Granted Patent B2

US 12,227,414 · App. 17/627,202 · Granted Feb 18, 2025

Inventors: Peter Mølgaard Mortensen (Roskilde, DK); Kasper Emil Larsen (Humlebæk, DK); Kim Aasberg-Petersen (Allerød, DK); Robert Klein (Roskilde, DK)

Assignee: HALDOR TOPSØE A/S

C01B3/047B01J3/04B01J19/0006B01J19/2485B01J35/56C01B3/56B01J2219/00132B01J2219/0015B01J2219/00162B01J2219/2428B01J2219/2438C01B2203/0277C01B2203/085

Abstract

Claims (30)

1. A reactor system for production of hydrogen from a feed gas comprising ammonia in the presence of a catalyst under ammonia cracking reaction conditions, said reactor system comprising:

a supply of feed gas comprising ammonia;

a structured catalyst arranged for catalyzing said ammonia cracking reaction of said feed gas, said structured catalyst comprising a macroscopic structure of an electrically conductive material, said macroscopic structure supporting a ceramic coating, wherein said ceramic coating supports a catalytically active material;

a pressure shell housing said structured catalyst, said pressure shell comprising an inlet for letting in said feed gas and an outlet for letting out product gas, wherein said inlet is positioned so that said feed gas enters said structured catalyst in a first end of said structured catalyst and said product gas exits said structured catalyst from a second end of said structured catalyst;

a heat insulation layer between said structured catalyst and said pressure shell;

at least two conductors electrically connected to said structured catalyst and to an electrical power supply placed outside said pressure shell, wherein said electrical power supply is dimensioned to heat at least part of said structured catalyst to a temperature of at least 300° C. by passing an electrical current through said macroscopic structure, wherein said at least two conductors are connected to the structured catalyst at a position on the structured catalyst closer to said first end of said structured catalyst than to said second end of said structured catalyst, and wherein the structured catalyst is constructed to direct an electrical current to run from one conductor substantially to the second end of the structured catalyst and return to a second of said at least two conductors;

an outlet for a product stream comprising hydrogen.

2. The reactor system according to claim 1 , wherein said electrical power supply is dimensioned to heat at least part of said structured catalyst to a temperature of at least 700° C.

3. The reactor system according to claim 1 , wherein the feed gas additionally comprises H 2 , N 2 , or Ar.

4. The reactor system according to claim 1 , wherein the pressure shell has a design pressure of between 2 and 30 bar.

5. The reactor system according to claim 1 , wherein the pressure shell has a design pressure of between 30 and 200 bar.

6. The reactor system according to claim 1 , wherein the resistivity of the electrically conductive material is between 10 −5 Ω·m and 10 −7 Ω·m.

7. The reactor system according to claim 1 , further comprising electrically insulating parts provided in the structured catalyst and positioned between the at least two conductors.

8. A method for rapidly switching a metal-catalysed ammonia cracking reaction of a feed gas comprising ammonia in a reactor system according to claim 1 , from a first steady-state reaction condition (A) to a second steady-state reaction condition (B) or vice-versa; said method comprising the steps of:

in said first steady-state reaction condition (A):

supplying said feed gas to the reactor system in a first total flow, and

supplying a first electrical power via electrical conductors connecting an electrical power supply placed outside said pressure shell to said structured catalyst, thereby allowing a first electrical current to run through said electrically conductive material, thereby heating at least part of the structured catalyst to a first temperature at which said feed gas is converted to a first product gas mixture over said structured catalyst under said first steady-state reaction conditions (A); and said first product gas is outlet from the reactor system;

and, in said second steady-state reaction condition (B):

supplying said feed gas to the reactor system in a second total flow,

supplying a second electrical power via electrical conductors connecting an electrical power supply placed outside said pressure shell to said structured catalyst, thereby allowing a second electrical current to run through said electrically conductive material,

thereby heating at least part of the structured catalyst to a second temperature; at which said feed gas is converted to a second product gas mixture over said structured catalyst under said second steady-state reaction conditions (B); and said second product gas is outlet from the reactor system;

wherein said second electrical power is higher than said first electrical power; and/or

said second total flow is higher than said first total flow.

9. A process for carrying out the ammonia cracking reaction of a feed gas comprising ammonia to hydrogen in the presence of a catalyst under ammonia cracking reaction conditions, in a reactor system comprising a pressure shell housing a structured catalyst arranged for catalyzing said ammonia cracking reaction of a feed gas, said structured catalyst comprising a macroscopic structure of electrically conductive material, said macroscopic structure supporting a ceramic coating, wherein said ceramic coating supports a catalytically active material; wherein said reactor system is provided with heat insulation between said structured catalyst and said pressure shell; said process comprising the steps of:

pressurizing said feed gas,

supplying said pressurized feed gas to said pressure shell through an inlet positioned so that said feed gas enters said structured catalyst in a first end of said structured catalyst; allowing the feed gas to undergo an ammonia cracking reaction over the structured catalyst and outletting a product gas from said pressure shell, wherein said product gas exits said structured catalyst from a second end of said structured catalyst;

supplying electrical power via electrical conductors connecting an electrical power supply placed outside said pressure shell to said structured catalyst, allowing an electrical current to run through said macroscopic structure, thereby heating at least part of the structured catalyst to a temperature of at least 300° C., wherein said at least two conductors are connected to the structured catalyst at a position on the structured catalyst closer to said first end of said structured catalyst than to said second end of said structured catalyst, and wherein the structured catalyst is constructed to direct an electrical current to run from one conductor substantially to the second end of the structured catalyst and return to a second of said at least two conductors, thereby heating at least part of the structured catalyst to a temperature sufficient for said feed gas to undergo the ammonia cracking reaction over the structured catalyst, thereby heating at least part of the structured catalyst to a temperature sufficient for said feed gas to undergo the ammonia cracking reaction over the structured catalyst,

outletting a product gas comprising hydrogen from the reactor system.

10. The process according to claim 9 , wherein the process further comprises the step of feeding the product stream comprising hydrogen to an upgrading unit and separating it into an upgraded hydrogen stream and an off-gas stream.

11. The process according to claim 10 , wherein the process further comprises the step of feeding the product gas or upgraded hydrogen stream from said upgrading unit to a downstream plant for electricity production.

Assignments (2)

Priority Claims (2)

Continuity (1)

References Cited (155)