicant]
Chae, Munseok S., et al. “Electrochemical zinc-ion intercalation properties and crystal structures of ZnMo6S8 and Zn2Mo6S8 chevrel phases in aqueous electrolytes.” Inorganic chemistry 55.7 (2016): 3294-3301.
[cited by applicant]
Chakraborty, Tanushree, et al. “Microscopic distribution of metal dopants and anion vacancies in Fe-doped BaTiO3-δ single crystals.” Journal of Physics: Condensed Matter 25.23 (2013): 236002.
[cited by applicant]
Chamoun, Mylad, et al. “Rechargeability of aqueous sulfate Zn/MnO2 batteries enhanced by accessible Mn2+ ions.” Energy Storage Materials 15 (2018): 351-360.
[cited by applicant]
Chao, Dongliang, et al. “A high-rate and stable quasi-solid-state zinc-ion battery with novel 2D layered zinc orthovanadate array.” Advanced Materials 30.32 (2018): 1803181.
[cited by applicant]
Chao, D. et al., An electrolytic Zn—MnO2 battery demonstrated for high-voltage and scalable energy storage, Angew. Chem. Int. Ed. 2019, 58, pp. 7823-7828.
[cited by applicant]
Chen, Dong, et al. “Persistent zinc-ion storage in mass-produced V2O5 architectures.” Nano Energy 60 (2019): 171-178.
[cited by applicant]
Chen, Lineng, et al. “Ultrastable and high-performance Zn/VO2 battery based on a reversible single-phase reaction.” Chemistry of Materials 31.3 (2019): 699-706.
[cited by applicant]
Cheng, Yingwen, et al. “Highly reversible zinc-ion intercalation into chevrel phase Mo6S8 nanocubes and applications for advanced zinc-ion batteries.” ACS applied materials & interfaces 8.22 (2016): 13673-13677.
[cited by applicant]
Chu, Steven, Yi Cui, and Nian Liu. “The path towards sustainable energy.” Nature materials 16.1 (2017): 16-22.
[cited by applicant]
Chung, Sheng-Heng, and Arumugam Manthiram. “Lithium-sulfur batteries with the lowest self-discharge and the longest shelf life.” ACS Energy Letters 2.5 (2017): 1056-1061.
[cited by applicant]
Copper. X-ray Photoelectron Spectroscopy (XPS) Reference Pages,<http://www.xpsfitting.com/2012/01/copper.html> [retrieved Nov. 2, 2021], 3 pages.
[cited by applicant]
Crabtree, George. “Perspective: The energy-storage revolution.” Nature 526.7575 (2015): S92-S92.
[cited by applicant]
Dai, Xi, et al. “Freestanding graphene/VO2 composite films for highly stable aqueous Zn-ion batteries with superior rate performance.” Energy Storage Materials 17 (2019): 143-150.
[cited by applicant]
Dees, Dennis W., et al. “Analysis of the Galvanostatic Intermittent Titration Technique (GITT) as applied to a lithium-ion porous electrode.” Journal of Power Sources 189.1 (2009): 263-268.
[cited by applicant]
Demeter, M., M. Neumann, and W. J. S. S. Reichelt. “Mixed-valence vanadium oxides studied by XPS.” Surface Science 454 (2000): 41-44.
[cited by applicant]
Deng, X. et al. Manganese ion pre-intercalated hydrated vanadium oxide as a high-performance cathode for magnesium ion batteries. Journal of Materials Chemistry A. 7, 2019, 10644-10650.
[cited by applicant]
Deng, Yilin, et al. “In situ Raman spectroscopy of copper and copper oxide surfaces during electrochemical oxygen evolution reaction: identification of CuIII oxides as catalytically active species.” ACS Catalysis 6.4 (2…
[cited by applicant]
Ding, Junwei, et al. “Ultrafast Zn2+ intercalation and deintercalation in vanadium dioxide.” Advanced Materials 30.26 (2018): 1800762.
[cited by applicant]
Dong, Liubing, et al. “Extremely safe, high-rate and ultralong-life zinc-ion hybrid supercapacitors.” Energy Storage Materials 13 (2018): 96-102.
[cited by applicant]
Dunn, Bruce, Haresh Kamath, and Jean-Marie Tarascon. “Electrical energy storage for the grid: a battery of choices.” Science 334.6058 (2011): 928-935.
[cited by applicant]
Fang, Guozhao, et al. “Recent advances in aqueous zinc-ion batteries.” ACS Energy Letters 3.10 (2018): 2480-2501.
[cited by applicant]
Fang, Guozhao, et al. “Suppressing manganese dissolution in potassium manganate with rich oxygen defects engaged high-energy-density and durable aqueous zinc-ion battery.” Advanced Functional Materials 29.15 (2019): 180…
[cited by applicant]
Fang, Guozhao, et al. “Facile synthesis of potassium vanadate cathode material with superior cycling stability for lithium ion batteries.” Journal of Power Sources 275 (2015): 694-701.
[cited by applicant]
Foo, Ce Yao, et al. “Flexible and Highly Scalable V2O5-rGO Electrodes in an Organic Electrolyte for Supercapacitor Devices.” Advanced Energy Materials 4.12 (2014): 1400236.
[cited by applicant]
Fu, Yanqing, et al. “High-Performance Reversible Aqueous Zn-Ion Battery Based on Porous MnOx Nanorods Coated by MOF-Derived N-Doped Carbon.” Advanced Energy Materials 8.26 (2018): 1801445.
[cited by applicant]
Gaur, A., and B. D. Shrivastava. “Speciation using X-ray absorption fine structure (XAFS).” Review Journal of Chemistry 5.4 (2015): 361-398.
