Preparation method and application of tetragonal NaV
A preparation method of a tetragonal NaV 2 O 5 .H 2 O nanosheet-like powder includes steps of: (S1) simultaneously adding NaVO 3 and Na 2 S.9H 2 O into deionized water, and then magnetically stirring, and obtaining a black turbid solution; (S2) sealing after putting the black turbid solution into an inner lining of a reaction kettle, fixing the sealed inner lining in an outer lining of the reaction kettle, placing the reaction kettle into a homogeneous reactor, and then performing a hydrothermal reaction; and (S3) after completing the hydrothermal reaction, naturally cooling the reaction kettle to the room temperature, and then alternately cleaning through water and alcohol, and then collecting a product, drying the product, and finally obtaining the tetragonal NaV 2 O 5 .H 2 O nanosheet-like powder with a thickness in a range of 30-60 nm and a single crystal structure grown along a (002) crystal orientation.
1. A tetragonal NaV 2 O 5 .H 2 O nanosheet-like powder used as an anode material of a lithium ion battery and prepared by a preparation method which comprises steps of:
(S1) simultaneously adding 0.8-1.2 g of NaVO 3 and 0.5-3.5 g of Na 2 S.9H 2 O into 55-65 ml of deionized water, and then magnetically stirring for 55-65 min under a rotational speed in a range of 800-1000 r/min, and obtaining a black turbid solution;
(S2) sealing after putting the black turbid solution into an inner lining of a reaction kettle according to a filling ratio in a range of 55-65%, fixing the sealed inner lining in an outer lining of the reaction kettle, placing the reaction kettle into a homogeneous reactor, and then heating under a rotational speed in a range of 5-15 r/min from a room temperature to 150-200° C., and then performing a hydrothermal reaction for 1-36 h; and
(S3) after completing the hydrothermal reaction, naturally cooling, the reaction kettle to the room temperature, and then alternately cleaning with water and alcohol by suction filtration or centrifugation for 3-6 times, and then collecting a product by suction filtration or centrifugation, drying the product at 40-80° C., and finally obtaining the tetragonal NaV 2 O 5 .H 2 O nanosheet-like powder, wherein:
the tetragonal NaV 2 O 5 .H 2 O nanosheet-like powder has a thickness in a range of 30-60 nm, a layer spacing of 7.71 Å, and is a single crystal layered structure grown along a (002) crystal orientation;
when the tetragonal NaV 2 O 5 .H 2 O nanosheet-like powder acts as the anode material of the lithium ion battery, at a current density of 100, 200, 500, 1000 and 2000 mAg −1 , a capacity reaches 348, 285, 209, 167 and 130 mAhg −1 , respectively; at the current density of 100 and 200 mAg −1 , a first discharge capacity reaches 859 and 633 mAhg −1 , respectively; and after 480 and 600 cycles, the capacity reaches 483 and 320 mAhg −1 , respectively; and after 1000 cycles at the current density of 1000 mAg −1 , the capacity reaches 129 mAhg −1 .