IP Library Granted Patent US 11,712,738
Granted Patent B2
US 11,712,738 · App. 17/649,281 · Granted Aug 1, 2023

Crack healing additive manufacturing of a superalloy component

Inventors: Kazim Ozbaysal (Charlotte, NC); Ahmed Kamel (Orlando, FL); Shankar P. Srinivasan (Tega Cay, SC)
Assignee: SIEMENS ENERGY, INC.
B22F1/09B22F10/64B22F12/10B22F12/41B23P6/002B22F2301/052B22F2301/15B33Y10/00B33Y70/10Y10T29/49737
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 11,712,738
App. No.
17/649,281
Granted
Aug 1, 2023
Kind
B2
Abstract

A method of additively manufacturing is provided. The method may include successively depositing and fusing together layers of a superalloy powder mixture comprised of a base material powder and a eutectic powder, to build up an additive portion, which eutectic powder has a solidus temperature lower than the solidus temperature of the base material powder. The method may also include heat treating the additive portion at a temperature greater than 1200° C. to heal cracks and/or fill pores and to homogenize the alloy of which the additive portion is comprised. The additive portion alloy has a chemistry defined by the superalloy powder mixture. The base material powder may be formed of a nickel-base superalloy with an aluminum content by weight of at least 1.5%. The eutectic powder may be a nickel-base alloy including by weight about 6% to about 11% chromium, about 5% to about 9% titanium, and about 9% to about 13% zirconium, with balance nickel as its primary components.

Claims (157)

1. A method of additively manufacturing comprising:

successively depositing and fusing together layers of a superalloy powder mixture comprised of a base material powder and a eutectic powder, to build up an additive portion, wherein the eutectic powder has a solidus temperature lower than the solidus temperature of the base material powder; and

heat treating the additive portion at a temperature greater than 1200° C. to heal cracks and/or fill pores and to homogenize the alloy of which the additive portion is comprised, which additive portion alloy has a chemistry defined by the superalloy powder mixture,

wherein the base material powder has a nickel content by weight greater than 40% and an aluminum content by weight greater than 1.5%, wherein the eutectic powder includes by weight about 6% to about 11% chromium, about 5% to about 9% titanium, about 9% to about 13% zirconium, and greater than 40% nickel.

2. The method according to claim 1 , including:

removing a damaged portion from a component to leave a first interface;

printing a replacement portion via the successively depositing and fusing together layers of the superalloy powder mixture, which replacement portion has a second interface surface; and

attaching the second interface surface to the first interface surface to replace the damaged portion of the component.

3. The method according to claim 1 , wherein the solidus temperature of the eutectic powder is more than 220° C. below the solidus temperature of the base material powder.

4. The method according to claim 1 , wherein the eutectic powder has a liquidus temperature below 1300° C.

5. The method according to claim 1 , wherein heat treating includes heat treating the additive portion at a temperature at or above 1230° C.

6. The method according to claim 1 , wherein the ratio of the base material powder to the eutectic powder by weight is between about 94:06 and about 76:24 in the superalloy powder mixture.

7. The method according to claim 6 , wherein the ratio of the base material powder to the eutectic powder by weight is between about 94:06 and about 85:15 in the superalloy powder mixture.

8. The method according to claim 1 , wherein the eutectic powder includes at maximum 1% aluminum by weight.

9. The method according to claim 8 , wherein the base material powder is comprised by weight of about 4% to about 23% chromium, about 4% to about 20% cobalt, 0% to about 8% titanium, about 1.5% to about 8% aluminum, 0% to about 11% tungsten, 0% to about 4% molybdenum, 0% to about 13% tantalum, 0% to about 0.2% carbon, 0% to about 1% zirconium, 0% to about 4% hafnium, 0% to about 4% rhenium, 0% to about 0.1% yttrium and/or cerium, 0% to about 0.04% boron, 0% to about 2% niobium, 0% to about 1.5% optional incidental elements and unavoidable impurities, and balance nickel.

10. The method according to claim 9 , wherein the base material powder includes at least 4.5% by weight of aluminum.

11. The method according to claim 10 , wherein the base material powder is a nickel-base superalloy including at least 5.5% aluminum by weight and greater than 45% nickel by weight.