[cited by applicant]
Godshall, N. A., I. D. Raistrick, and R. A. Huggins. “Thermodynamic investigations of ternary lithium-transition metal-oxygen cathode materials.” Materials Research Bulletin 15.5 (1980): 561-570.
[cited by applicant]
Goodenough, J. B. et al., Challenges for rechargeable Li batteries, Chem. Mater. 22 (2010) 587-603.
[cited by applicant]
Liu, Chaofeng, et al. “Expanded hydrated vanadate for high-performance aqueous zinc-ion batteries.” Energy & Environmental Science 12.7 (2019): 2273-2285.
[cited by applicant]
Liu, Chaofeng, et al. “Exploiting high-performance anode through tuning the character of chemical bonds for Li-ion batteries and capacitors.” Advanced Energy Materials 7.1 (2017): 1601127.
[cited by applicant]
Liu, Chang, et al. “Advanced materials for energy storage.” Advanced materials 22.8 (2010): E28-E62.
[cited by applicant]
Liu, Chaofeng, et al. “High power high safety battery with electrospun Li3V2 (PO4) 3 cathode and Li4Ti5O12 anode with 95% energy efficiency.” Energy Storage Materials 5 (2016): 93-102.
[cited by applicant]
Liu, Chaofeng, et al. “Interphases, interfaces, and surfaces of active materials in rechargeable batteries and perovskite solar cells.” Advanced Materials 33.22 (2021): 1905245.
[cited by applicant]
Liu, Chaofeng, Zachary G. Neale, and Guozhong Cao. “Understanding electrochemical potentials of cathode materials in rechargeable batteries.” Materials Today 19.2 (2016): 109-123.
[cited by applicant]
Liu, Fei, et al. “V2O5 nanospheres with mixed vanadium valences as high electrochemically active aqueous zinc-ion battery cathode.” Nano-Micro Letters 11.1 (2019): 1-11.
[cited by applicant]
Liu, Guoxue, et al. “K+ pre-intercalated manganese dioxide with enhanced Zn 2+ diffusion for high rate and durable aqueous zinc-ion batteries.” Journal of Materials Chemistry A 7.36 (2019): 20806-20812.
[cited by applicant]
Liu, Kai, et al. “Materials for lithium-ion battery safety.” Science advances 4.6 (2018): eaas9820.
[cited by applicant]
Liu, P. et al. Vanadium-oxide-based electrode materials for Li-ion batteries. The University of Queensland, School of Chemical Engineering Doctor of Philosophy Thesis, 2016.
[cited by applicant]
Liu, Pengcheng, et al. “Recent progress in the applications of vanadium-based oxides on energy storage: from low-dimensional nanomaterials synthesis to 3D micro/nano-structures and free-standing electrodes fabrication.”…
[cited by applicant]
Liu, Wenbao, et al. “Investigation of zinc ion storage of transition metal oxides, sulfides, and borides in zinc ion battery systems.” Chemical Communications 53.51 (2017): 6872-6874.
[cited by applicant]
Liu, X. et al., Calcium vanadate sub-microfibers as highly reversible host cathode material for aqueous zinc-ion batteries, Chem.Commun. 55 (2019) 2265-2268.
[cited by applicant]
Liu, Xiang, et al. “Thermal runaway of lithium-ion batteries without internal short circuit.” Joule 2.10 (2018): 2047-2064.
[cited by applicant]
Liu, Yanyi, et al. “V2O5 nano-electrodes with high power and energy densities for thin film li-ion batteries.” Advanced Energy Materials 1.2 (2011): 194-202.
[cited by applicant]
Liu, Yi, et al. “Electroactivation-induced spinel ZnV2O4 as a high-performance cathode material for aqueous zinc-ion battery.” Nano Energy 67 (2020): 104211.
[cited by applicant]
Liu, Zhen, Giridhar Pulletikurthi, and Frank Endres. “A prussian blue/zinc secondary battery with a bio-ionic liquid-water mixture as electrolyte.” ACS applied materials & interfaces 8.19 (2016): 12158-12164.
[cited by applicant]
Livage, J. “Vanadium pentoxide gels.” Chemistry of Materials 3.4 (1991): 578-593.
[cited by applicant]
Londoño-Calderón, C. L., C. Vargas-Hernández, and J. F. Jurado. “Desorption influence of water on structural, electrical properties and molecular order of vanadium pentoxide xerogel films.” Revista mexicana de física 56…
[cited by applicant]
Lu, Xihong, et al. “Flexible solid-state supercapacitors: design, fabrication and applications.” Energy & Environmental Science 7.7 (2014): 2160-2181.
[cited by applicant]
Luo, Yu-Ran. Comprehensive handbook of chemical bond energies. CRC press, 2007.
[cited by applicant]
Manthiram, Arumugam, et al. “Nickel-rich and lithium-rich layered oxide cathodes: progress and perspectives.” Advanced Energy Materials 6.1 (2016): 1501010.
[cited by applicant]
Marcus, Yizhak. “Ionic radii in aqueous solutions.” Chemical Reviews 88.8 (1988): 1475-1498.
[cited by applicant]
Massé, Robert C., et al. “Energy storage through intercalation reactions: electrodes for rechargeable batteries.” National Science Review 4.1 (2017): 26-53.
[cited by applicant]
McNulty, David, D. Noel Buckley, and Colm O'Dwyer. “Optimizing the structure and yield of vanadium oxide nanotubes by periodic 2D layer scrolling.” RSC advances 6.47 (2016): 40932-40944.
[cited by applicant]
Melot, Brent C., and J-M. Tarascon. “Design and preparation of materials for advanced electrochemical storage.” Accounts of chemical research 46.5 (2013): 1226-1238.
