Superalloy powder mixture for liquid assisted additive manufacturing of a superalloy component
A superalloy powder mixture is provided for use with additive manufacturing or welding metal components or portions thereof. The superalloy powder mixture includes at least 51% by weight a high melt superalloy powder and at least 5% by weight a low melt superalloy powder. The low melt superalloy powder may have a solidus temperature lower than the solidus temperature of the high melt superalloy powder by between 50° C. and 220° C. Each of the high melt superalloy powder, the low melt superalloy powder, and the superalloy powder mixture may have a nickel content by weight greater than 40% and may have an aluminum content by weight of greater than 1.5%. The low melt superalloy powder may include at least 5% by weight of tantalum, and the high melt superalloy powder may include less than half the content by weight percent of tantalum compared to the content by weight percent of tantalum in the low melt superalloy powder.
1 . A superalloy powder mixture for additively manufacturing or welding metal components or portions thereof comprising:
at least 51% by weight a high melt superalloy powder; and
at least 5% by weight a low melt superalloy powder,
wherein the low melt superalloy powder has a solidus temperature lower than the solidus temperature of the high melt superalloy powder by between 50° C. and 220° C., wherein each of the high melt superalloy powder, the low melt superalloy powder, and the superalloy powder mixture have a nickel content by weight greater than 40%, and have an aluminum content by weight of greater than 1.5%, wherein the low melt superalloy powder includes at least 5% by weight of tantalum, and wherein the high melt superalloy powder includes less than half the content by weight percent of tantalum compared to the content by weight percent of tantalum in the low melt superalloy powder, wherein the low melt superalloy powder has a liquidus temperature above 1300° C.
2 . The superalloy powder mixture according to claim 1 , wherein the high melt superalloy powder includes by weight at maximum 1% tantalum, wherein the high melt superalloy powder, the low melt superalloy powder, and the superalloy powder mixture have an aluminum content by weight of greater than 4.0%.
3 . The superalloy powder mixture according to claim 1 , wherein the low melt superalloy powder has a solidus temperature between 10° C. and 150° C. below the grain boundary melting temperature of a homogenized base alloy having a chemistry corresponding to the superalloy powder mixture.
4 . The superalloy powder mixture according to claim 1 , wherein the high melt superalloy powder has a solidus temperature between 1350° C. and 1430° C.
5 . The superalloy powder mixture according to claim 1 , wherein the low melt superalloy powder has a solidus temperature between 1210° C. and 1360° C.
6 . The superalloy powder mixture according to claim 1 , wherein the superalloy powder mixture has a total of aluminum and optional titanium content by weight of greater than 4%.
7 . The superalloy powder mixture according to claim 6 , wherein the superalloy powder mixtures is comprised by weight of about 4% to about 23% chromium, about 4% to about 20% cobalt, 0% to about 8% titanium, about 1.5% to about 8% aluminum, 0% to about 11% tungsten, 0% to about 4% molybdenum, about 1% to about 13% tantalum, 0% to about 0.2% carbon, 0% to about 1% zirconium, 0% to about 4% hafnium, 0% to about 4% rhenium, 0% to about 0.1% yttrium and/or cerium, 0% to about 0.04% boron, 0% to about 2% niobium, 0% to about 1.5% optional incidental elements and unavoidable impurities, and balance nickel.
8 . The superalloy powder mixture according to claim 7 , wherein each of the high melt superalloy powder, the low melt superalloy powder, and the superalloy powder mixture have an aluminum content by weight of greater than 4.0%.
9 . The superalloy powder mixture according to claim 8 , wherein each of the high melt superalloy powder, the low melt superalloy powder, and the superalloy powder mixture have a nickel content by weight greater than 45% and an aluminum content by weight of greater than 5.5%.
10 . The superalloy powder mixture according to claim 9 , wherein the superalloy powder mixture has an aluminum content by weight of at least 6%.
11 . The superalloy powder mixture according to claim 8 , wherein the low melt superalloy powder comprises by weight at least 8% aluminum.
12 . The superalloy powder mixture according to claim 11 , wherein the low melt superalloy powder comprises by weight 8% to 9% aluminum.
13 . The superalloy powder mixture according to claim 8 , wherein the high melt superalloy powder comprises by weight 4.5% to 6.5% aluminum.
14 . The superalloy powder mixture according to claim 7 , wherein the low melt superalloy powder includes at least 10% by weight of tantalum.
15 . The superalloy powder mixture according to claim 14 , wherein the high melt superalloy powder includes by weight at maximum 1% tantalum.
16 . The superalloy powder mixture according to claim 15 , wherein the superalloy powder mixture comprises by weight at maximum 6.2% tantalum.
17 . The superalloy powder mixture according to claim 7 , wherein the low melt superalloy powder includes at least 0.5% by weight of hafnium, and wherein the high melt superalloy powder includes less than half the content by weight percent of hafnium compared to the content by weight percent of hafnium in the low melt superalloy powder.
18 . The superalloy powder mixture according to claim 17 , wherein the low melt superalloy powder comprises by weight at least 3% hafnium.
19 . The superalloy powder mixture according to claim 18 , wherein the high melt superalloy powder comprises by weight at maximum 0.05% hafnium.
