Cyanide on demand
A reactor system and a process for carrying out the reaction of a feed gas comprising an alkane such as methane, and ammonia to hydrogen cyanide and/or a nitrile are provided, where the heat for the endothermic reaction is provided by resistance heating. In particular, the reaction is the BMA (Blausäure aus Methan und Ammoniak) reaction.
1. A reactor system for carrying out the reaction of a feed gas comprising an alkane and ammonia to hydrogen cyanide and/or a nitrile in the presence of a catalyst, said reactor system comprising:
a supply of feed gas comprising an alkane and ammonia;
a structured catalyst arranged for catalyzing the reaction of said feed gas, said structured catalyst comprising a macroscopic structure of an electrically conductive material, said macroscopic structure supporting a ceramic coating, wherein said ceramic coating supports a catalytically active material;
a pressure shell housing said structured catalyst, said pressure shell comprising an in-let for letting in said feed gas and an outlet for letting out product gas, wherein said inlet is positioned so that said feed gas enters said structured catalyst in a first end of said structured catalyst and said product gas exits said structured catalyst from a second end of said structured catalyst;
a heat insulation layer between said structured catalyst and said pressure shell;
at least two conductors electrically connected to said structured catalyst and to an electrical power supply placed outside said pressure shell, wherein said electrical power supply is dimensioned to heat at least part of said structured catalyst to a temperature of at least 500° C. by passing an electrical current through said macroscopic structure, wherein said at least two conductors are connected to the structured catalyst at a position on the structured catalyst closer to said first end of said structured catalyst than to said second end of said structured catalyst, and wherein the structured catalyst is constructed to direct an electrical current to run from one conductor substantially to the second end of the structured catalyst and return to a second of said at least two conductors;
an outlet for a product stream comprising hydrogen cyanide and/or a nitrile.
2. The reactor system according to claim 1 , wherein said electrical power supply is dimensioned to heat at least part of said structured catalyst to a temperature of at least 700° C.
3. The reactor system according to claim 1 , wherein the feed gas additionally comprises H 2 , N 2 , or Ar.
4. The reactor system according to claim 1 , wherein the pressure shell has a design pressure of between 2 and 30 bar.
5. A method for rapidly switching a metal-catalysed reaction of a feed gas comprising an alkane and ammonia in a reactor system according to claim 1 , from a first steady-state reaction condition (A) to a second steady-state reaction condition (B) or vice-versa; said method comprising the steps of:
in said first steady-state reaction condition (A):
supplying said feed gas to the reactor system in a first total flow, and
supplying a first electrical power via electrical conductors connecting an electrical power supply placed outside said pressure shell to said structured catalyst, thereby allowing a first electrical current to run through said electrically conductive material, thereby heating at least part of the structured catalyst to a first temperature at which said feed gas is converted to a first product gas mixture over said structured catalyst under said first steady-state reaction conditions (A); and said first product gas is outlet from the reactor system;
and, in said second steady-state reaction condition (B):
supplying said feed gas to the reactor system in a second total flow,
supplying a second electrical power via electrical conductors connecting an electrical power supply placed outside said pressure shell to said structured catalyst, thereby allowing a second electrical current to run through said electrically conductive material, thereby heating at least part of the structured catalyst to a second temperature; at which said feed gas is converted to a second product gas mixture over said structured catalyst under said second steady-state reaction conditions (B); and said second product gas is outlet from the reactor system;
wherein said second electrical power is higher than said first electrical power; and/or said second total flow is higher than said first total flow.
6. A process for carrying out the reaction of a feed gas comprising an alkane and ammonia to hydrogen cyanide and/or a nitrile in the presence of a catalyst, in a reactor system comprising a pressure shell housing a structured catalyst arranged for catalyzing said endothermic reaction of a feed gas, said structured catalyst comprising a macroscopic structure of electrically conductive material, said macroscopic structure supporting a ceramic coating, wherein said ceramic coating supports a catalytically active material; wherein said reactor system is provided with heat insulation between said structured catalyst and said pressure shell; said process comprising the steps of:
pressurizing said feed gas,
supplying said pressurized feed gas to said pressure shell through an inlet positioned so that said feed gas enters said structured catalyst in a first end of said structured catalyst;
allowing the feed gas to undergo reaction over the structured catalyst and outletting a product gas from said pressure shell, wherein said product gas exits said structured catalyst from a second end of said structured catalyst;
supplying electrical power via electrical conductors connecting an electrical power supply placed outside said pressure shell to said structured catalyst, allowing an electrical current to run through said macroscopic structure, thereby heating at least part of the structured catalyst to a temperature of at least 500° C., wherein said at least two conductors are connected to the structured catalyst at a position on the structured catalyst closer to said first end of said structured catalyst than to said second end of said structured catalyst, and wherein the structured catalyst is constructed to direct an electrical current to run from one conductor substantially to the second end of the structured catalyst and return to a second of said at least two conductors, thereby heating at least part of the structured catalyst to a temperature sufficient for said feed gas to undergo the BMA reaction over the structured catalyst, thereby heating at least part of the structured catalyst to a temperature sufficient for said feed gas to undergo the BMA reaction over the structured catalyst,
outletting a product gas comprising hydrogen cyanide and/or a nitrile from the reactor system.
7. The process according to claim 6 , wherein the alkane is methane, the catalyst is a BMA catalyst and the product stream comprises hydrogen cyanide.
8. The process according to claim 7 , wherein the process further comprises the step of feeding the product stream comprising hydrogen cyanide to an upgrading unit and separating it into an upgraded hydrogen cyanide stream and an off-gas stream.
9. The process according to claim 8 , wherein the upgrading unit is arranged so that the off-gas stream is recycled and mixed with the supply of feed gas before being passed over the structured catalyst.
10. The process according to claim 8 , wherein the process further comprises the step of feeding the upgraded hydrogen cyanide stream from said upgrading unit to a downstream plant for HCN conversion to an upgraded product and where the production of HCN is equivalent to the consumption of HCN in the downstream plant.