[cited by applicant]
Meng, Jiashen, et al. “A synergistic effect between layer surface configurations and K ions of potassium vanadate nanowires for enhanced energy storage performance.” Journal of Materials Chemistry A 4.13 (2016): 4893-48…
[cited by applicant]
Ming, Fangwang, et al. “Layered Mg x V2O5⋅ n H2O as cathode material for high-performance aqueous zinc ion batteries.” ACS Energy Letters 3.10 (2018): 2602-2609.
[cited by applicant]
Ming, Jun, et al. “Zinc-ion batteries: materials, mechanisms, and applications.” Materials Science and Engineering: R: Reports 135 (2019): 58-84.
[cited by applicant]
Mizushima, K. J. P. C., et al. “LixCoO2 (0<x<−1): A new cathode material for batteries of high energy density.” Materials Research Bulletin 15.6 (1980): 783-789.
[cited by applicant]
Muldoon, John, Claudiu B. Bucur, and Thomas Gregory. “Quest for nonaqueous multivalent secondary batteries: magnesium and beyond.” Chemical reviews 114.23 (2014): 11683-11720.
[cited by applicant]
O'Dwyer, Colm, et al. “Vanadate conformation variations in vanadium pentoxide nanostructures.” Journal of the Electrochemical Society 154.8 (2007): K29-K35.
[cited by applicant]
Pan, An Qiang, et al. “Uniform V2O5 nanosheet-assembled hollow microflowers with excellent lithium storage properties.” Energy & Environmental Science 6.5 (2013): 1476-1479.
[cited by applicant]
Pan, Huilin, et al. “Reversible aqueous zinc/manganese oxide energy storage from conversion reactions.” Nature Energy 1.5 (2016): 1-7.
[cited by applicant]
Pang, Qiang, et al. “H2V3O8 nanowire/graphene electrodes for aqueous rechargeable zinc ion batteries with high rate capability and large capacity.” Advanced Energy Materials 8.19 (2018): 1800144.
[cited by applicant]
Park, Heai-Ku. “Manganese vanadium oxides as cathodes for lithium batteries.” Solid State Ionics 176.3-4 (2005): 307-312.
[cited by applicant]
Parker, Joseph F., et al. “Translating materials-level performance into device-relevant metrics for zinc-based batteries.” Joule 2.12 (2018): 2519-2527.
[cited by applicant]
Peng, Xiang, et al. “Hydrogenated V2O5 nanosheets for superior lithium storage properties.” Advanced Functional Materials 26.5 (2016): 784-791.
[cited by applicant]
Perera, Sanjaya D., et al. “Vanadium oxide nanowire-carbon nanotube binder-free flexible electrodes for supercapacitors.” Advanced Energy Materials 1.5 (2011): 936-945.
[cited by applicant]
Petkov, Valeri, et al. “Structure of V2O5-nH2O Xerogel Solved by the Atomic Pair Distribution Function Technique.” Journal of the American Chemical Society 124.34 (2002): 10157-10162.
[cited by applicant]
Potiron, E., et al. “Electrochemically synthesized vanadium oxides as lithium insertion hosts.” Electrochimica Acta 45.1-2 (1999): 197-214.
[cited by applicant]
Potiron, E., et al. “Electrochemical synthesis, characterization and lithium intercalation properties of e-MxV2O5+ y. nH2O (M=NiII, CuII or MnIV).” Journal of Physics and Chemistry of Solids 62.8 (2001): 1447-1455.
[cited by applicant]
Qian Ii, et al. “Boosting the cyclic stability of aqueous zinc-ion battery based on Al-doped V10O24⋅12H2O cathode materials.” ACS applied materials & interfaces 11.23 (2019): 20888-20894.
[cited by applicant]
Qin, Haigang, et al. “V2O5 hollow spheres as high rate and long life cathode for aqueous rechargeable zinc ion batteries.” Electrochimica Acta 306 (2019): 307-316.
[cited by applicant]
Remith, P., and N. Kalaiselvi. “Li1.2Mn0.6Ni0.1Co0.1O2 microspheres constructed by hierarchically arranged nanoparticles as lithium battery cathode with enhanced electrochemical performance.” Nanoscale 6.24 (2014): 1472…
[cited by applicant]
Saha, Partha, et al. “Rechargeable magnesium battery: Current status and key challenges for the future.” Progress in Materials Science 66 (2014): 1-86.
[cited by applicant]
Sambandam, Balaji, et al. “Aqueous rechargeable Zn-ion batteries: an imperishable and high-energy Zn2V2O7 nanowire cathode through intercalation regulation.” Journal of Materials Chemistry A 6.9 (2018): 3850-3856.
[cited by applicant]
Sambandam, Balaji, et al. “K2V6O16⋅2.7H2O nanorod cathode: an advanced intercalation system for high energy aqueous rechargeable Zn-ion batteries.” Journal of Materials Chemistry A 6.32 (2018): 15530-15539.
[cited by applicant]
Sanchez, C., J. Livage, and G. Lucazeau. “Infrared and Raman study of amorphous V2O5.” Journal of Raman Spectroscopy 12.1 (1982): 68-72.
[cited by applicant]
Saravanakumar, Balakrishnan, Kamatchi Kamaraj Purushothaman, and Gopalan Muralidharan. “V2O5/nitrogen enriched mesoporous carbon spheres nanocomposite as supercapacitor electrode.” Microporous and Mesoporous Materials 2…
[cited by applicant]
Yoshino, Akira. “The birth of the lithium-ion battery.” Angewandte Chemie International Edition 51.24 (2012): 5798-5800.