20 . The superalloy powder mixture according to claim 19 , wherein the superalloy powder mixture comprises by weight at maximum 2.0% hafnium.
21 . The superalloy powder mixture according to claim 7 , wherein the low melt superalloy powder comprises by weight 10% to 20% tantalum and 3% to 12% hafnium.
22 . The superalloy powder mixture according to claim 7 , wherein at least one of the amounts of chromium, aluminum, or molybdenum in weight percent in the low melt superalloy powder is at least 15% to 75% less than the corresponding weight percent in the high melt superalloy powder.
23 . The superalloy powder mixture according to claim 7 , wherein at least one of the amounts of cobalt or tungsten in weight percent in the high low melt superalloy powder is at least 50% to 75% less than the corresponding weight percent in the low melt superalloy powder.
24 . The superalloy powder mixture according to claim 7 , wherein the low melt superalloy powder comprises by weight at maximum 3.4% cobalt.
25 . The superalloy powder mixture according to claim 7 , wherein the low melt superalloy powder comprises by weight at least 3.8% tungsten.
26 . The superalloy powder mixture according to claim 7 , wherein the superalloy powder mixture comprises by weight at least 9% tungsten.
27 . The superalloy powder mixture according to claim 7 , wherein the low melt superalloy powder includes at least 7% by weight of titanium, and wherein the high melt superalloy powder includes less than half the content by weight percent of titanium compared to the content by weight percent of titanium in the low melt superalloy powder.
28 . The superalloy powder mixture according to claim 7 , wherein the superalloy powder mixture, the high melt superalloy powder, and the low melt superalloy powder each comprise by weight at maximum 0.05% titanium.
29 . The superalloy powder mixture according to claim 7 , wherein the low melt superalloy powder comprises by weight 0.03% to 0.07% yttrium and/or cerium.
30 . The superalloy powder mixture according to claim 7 , wherein the low melt superalloy powder comprises by weight at maximum 0.08% carbon.
31 . The superalloy powder mixture according to claim 7 , wherein the superalloy powder mixture comprises the following composition in weight %:
Cr
7.8-17.3
Co
8.7-10.2
Ti
0-2.9
Al
4.8-7.3
W
9-10.3
Mo
0.35-0.75
Ta
1.0-6.2
C
0-0.12
Zr
0-1
Hf
0.3-3.6
Re
0-0.05
Y and/or Ce
0-0.1
B
0-0.04
the balance nickel and optional incidental elements and unavoidable impurities.
32 . The superalloy powder mixture according to claim 31 , wherein the superalloy powder mixture comprises by weight 7.8% to 8.8% chromium.
33 . The superalloy powder mixture according to claim 31 , wherein the superalloy powder mixture comprises by weight 11.7% to 15.5% chromium.
34 . The superalloy powder mixture according to claim 31 , wherein the high melt superalloy powder comprises by weight 7.7% to 8.1% chromium.
35 . The superalloy powder mixture according to claim 31 , wherein the high melt superalloy powder comprises by weight 12% to 16% chromium.
36 . The superalloy powder mixture according to claim 31 , wherein each of the superalloy powder mixture, the high melt superalloy powder, and the low melt superalloy powder comprise by weight 0% to 0.01% of one or more unavoidable impurities.
37 . The superalloy powder mixture according to claim 31 , wherein each of the superalloy powder mixture, the high melt superalloy powder, and the low melt superalloy powder comprise by weight 0% to 1.5% of one or more incidental elements other than Cr, Co, Ti, Al, W, Mo, Ta, C, Zr, Hf, Re, Y, Ce and B.
38 . The superalloy powder mixture according to claim 31 , wherein the superalloy powder mixture, high melt superalloy powder, and low melt superalloy powder comprise one or more incidental elements selected from the following with a respective maximum weight percent or maximum ppm as indicated:
S
30
ppm
Nb
1.5%
Mη
0.6%
Fe
0.05%
Si
0.30%
P
50
ppm
Mg
50
ppm
Cu
0.01%
N
60
ppm
O
250
ppm
Ag
1
ppm
As
5
ppm
Bi
0.1
ppm
Cd
2
ppm
Ga
25
ppm
In
0.2
ppm
Pb
2
ppm
Sb
2
ppm
Se
1
ppm
Sn
10
ppm
Te
0.1
ppm
Tl
0.2
ppm
Zn
5
ppm.
V
1.5%
39 . The superalloy powder mixture according to claim 38 , wherein the unavoidable impurities are within the maximum amounts for the respective incidental elements and for any other elements that maximum is 0.001% by weight.
40 . The superalloy powder mixture according to claim 1 , wherein the ratio of the high melt superalloy powder to the low melt superalloy powder by weight is between 94:06 and 76:24 in the superalloy powder mixture.
41 . The superalloy powder mixture according to claim 40 , wherein the ratio of the high melt superalloy powder to the low melt superalloy powder by weight is between 85:15 and 75:25 in the superalloy powder mixture.
42 . The superalloy powder mixture according to claim 2 , wherein the high melt superalloy powder comprises by weight at least 10.6% tungsten.