Solid electrolyte material and battery using same
The solid electrolyte material of the present disclosure includes Li, M, O, X, and F. M is at least one element selected from the group consisting of Ta and Nb. X is at least one element selected from the group consisting of Cl, Br, and I.
1. A solid electrolyte material consisting of:
Li, M, O, X, and F, wherein
M is at least one element selected from the group consisting of Ta and Nb;
X is at least one element selected from the group consisting of Cl, Br, and I; and
the solid electrolyte material includes a first crystal phase having a peak in a first range in which the value of diffraction angle 2θ is 13.7° or more and 14.8° or less in an X-ray diffraction pattern obtained by X-ray diffraction measurement using Cu-Kα rays.
2. The solid electrolyte material according to claim 1 , wherein X includes Cl.
3. The solid electrolyte material according to claim 2 , wherein
the X-ray diffraction pattern further includes a peak resulting from the first crystal phase in a second range in which the value of diffraction angle 20 is 24.0° or more and 25.3° or less.
4. The solid electrolyte material according to claim 1 , wherein
a molar proportion of F to the sum of X and F is 1% or more and 50% or less.
5. The solid electrolyte material according to claim 4 , wherein
the molar proportion is 1% or more and 10% or less.
6. The solid electrolyte material according to claim 4 , wherein
the molar proportion is 10% or more and 50% or less.
7. The solid electrolyte material according to claim 1 , further comprising:
a second crystal phase that is different from the first crystal phase.
8. A battery comprising:
a positive electrode;
a negative electrode; and
an electrolyte layer disposed between the positive electrode and the negative electrode, wherein
at least one selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte layer contains the solid electrolyte material according to claim 1 .
9. The solid electrolyte material according to claim 1 , wherein
the peak in the first range in which the value of diffraction angle 2θ is 13.7° or more and 13.96° or less.