[cited by applicant]
Yu, Minghao, et al. “Valence-optimized vanadium oxide supercapacitor electrodes exhibit ultrahigh capacitance and super-long cyclic durability of 100 000 cycles.” Advanced Functional Materials 25.23 (2015): 3534-3540.
[cited by applicant]
Yu, Peng, et al. “Flexible Zn-ion batteries: recent progresses and challenges.” Small 15.7 (2019): 1804760.
[cited by applicant]
Zeng, Xiaohui, et al. “Recent progress and perspectives on aqueous Zn-based rechargeable batteries with mild aqueous electrolytes.” Energy Storage Materials 20 (2019): 410-437.
[cited by applicant]
Zhai, Yunpu, et al. “Carbon materials for chemical capacitive energy storage.” Advanced materials 23.42 (2011): 4828-4850.
[cited by applicant]
Zhan, Shiying, et al. “Structural and electrochemical properties of Al3+ doped V2O5 nanoparticles prepared by an oxalic acid assisted soft-chemical method.” Journal of alloys and compounds 502.1 (2010): 92-96.
[cited by applicant]
Zhang, Fan, Peter Y. Zavalij, and M. Stanley Whittingham. “Hydrothermal synthesis and characterization of a series of novel zinc vanadium oxides as cathode materials.” Mat. res. Soc. Symp. Proc., vol. 496 (1997).
[cited by applicant]
Zhang, Leyuan, et al. “Towards high-voltage aqueous metal-ion batteries beyond 1.5 V: the zinc/zinc hexacyanoferrate system.” Advanced Energy Materials 5.2 (2015): 1400930.
[cited by applicant]
Zhang, Li Li, and X. S. Zhao. “Carbon-based materials as supercapacitor electrodes.” Chemical Society Reviews 38.9 (2009): 2520-2531.
[cited by applicant]
Zhang, Leyuan, et al. “Morphology-dependent electrochemical performance of zinc hexacyanoferrate cathode for zinc-ion battery.” Scientific reports 5.1 (2015): 18263. pp. 1-11.
[cited by applicant]
Zhang, Ning, et al. “Hydrated layered vanadium oxide as a highly reversible cathode for rechargeable aqueous zinc batteries.” Advanced Functional Materials 29.10 (2019): 1807331.
[cited by applicant]
Zhang, Ning, et al. “Cation-deficient spinel ZnMn204 cathode in Zn (CF3SO3) 2 electrolyte for rechargeable aqueous Zn-ion battery.” Journal of the American Chemical Society 138.39 (2016): 12894-12901.
[cited by applicant]
Zhang, Ning, et al. “Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities.” Nature communications 8.1 (2017): 405. pp. 1-9.
[cited by applicant]
Zhang, Ning, et al. “Rechargeable aqueous Zn—V2O5 battery with high energy density and long cycle life.” ACS Energy Letters 3.6 (2018): 1366-1372.
[cited by applicant]
Zhang, Jingyan, et al. “Bimetallic nickel cobalt sulfide as efficient electrocatalyst for Zn—air battery and water splitting.” Nano-micro letters 11.1 (2019): 2.
[cited by applicant]
Zhang, Yifu, et al. “Ammonium vanadium oxide [(NH4) 2V4O9] sheets for high capacity electrodes in aqueous zinc ion batteries.” ACS Applied Energy Materials 2.11 (2019): 7861-7869.
[cited by applicant]
Zhao, Qing, et al. “High-capacity aqueous zinc batteries using sustainable quinone electrodes.” Science advances 4.3 (2018): eaao1761.
[cited by applicant]
Zhao, Shuai, et al. “Unravelling the reaction chemistry and degradation mechanism in aqueous Zn/MnO 2 rechargeable batteries.” Journal of Materials Chemistry A 6.14 (2018): 5733-5739.
[cited by applicant]
Zhao, Xin, et al. “The role of nanomaterials in redox-based supercapacitors for next generation energy storage devices.” Nanoscale 3.3 (2011): 839-855.
[cited by applicant]
Zhao, Yunlong, et al. “Stable alkali metal ion intercalation compounds as optimized metal oxide nanowire cathodes for lithium batteries.” Nano letters 15.3 (2015): 2180-2185.
[cited by applicant]
Zheng, Jiqi, et al. “New strategy for the morphology-controlled synthesis of V2O5 microcrystals with enhanced capacitance as battery-type supercapacitor electrodes.” Crystal Growth & Design 18.9 (2018): 5365-5376.
[cited by applicant]
Zheng, Jiqi, et al. “Hydrothermal encapsulation of VO 2 (A) nanorods in amorphous carbon by carbonization of glucose for energy storage devices.” Dalton Transactions 47.2 (2018): 452-464.
[cited by applicant]
Zheng, Jiqi, et al. “Fast and reversible zinc ion intercalation in Al-ion modified hydrated vanadate.” Nano Energy 70 (2020): 104519.
[cited by applicant]
Zhou, Jiang, et al. “Investigation of V 2 O 5 as a low-cost rechargeable aqueous zinc ion battery cathode.” Chemical communications 54.35 (2018): 4457-4460.
[cited by applicant]
Zhou, Ye, et al. “Significance of engineering the octahedral units to promote the oxygen evolution reaction of spinel oxides.” Advanced Materials 31.41 (2019): 1902509.
[cited by applicant]
Zhu, Chuyu, et al. “Binder-free stainless steel@ Mn 3 O 4 nanoflower composite: a high-activity aqueous zinc-ion battery cathode with high-capacity and long-cycle-life.” Journal of Materials Chemistry A 6.20 (2018): 967…
[cited by applicant]
Zhu, Kai, et al. “Synergetic effects of Al3+ doping and graphene modification on the electrochemical performance of V2O5 cathode materials.” ChemSusChem 8.6 (2015): 1017-1025.