12. The method according to claim 9 , wherein the eutectic powder comprises the following composition by weight %:

Cr

6-11

Co

0-1

Ti

5-9

Al

0-1

W

0-1

Mo

0-0.55

Ta

0-0.05

C

0-0.08

Zr

9-13

Hf

0.0-0.05

Re

0.0-0.05

Y and/or Ce

0-0.01

B

0.0-0.04

the balance nickel and optional incidental elements and unavoidable impurities.

13. The method according to claim 12 , wherein the eutectic powder comprises by weight at maximum 0.01% of one or more unavoidable impurities.

14. The method according to claim 12 , wherein the eutectic powder comprises by weight at maximum 1.5% of one or more incidental elements other than Co, Al, W, Mo, Ta, C, Hf, Re, Y, Ce, and B.

15. The method according to claim 12 , wherein the eutectic powder comprises one or more incidental elements selected from the following with a respective maximum weight percent or maximum ppm as indicated:

S

30 ppm

Nb

1.5%

Mn

0.6%

Fe

0.05%

Si

0.30%

P

50 ppm

Mg

50 ppm

Cu

0.01 %

N

60 ppm

0

250 ppm

Ag

I ppm

As

5 PPm

Bi

0.1 ppm

Cd

2 ppm

Ga

25 ppm

In

0.2 ppm

Pb

2 ppm

Sb

2 ppm

Se

I ppm

Sn

10 ppm

Te

0.1 ppm

Ti

0.2 ppm

Zn

5 Ppm.

V

1.5%.

16. The method according to claim 15 , wherein the unavoidable impurities are within the maximum amounts for the respective incidental elements and for any other elements that maximum is about 0.001% by weight.

17. The method according to claim 12 , wherein the base material powder comprises the following composition in weight %:

Cr

8-8.5

Co

9-9.5

Ti

0.6-0.9

Al

5.4-5.7

W

9.3-9.7

Mo

0.4-0.6

Ta

3.1-3.3

C

0.05-0.11

Zr

0-0.02

Hf

1.3-1.5

Re

0-0.05

Y and/or Ce

0-0.1

B

0-0.04

the balance nickel and optional incidental elements and unavoidable impurities.

18. The method according to claim 12 , wherein the base material powder comprises the following composition in weight %:

Cr

5-7.3

Co

7-13

Ti

0-0.05

Al

5.5-6.5

W

4.7-5.2

Mo

1.2-2.2

Ta

0-4.5

C

0-0.15

Zr

0-1

Hf

0-1.7

Re

2.0-4.2

Y and/or Ce

0-0.1

B

0-0.04

the balance nickel and optional incidental elements and unavoidable impurities.

19. The method according to claim 12 , wherein the additive portion forms at least a portion of a turbine blade or turbine guide vane.

20. The method according to claim 12 , wherein the superalloy powder mixture is deposited and fused together via a selective laser melting (SLM) 3D printer to form the additive portion.

21. The method according to claim 12 , wherein the superalloy powder mixture is deposited and fused together via a laser wire deposition (LWD) system, which employs a welding wire to provide the superalloy powder mixture.

22. The method according to claim 21 , wherein the welding wire comprises a nickel or a nickel alloy foil sheath including therein the superalloy powder mixture.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 4, 2022
From: OZBAYSAL, KAZIM; KAMEL, AHMED; SRINIVASAN, SHANKAR P.
To: SIEMENS ENERGY, INC.
Reel/Frame 058893/0366 →
Continuity (5)
Continuation In Part 17577607 · Jan 18, 2022
Provisional Application 63286202 · Dec 6, 2021
Provisional Application 63229753 · Aug 5, 2021
Provisional Application 63142540 · Jan 28, 2021
Related Publication 20220234101A1 · Jul 28, 2022
Cited By (11)
US 12,286,691 US 12,502,713 US 12,528,133 US 12,529,126 US 12,534,778 US 12,544,845 US 12,576,614 US 12,605,768 US 12,636,741 US 12,722,360 US 12,735,986