Chloroprene copolymer latex and production method therefor
One embodiment of the present invention relates to a chloroprene copolymer latex, a method for producing a chloroprene copolymer latex, a chloroprene copolymer latex composition, and a molded article or dipped product of a chloroprene copolymer rubber. The chloroprene copolymer latex is a latex of a chloroprene copolymer including monomer units derived from 2-chloro-1,3-butadiene (chloroprene) and monomer units derived from 2-methyl-1,3-butadiene, wherein the tetrahydrofuran insoluble content in the chloroprene copolymer is 20% by mass or less, and the proportion of the monomer units derived from 2-methyl-1,3-butadiene is 10 to 27 mol % in the chloroprene copolymer.
1. A latex of a chloroprene copolymer consisting of monomer units derived from 2-chloro-1,3-butadiene (chloroprene) and monomer units derived from 2-methyl-1,3-butadiene, wherein
a tetrahydrofuran insoluble content in the chloroprene copolymer is 20% by mass or less,
a weight average molecular weight of a tetrahydrofuran soluble component at 25° ° C. of the chloroprene copolymer is 550,000 or more, and
a proportion of the monomer units derived from 2-methyl-1,3-butadiene in the chloroprene copolymer is 10 to 27 mol %.
2. A method for producing a chloroprene copolymer latex according to claim 1 , comprising a step of emulsion-copolymerizing monomer components containing 2-chloro-1,3-butadiene (chloroprene) and 2-methyl-1,3-butadiene, wherein
a proportion of 2-methyl-1,3-butadiene in the total monomer components is 2 to 40 mol %, and a polymerization conversion of the total monomers is 61 to 90% by mass.
3. The method for producing a chloroprene copolymer latex according to claim 2 , wherein an alkylmercaptan is used as a chain transfer agent.
4. The method for producing a chloroprene copolymer latex according to claim 2 , wherein a potassium salt of rosin acid is used as an emulsifier.
5. A chloroprene copolymer latex composition comprising:
100 parts by mass of solid content of a chloroprene copolymer latex;
0.1 to 20.0 parts by mass of a metal oxide (B);
0.1 to 10.0 parts by mass of a vulcanization accelerator (C);
0.1 to 10.0 parts by mass of sulfur (D); and
0.1 to 10.0 parts by mass of an antioxidant (E),
wherein a chloroprene copolymer included in the chloroprene copolymer latex consists of monomer units derived from 2-chloro-1,3-butadiene (chloroprene) and monomer units derived from 2-methyl-1,3-butadiene,
a tetrahydrofuran insoluble content in the chloroprene copolymer is 20% by mass or less, and
a proportion of the monomer units derived from 2-methyl-1,3-butadiene in the chloroprene copolymer is 10 to 27 mol %.
6. A molded article of a chloroprene copolymer rubber, provided by curing the chloroprene copolymer latex composition according to claim 5 .
7. A dip-molded product provided by molding the chloroprene copolymer latex composition according to claim 5 by a dipping method followed by curing.
8. The dip-molded product according to claim 7 , wherein the dip-molded product is gloves.
9. The dip-molded product according to claim 8 , wherein the dip-molded product is medical disposable gloves.