[cited by applicant]
Zhu, Yujie, and Chunsheng Wang. “Galvanostatic intermittent titration technique for phase-transformation electrodes.” The Journal of Physical Chemistry C 114.6 (2010): 2830-2841.
[cited by applicant]
International Search Report and Written Opinion mailed Aug. 17, 2020, issued in corresponding International Application No. PCT/US2020/033204, filed May 15, 2020, 9 pages.
[cited by applicant]
International Preliminary Report on Patentability mailed Nov. 16, 2021, issued in corresponding International Application No. PCT/US2020/033204, filed May 15, 2020, 7 pages.
[cited by applicant]
Seidler, G. T., et al. “A laboratory-based hard x-ray monochromator for high-resolution x-ray emission spectroscopy and x-ray absorption near edge structure measurements.” Review of scientific instruments 85.11 (2014): …
[cited by applicant]
Selvakumaran, Dinesh, et al. “A review on recent developments and challenges of cathode materials for rechargeable aqueous Zn-ion batteries.” Journal of Materials Chemistry A 7.31 (2019): 18209-18236.
[cited by applicant]
Senguttuvan, Premkumar, et al. “A high power rechargeable nonaqueous multivalent Zn/V2O5 battery.” Advanced Energy Materials 6.24 (2016): 1600826.
[cited by applicant]
Shan, Lutong, et al. “Observation of combination displacement/intercalation reaction in aqueous zinc-ion battery.” Energy Storage Materials 18 (2019): 10-14.
[cited by applicant]
Shin, Jaeho, et al. “Hydrated intercalation for high-performance aqueous zinc ion batteries.” Advanced Energy Materials 9.14 (2019): 1900083.
[cited by applicant]
Simon, Patrice, Yury Gogotsi, and Bruce Dunn. “Where do batteries end and supercapacitors begin?” Science 343.6176 (2014): 1210-1211.
[cited by applicant]
Snook, Graeme A., Pon Kao, and Adam S. Best. “Conducting-polymer-based supercapacitor devices and electrodes.” Journal of power sources 196.1 (2011): 1-12.
[cited by applicant]
Song, Huanqiao, et al. “Self-doped V4+—V2O5 nanoflake for 2 Li-ion intercalation with enhanced rate and cycling performance.” Nano Energy 22 (2016): 1-10.
[cited by applicant]
Song, Ming, et al. “Recent advances in Zn-ion batteries.” Advanced Functional Materials 28.41 (2018): 1802564.
[cited by applicant]
Soundharrajan, Vaiyapuri, et al. “Na2V6O16⋅ 3H2O barnesite nanorod: an open door to display a stable and high energy for aqueous rechargeable Zn-ion batteries as cathodes.” Nano letters 18.4 (2018): 2402-2410.
[cited by applicant]
Sun, Wei, et al. “Zn/MnO2 battery chemistry with H+ and Zn2+ coinsertion.” Journal of the American Chemical Society 139.29 (2017): 9775-9778.
[cited by applicant]
Suo, Liumin, et al. ““Water-in-salt” electrolyte enables high-voltage aqueous lithium-ion chemistries.” Science 350.6263 (2015): 938-943.
[cited by applicant]
Tang, Boya, et al. “Issues and opportunities facing aqueous zinc-ion batteries.” Energy & Environmental Science 12.11 (2019): 3288-3304.
[cited by applicant]
Tang, Boya, et al. “Potassium vanadates with stable structure and fast ion diffusion channel as cathode for rechargeable aqueous zinc-ion batteries.” Nano Energy 51 (2018): 579-587.
[cited by applicant]
Tang, Boya, et al. “Engineering the interplanar spacing of ammonium vanadates as a high-performance aqueous zinc-ion battery cathode.” Journal of Materials Chemistry A 7.3 (2019): 940-945.
[cited by applicant]
Tian, Meng, et al. “Structural engineering of hydrated vanadium oxide cathode by K+ incorporation for high-capacity and long-cycling aqueous zinc ion batteries.” Energy Storage Materials 29 (2020): 9-16.
[cited by applicant]
Torardi, C. C., et al. “High lithium capacity MxV2O5Ay⋅ nH2O for rechargeable batteries.” Journal of Solid State Chemistry 163.1 (2002): 93-99.
[cited by applicant]
Trócoli, Rafael, and Fabio La Mantia. “An aqueous zinc-ion battery based on copper hexacyanoferrate.” ChemSusChem 8.3 (2015): 481-485.
[cited by applicant]
Van der Heide, Paul. X-ray photoelectron spectroscopy: an introduction to principles and practices. John Wiley & Sons. 2011.
[cited by applicant]
Verma, Vivek, et al. “Progress in rechargeable aqueous zinc-and aluminum-ion battery electrodes: challenges and outlook.” Advanced Sustainable Systems 3.1 (2019): 1800111.
[cited by applicant]
Wan, Fang, et al. “Aqueous rechargeable zinc/sodium vanadate batteries with enhanced performance from simultaneous insertion of dual carriers.” Nature communications (2018)9: 1656, pp. 1-11.
[cited by applicant]
Wang, Fei, et al. “A rechargeable aqueous Zn 2+-battery with high power density and a long cycle-life.” Energy & Environmental Science 11.11 (2018): 3168-3175.
[cited by applicant]
Wang, Guoping, Lei Zhang, and Jiujun Zhang. “A review of electrode materials for electrochemical supercapacitors.” Chemical Society Reviews 41.2 (2012): 797-828.
