IP Library › Granted Patent US 10,577,679
Granted Patent B1
US 10,577,679 · App. 16/208,827 · Granted Mar 3, 2020

Gamma prime strengthened nickel superalloy for additive manufacturing

Inventors: Andrew Ezekiel Wessman (Walton, KY); Timothy Hanlon (Glenmont, NY); Laura Cerully Dial (Clifton Park, NY)
Assignee: General Electric Company
C22C19/056B22F3/1055C22C19/057B22F2301/15B22F2303/15B22F2999/00B33Y70/00B33Y80/00
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Quick Facts
Patent No.
US 10,577,679
App. No.
16/208,827
Granted
Mar 3, 2020
Kind
B1
Abstract

An additive manufactured product, along with methods of its formation, is provided. The additive manufactured product may include a fused multilayer component comprising a nickel superalloy having a composition comprising, by weight: 7% to 11% of cobalt; 9% to 14% of chromium; 1.5% to 8% of molybdenum; up to 8% of tungsten; 4% to 6% of aluminum; 1% to 4% of titanium; up to 4.6% tantalum; up to 2% hafnium; up to 0.04% zirconium; up to 0.05% carbon; up to 0.04% boron; up to 1% niobium; and the balance nickel along with unavoidable residual elements in trace amounts. This composition may have a sum of the weight percentages of zirconium and boron that is up to 0.06%.

Claims (88)

1. An additive manufactured product, comprising:

a fused multilayer component comprising a nickel superalloy, wherein the nickel superalloy has a composition comprising, by weight:

7% to 11% of cobalt;

9% to 14% of chromium;

1.5% to 8% of molybdenum;

up to 8% of tungsten;

4% to 6% of aluminum;

1% to 3% of titanium;

up to 4.6% tantalum;

up to 2% hafnium;

up to 0.04% zirconium;

up to 0.05% carbon;

up to 0.04% boron;

up to 1% niobium;

and the balance nickel along with unavoidable residual elements in trace amounts, wherein the composition has a sum of the weight percentage of zirconium and boron that is up to 0.06%.

2. The additive manufacturing product as in claim 1 , wherein the sum of the weight percentage of zirconium and boron is up to 0.05%.

3. The additive manufacturing product as in claim 1 , wherein the sum of the weight percentage of zirconium and boron is 0.01% to 0.04%.

4. The additive manufacturing product as in claim 1 , wherein the composition includes 0.005% to 0.04% by weight zirconium.

5. The additive manufacturing product as in claim 1 , wherein the composition includes 0.005% to 0.04% by weight boron.

6. The additive manufacturing product as in claim 1 , wherein the composition comprises, by weight:

8% to 11% of cobalt;

9% to 12% of chromium;

2% to 6% of molybdenum;

2% to 6% of tungsten;

4% to 6% of aluminum;

1% to 3% of titanium;

up to 2% tantalum;

up to 2% hafnium;

up to 0.03% zirconium;

up to 0.04% carbon;

up to 0.03% boron;

up to 1% niobium;

and the balance nickel along with unavoidable residual elements in trace amounts.

7. The additive manufacturing product as in claim 1 , wherein the composition comprises, by weight, greater than 0 to about 0.03 carbon.

8. The additive manufacturing product as in claim 1 , wherein the composition is substantially free from tantalum, hafnium, niobium, and rhenium.

9. The additive manufacturing product as in claim 1 , wherein the composition has a weight ratio of molybdenum to tungsten (Mo/W) of 0.25 to 2.

10. The additive manufacturing product as in claim 1 , wherein the composition has a weight ratio of molybdenum to tungsten (Mo/W) of 0.25 to 1.

11. The additive manufacturing product as in claim 1 , wherein the fused multilayer component has an areal microcrack density of less than 0.1%.

12. The additive manufacturing product as in claim 1 , wherein the fused multilayer component has an areal microcrack density of less than 0.05%.

13. The additive manufacturing product as in claim 1 , wherein the composition consists essentially of, by weight:

7% to 11% of cobalt;

9% to 14% of chromium;

1.5% to 8% of molybdenum;

0.05% to 8% of tungsten;

4% to 6% of aluminum;

1% to 3% of titanium;

up to 0.04% zirconium;

up to 0.05% carbon;

up to 0.04% boron; and

the balance Ni along with unavoidable residual elements in trace amounts.

14. An additive manufactured product, comprising:

a fused multilayer component comprising a nickel superalloy, wherein the nickel superalloy has a composition comprising, by weight:

9% to 11% of cobalt;

10% to 12% of chromium;

2.5% to 3.5% of molybdenum;

5.5% to 6% of tungsten;

5% to 6% of aluminum;

1% to 2% of titanium;

0.005% to 0.015% zirconium;

0.01% to 0.03% carbon;

0.005% to 0.015% boron;

and the balance nickel,

wherein the fused multilayer component has an areal microcrack density of less than 0.1%.

15. The additive manufacturing product as in claim 14 , wherein the composition is substantially free from tantalum; hafnium; niobium, and rhenium.

16. A method of forming an additive manufacturing product, the method comprising:

forming a layer of powder;

bonding a portion of the powder to form a bonded layer portion; and

repeating the forming and bonding steps to form a fused multilayer component comprising a plurality of the bonded layer portions,

wherein the powder comprises a nickel superalloy having a composition comprising, by weight:

7% to 11% of cobalt;

9% to 14% of chromium;

1.5% to 8% of molybdenum;

up to 8% of tungsten;

4% to 6% of aluminum;

1% to 3% of titanium;

up to 4.6% tantalum;

up to 2% hafnium;

up to 0.04% zirconium;

up to 0.05% carbon;

up to 0.04% boron;

up to 1% niobium;

and the balance nickel,

wherein the composition has a sum of the weight percentage of zirconium and boron is up to 0.06%.

17. The method as in claim 16 , wherein the composition includes 0.005% to 0.04% by weight zirconium, and wherein the composition includes 0.005% to 0.04% by weight boron.

18. The method as in claim 16 , further comprising:

heat treating the fused multilayer component to recrystallize at least 50% by volume of the nickel superalloy, and wherein the fused multilayer component has an areal microcrack density of less than 0.1%.

19. The method as in claim 18 , wherein the fused multilayer component is heat treated at a temperature of 1150° C. or higher.

20. The method as in claim 16 , wherein bonding the portion of the powder comprises directing energy onto the powder to at least partially melt the portion of the powder to form the bonded layer portion.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 4, 2018
From: WESSMAN, ANDREW EZEKIEL; HANLON, TIMOTHY; DIAL, LAURA CERULLY
To: GENERAL ELECTRIC COMPANY
Reel/Frame 047666/0710 →
Cited By (4)
US 12,286,691 US 12,529,126 US 12,534,778 US 12,742,227