Gamma prime strengthened nickel superalloy for additive manufacturing
An additive manufactured product, along with methods of its formation, is provided. The additive manufactured product may include a fused multilayer component comprising a nickel superalloy having a composition comprising, by weight: 7% to 11% of cobalt; 9% to 14% of chromium; 1.5% to 8% of molybdenum; up to 8% of tungsten; 4% to 6% of aluminum; 1% to 4% of titanium; up to 4.6% tantalum; up to 2% hafnium; up to 0.04% zirconium; up to 0.05% carbon; up to 0.04% boron; up to 1% niobium; and the balance nickel along with unavoidable residual elements in trace amounts. This composition may have a sum of the weight percentages of zirconium and boron that is up to 0.06%.
1. An additive manufactured product, comprising:
a fused multilayer component comprising a nickel superalloy, wherein the nickel superalloy has a composition comprising, by weight:
7% to 11% of cobalt;
9% to 14% of chromium;
1.5% to 8% of molybdenum;
up to 8% of tungsten;
4% to 6% of aluminum;
1% to 3% of titanium;
up to 4.6% tantalum;
up to 2% hafnium;
up to 0.04% zirconium;
up to 0.05% carbon;
up to 0.04% boron;
up to 1% niobium;
and the balance nickel along with unavoidable residual elements in trace amounts, wherein the composition has a sum of the weight percentage of zirconium and boron that is up to 0.06%.
2. The additive manufacturing product as in claim 1 , wherein the sum of the weight percentage of zirconium and boron is up to 0.05%.
3. The additive manufacturing product as in claim 1 , wherein the sum of the weight percentage of zirconium and boron is 0.01% to 0.04%.
4. The additive manufacturing product as in claim 1 , wherein the composition includes 0.005% to 0.04% by weight zirconium.
5. The additive manufacturing product as in claim 1 , wherein the composition includes 0.005% to 0.04% by weight boron.
6. The additive manufacturing product as in claim 1 , wherein the composition comprises, by weight:
8% to 11% of cobalt;
9% to 12% of chromium;
2% to 6% of molybdenum;
2% to 6% of tungsten;
4% to 6% of aluminum;
1% to 3% of titanium;
up to 2% tantalum;
up to 2% hafnium;
up to 0.03% zirconium;
up to 0.04% carbon;
up to 0.03% boron;
up to 1% niobium;
and the balance nickel along with unavoidable residual elements in trace amounts.
7. The additive manufacturing product as in claim 1 , wherein the composition comprises, by weight, greater than 0 to about 0.03 carbon.
8. The additive manufacturing product as in claim 1 , wherein the composition is substantially free from tantalum, hafnium, niobium, and rhenium.
9. The additive manufacturing product as in claim 1 , wherein the composition has a weight ratio of molybdenum to tungsten (Mo/W) of 0.25 to 2.
10. The additive manufacturing product as in claim 1 , wherein the composition has a weight ratio of molybdenum to tungsten (Mo/W) of 0.25 to 1.
11. The additive manufacturing product as in claim 1 , wherein the fused multilayer component has an areal microcrack density of less than 0.1%.
12. The additive manufacturing product as in claim 1 , wherein the fused multilayer component has an areal microcrack density of less than 0.05%.
13. The additive manufacturing product as in claim 1 , wherein the composition consists essentially of, by weight:
7% to 11% of cobalt;
9% to 14% of chromium;
1.5% to 8% of molybdenum;
0.05% to 8% of tungsten;
4% to 6% of aluminum;
1% to 3% of titanium;
up to 0.04% zirconium;
up to 0.05% carbon;
up to 0.04% boron; and
the balance Ni along with unavoidable residual elements in trace amounts.
14. An additive manufactured product, comprising:
a fused multilayer component comprising a nickel superalloy, wherein the nickel superalloy has a composition comprising, by weight:
9% to 11% of cobalt;
10% to 12% of chromium;
2.5% to 3.5% of molybdenum;
5.5% to 6% of tungsten;
5% to 6% of aluminum;
1% to 2% of titanium;
0.005% to 0.015% zirconium;
0.01% to 0.03% carbon;
0.005% to 0.015% boron;
and the balance nickel,
wherein the fused multilayer component has an areal microcrack density of less than 0.1%.
15. The additive manufacturing product as in claim 14 , wherein the composition is substantially free from tantalum; hafnium; niobium, and rhenium.
16. A method of forming an additive manufacturing product, the method comprising:
forming a layer of powder;
bonding a portion of the powder to form a bonded layer portion; and
repeating the forming and bonding steps to form a fused multilayer component comprising a plurality of the bonded layer portions,
wherein the powder comprises a nickel superalloy having a composition comprising, by weight:
7% to 11% of cobalt;
9% to 14% of chromium;
1.5% to 8% of molybdenum;
up to 8% of tungsten;
4% to 6% of aluminum;
1% to 3% of titanium;
up to 4.6% tantalum;
up to 2% hafnium;
up to 0.04% zirconium;
up to 0.05% carbon;
up to 0.04% boron;
up to 1% niobium;
and the balance nickel,
wherein the composition has a sum of the weight percentage of zirconium and boron is up to 0.06%.
17. The method as in claim 16 , wherein the composition includes 0.005% to 0.04% by weight zirconium, and wherein the composition includes 0.005% to 0.04% by weight boron.
18. The method as in claim 16 , further comprising:
heat treating the fused multilayer component to recrystallize at least 50% by volume of the nickel superalloy, and wherein the fused multilayer component has an areal microcrack density of less than 0.1%.
19. The method as in claim 18 , wherein the fused multilayer component is heat treated at a temperature of 1150° C. or higher.
20. The method as in claim 16 , wherein bonding the portion of the powder comprises directing energy onto the powder to at least partially melt the portion of the powder to form the bonded layer portion.