[cited by applicant]
Wang, Huali, et al. “Binder-free V2O5 cathode for greener rechargeable aluminum battery.” ACS applied materials & interfaces 7.1 (2015): 80-84.
[cited by applicant]
Wang, Huali, et al. “Open-structured V2O5⋅ nH2O nanoflakes as highly reversible cathode material for monovalent and multivalent intercalation batteries.” Advanced Energy Materials 7.14 (2017): 1602720.
[cited by applicant]
Wang, John, et al. “Pseudocapacitive contributions to electrochemical energy storage in TiO2 (anatase) nanoparticles.” The Journal of Physical Chemistry C 111.40 (2007): 14925-14931.
[cited by applicant]
Wang, Lulu, et al. “Transformed akhtenskite MnO2 from Mn3O4 as cathode for a rechargeable aqueous zinc ion battery.” ACS Sustainable Chemistry & Engineering 6.12 (2018): 16055-16063.
[cited by applicant]
Wang, Qiushi, et al. “In-situ grown manganese silicate from biomass-derived heteroatom-doped porous carbon for supercapacitors with high performance.” Journal of colloid and interface science 534 (2019): 142-155.
[cited by applicant]
Wang, Yao, Jing Li, and Zidong Wei. “Transition-metal oxide-based catalysts for the oxygen reduction reaction.” Journal of Materials Chemistry A 6.18 (2018): 8194-8209.
[cited by applicant]
Wei, Qiulong, et al. “Hydrated vanadium pentoxide with superior sodium storage capacity.” Journal of Materials Chemistry A 3.15 (2015): 8070-8075.
[cited by applicant]
Wei, Tongye, et al. “Highly reversible and long-life cycling aqueous zinc-ion battery based on ultrathin (NH 4) 2 V 10 O 25⋅ 8H 2 O nanobelts.” Journal of Materials Chemistry A 6.41 (2018): 20402-20410.
[cited by applicant]
Wei, Tongye, et al. “An electrochemically induced bilayered structure facilitates long-life zinc storage of vanadium dioxide.” Journal of Materials Chemistry A 6.17 (2018): 8006-8012.
[cited by applicant]
Whittingham, M. Stanley. “Intercalation chemistry and energy storage.” Journal of Solid State Chemistry 29.3 (1979): 303-310.
[cited by applicant]
Whittingham, M. Stanley. “Electrical energy storage and intercalation chemistry.” Science 192.4244 (1976): 1126-1127.
[cited by applicant]
Winter, Martin, and Ralph J. Brodd. “What are batteries, fuel cells, and supercapacitors?.” Chemical reviews 104.10 (2004): 4245-4269.
[cited by applicant]
Wu, Tao, et al. “Unraveling the role of structural water in bilayer V 2 O 5 during Zn 2+-intercalation: insights from DFT calculations.” Journal of Materials Chemistry A 7.10 (2019): 5612-5620.
[cited by applicant]
Wu, Zili, et al. “Raman spectroscopic study of V/θ-Al2O3 catalysts: quantification of surface vanadia species and their structure reduced by hydrogen.” The Journal of Physical Chemistry C 111.44 (2007): 16460-16469.
[cited by applicant]
Xia, Chuan, et al. “Highly stable aqueous zinc-ion storage using a layered calcium vanadium oxide bronze cathode.” Angewandte Chemie International Edition 57.15 (2018): 3943-3948.
[cited by applicant]
Xiong, Ting, et al. “Defect engineering of oxygen-deficient manganese oxide to achieve high-performing aqueous zinc ion battery.” Advanced Energy Materials 9.14 (2019): 1803815.
[cited by applicant]
Xu, J. F., et al. “Raman spectra of CuO nanocrystals.” Journal of Raman spectroscopy 30.5 (1999): 413-415.
[cited by applicant]
Xu, Wangwang, et al. “Defect engineering activating (Boosting) zinc storage capacity of MoS2.” Energy Storage Materials 16 (2019): 527-534.
[cited by applicant]
Xu, Yin, and Dezhi Sun. “Structure and catalytic activity of MoZnAlO catalyst for degradation of cationic red GTL under room conditions.” Chemical Engineering Journal 183 (2012): 332-338.
[cited by applicant]
Yadav, Gautam G., et al. “Regenerable Cu-intercalated MnO 2 layered cathode for highly cyclable energy dense batteries.” Nature communications 8.1 (2017): 1-9.
[cited by applicant]
Yamada, Yuki, et al. “Hydrate-melt electrolytes for high-energy-density aqueous batteries.” Nature Energy 1.10 (2016): 1-9.
[cited by applicant]
Yan, Jun, et al. “Recent advances in design and fabrication of electrochemical supercapacitors with high energy densities.” Advanced Energy Materials 4.4 (2014): 1300816.
[cited by applicant]
Yan, Mengyu, et al. “Water-lubricated intercalation in V2O5⋅ nH2O for high-capacity and high-rate aqueous rechargeable zinc batteries.” Advanced materials 30.1 (2018): 1703725.
[cited by applicant]
Yang, Yongqiang, et al. “Li+ intercalated V 2 O 5⋅ n H 2 O with enlarged layer spacing and fast ion diffusion as an aqueous zinc-ion battery cathode.” Energy & Environmental Science 11.11 (2018): 3157-3162.
[cited by applicant]
Yang, Yongqiang, et al. “Transition metal ion-preintercalated V2O5 as high-performance aqueous zinc-ion battery cathode with broad temperature adaptability.” Nano Energy 61 (2019): 617-625.
[cited by applicant]
Yao, Jinhuan, et al. “Revitalized interest in vanadium pentoxide as cathode material for lithium-ion batteries and beyond.” Energy Storage Materials 11 (2018): 205-259.
[cited by applicant]
Yoo, Hyun Deog, et al. “Mg rechargeable batteries: an on-going challenge.” Energy & Environmental Science 6.8 (2013): 2265-2279.
[cited by applicant]
Gummow, Rosalind J., et al. “Calcium-ion batteries: current state-of-the-art and future perspectives.” Advanced Materials 30.39 (2018): 1801702.
[cited by applicant]
Guo, Daoyou, et al. “Room temperature ferromagnetism in (Ga 1-x Mn x) 2 O 3 epitaxial thin films.” Journal of Materials Chemistry C 3.8 (2015): 1830-1834.
[cited by applicant]
Guo, Shan, et al. “Structural perspective on revealing energy storage behaviors of silver vanadate cathodes in aqueous zinc-ion batteries.” Acta Materialia 180 (2019): 51-59.
[cited by applicant]
Guo, Xun, et al. “Mechanistic insights of Zn2+ storage in sodium vanadates.” Advanced Energy Materials 8.27 (2018): 1801819.
[cited by applicant]
Gupta, Tanya, et al. “Improving the cycle life of a high-rate, high-potential aqueous dual-ion battery using hyper-dendritic zinc and copper hexacyanoferrate.” Journal of Power Sources 305 (2016): 22-29.
[cited by applicant]
Hagemann, H., et al. “Raman spectra of single crystal CuO.” Solid state communications 73.6 (1990): 447-451.
[cited by applicant]
Han, Man Huon, et al. “A comprehensive review of sodium layered oxides: powerful cathodes for Na-ion batteries.” Energy & Environmental Science 8.1 (2015): 81-102.
[cited by applicant]
Hardcastle, Franklin D., and Israel E. Wachs. “Determination of vanadium-oxygen bond distances and bond orders by Raman spectroscopy.” The Journal of Physical Chemistry 95.13 (1991): 5031-5041.
[cited by applicant]
Hayner, Cary M., Xin Zhao, and Harold H. Kung. “Materials for rechargeable lithium-ion batteries.” Annual review of chemical and biomolecular engineering 3 (2012): 445-471.
[cited by applicant]
He, A. J. et al., Enhancing Zn-ion storage capability of hydrated vanadium pentoxide by the strategic introduction of La3, ChemSusChem 13 (6) (2019) 1568-1574.
[cited by applicant]
He, Jiarui, et al. “Freestanding 1T MoS 2/graphene heterostructures as a highly efficient electrocatalyst for lithium polysulfides in Li—S batteries.” Energy & Environmental Science 12.1 (2019): 344-350.
[cited by applicant]
He, Pan, et al. “Sodium ion stabilized vanadium oxide nanowire cathode for high-performance zinc-ion batteries.” Advanced Energy Materials 8.10 (2018): 1702463.
[cited by applicant]
Holland, Gregory P., et al. “Comparison of V 2 O 5 xerogels prepared by the vanadate and alkoxide routes using X-Ray absorption and other methods.” Journal of the Electrochemical Society 150.6 (2003): A721-A725.
[cited by applicant]
Horrocks, Gregory A., et al. “Vanadium K-edge X-ray absorption spectroscopy as a probe of the heterogeneous lithiation of V2O5: first-principles modeling and principal component analysis.” The Journal of Physical Chemis…
[cited by applicant]
Hryha, Eduard, Elin Rutqvist, and Lars Nyborg. “Stoichiometric vanadium oxides studied by XPS.” Surface and interface analysis 44.8 (2012): 1022-1025.
[cited by applicant]
Hu, Ping, et al. “Zn/V2O5 aqueous hybrid-ion battery with high voltage platform and long cycle life.” ACS applied materials & interfaces 9.49 (2017): 42717-42722.
[cited by applicant]
Hu, Ping, et al. “Highly durable Na2V6O16⋅ 1.63 H2O nanowire cathode for aqueous zinc-ion battery.” Nano letters 18.3 (2018): 1758-1763.
[cited by applicant]
Hua, Li, et al. “Ultrathin and large-sized vanadium oxide nanosheets mildly prepared at room temperature for high performance fiber-based supercapacitors.” Journal of Materials Chemistry A 5.6 (2017): 2483-2487.
[cited by applicant]
Huang, Haijian, et al. “Fast Na-Ion Intercalation in Zinc Vanadate for High-Performance Na-Ion Hybrid Capacitor.” Advanced Energy Materials 8.35 (2018): 1802800.
[cited by applicant]
Islam, Saiful, et al. “A new rechargeable battery based on a zinc anode and a NaV 6 O 15 nanorod cathode.” Chemical Communications 55.26 (2019): 3793-3796.
[cited by applicant]
Islam, Saiful, et al. “Facile synthesis and the exploration of the zinc storage mechanism of β-MnO 2 nanorods with exposed (101) planes as a novel cathode material for high performance eco-friendly zinc-ion batteries.” …
[cited by applicant]
Jaffari, G. Hassnain, et al. “Study of surface-active modes and defects in single-phase Li-incorporated MgO nanoparticles.” The Journal of Physical Chemistry C 119.50 (2015): 28182-28189.
[cited by applicant]
Jahrman, Evan P., et al. “Laboratory-based x-ray absorption spectroscopy on a working pouch cell battery at industrially-relevant charging rates.” Journal of The Electrochemical Society (2019).
[cited by applicant]
Jahrman, Evan P., et al. “An improved laboratory-based x-ray absorption fine structure and x-ray emission spectrometer for analytical applications in materials chemistry research.” Review of Scientific Instruments 90.2 …
[cited by applicant]
Janousch, Markus, et al. “Role of oxygen vacancies in Cr-doped SrTiO3 for resistance-change memory.” Advanced materials 19.17 (2007): 2232-2235.
[cited by applicant]
Jia, Zhijun, Baoguo Wang, and Yi Wang. “Copper hexacyanoferrate with a well-defined open framework as a positive electrode for aqueous zinc ion batteries.” Materials Chemistry and Physics 149 (2015): 601-606.
[cited by applicant]
Jiang, Hanmei, et al. “Fabrication of (NH4) 2V3O8 nanoparticles encapsulated in amorphous carbon for high capacity electrodes in aqueous zinc ion batteries.” Chemical Engineering Journal 382 (2020): 122844.
[cited by applicant]
Jiao, Tianpeng, et al. “Binder-free hierarchical VS 2 electrodes for high-performance aqueous Zn ion batteries towards commercial level mass loading.” Journal of Materials Chemistry A 7.27 (2019): 16330-16338.
[cited by applicant]
Kasiri, Ghoncheh, et al. “An electrochemical investigation of the aging of copper hexacyanoferrate during the operation in zinc-ion batteries.” Electrochimica Acta 222 (2016): 74-83.
[cited by applicant]
Kim, Haegyeom, et al. “Aqueous rechargeable Li and Na ion batteries.” Chemical reviews 114.23 (2014): 11788-11827.
[cited by applicant]
Konarov, Aishuak, et al. “Present and future perspective on electrode materials for rechargeable zinc-ion batteries.” ACS Energy Letters 3.10 (2018): 2620-2640.
[cited by applicant]
Kong, Lingping, et al. “Free-standing T-Nb2O5/graphene composite papers with ultrahigh gravimetric/volumetric capacitance for Li-ion intercalation pseudocapacitor.” ACS nano 9.11 (2015): 11200-11208.
[cited by applicant]
Kundu, Dipan, et al. “Organic cathode for aqueous Zn-ion batteries: taming a unique phase evolution toward stable electrochemical cycling.” Chemistry of materials 30.11 (2018): 3874-3881.
[cited by applicant]
Kundu, Dipan, et al. “A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode.” Nature Energy 1.10 (2016): 1-8.
[cited by applicant]
Lang, Xing-You, et al. “Ultrahigh-power pseudocapacitors based on ordered porous heterostructures of electron-correlated oxides.” Advanced Science 3.5 (2016): 1500319.
[cited by applicant]
Larcher, Dominique, and Jean-Marie Tarascon. “Towards greener and more sustainable batteries for electrical energy storage.” Nature chemistry 7.1 (2015): 19-29.
[cited by applicant]
Lee, Boeun, et al. “Elucidating the intercalation mechanism of zinc ions into α-MnO 2 for rechargeable zinc batteries.” Chemical communications 51.45 (2015): 9265-9268.
[cited by applicant]
Lee, J. et al., “Electrodeposition of hydrated vanadium pentoxide on nanoporous carbon cloth for hybrid energy storage,” Sustain. Energy & Fuels, 2018, 2, pp. 577-588.
[cited by applicant]
Lee, Jung Woo, et al. “Extremely stable cycling of ultra-thin V 2 O 5 nanowire-graphene electrodes for lithium rechargeable battery cathodes.” Energy & Environmental Science 5.12 (2012): 9889-9894.
[cited by applicant]
Lee, S. et al., Raman spectroscopic studies of amorphous vanadium oxide thin films, Solid State Ionics 165 (2003) 111-116.
[cited by applicant]
Li, Chunbao, et al. “The dual roles of oxodiperoxovanadate both as a nucleophile and an oxidant in the green oxidation of benzyl alcohols or benzyl halides to aldehydes and ketones.” Angewandte Chemie International Edit…
[cited by applicant]
Li, Yingbo, et al. “Recent advances in flexible zinc-based rechargeable batteries.” Advanced Energy Materials 9.1 (2019): 1802605.
[cited by applicant]
Li, Matthew, et al. “30 years of lithium-ion batteries.” Advanced Materials 30.33 (2018): 1800561.
[cited by applicant]
Li, M. et al., Controlling the formation of rodlike V2O5 nanocrystals on reduced graphene oxide for high-performance supercapacitors, ACS Appl. Mater. Interfaces, 5(21) (2013) 11462-11470.
[cited by applicant]
Li, Xinyuan, et al. “Effects of preinserted Na ions on Li-ion electrochemical intercalation properties of V2O5.” ACS applied materials & interfaces 8.37 (2016): 24629-24637.
[cited by applicant]
Li, Yanwei, et al. “Leaf-Like V2O5 Nanosheets Fabricated by a Facile Green Approach as High Energy Cathode Material for Lithium-Ion Batteries.” Advanced Energy Materials 3.9 (2013): 1171-1175.
[cited by applicant]
Li, Hongfei, et al. “MoS2 nanosheets with expanded interlayer spacing for rechargeable aqueous Zn-ion batteries.” Energy Storage Materials 19 (2019): 94-101.
[cited by applicant]
Liang, Yaru, et al. “Nanocomposite materials for the sodium-ion battery: a review.” Small 14.5 (2018): 1702514.
[cited by applicant]
Liu, Bo-Tian, et al. “Extraordinary pseudocapacitive energy storage triggered by phase transformation in hierarchical vanadium oxides.” Nature communications 9.1 (2018): 1-9.
[cited by applicant]
Liu, Canzheng, et al. “Boosting the cycling stability of hydrated vanadium pentoxide by Y3+ pillaring for sodium-ion batteries.” Materials today energy 11 (2019): 218-227.
[cited by applicant]