Nonaqueous electrolyte secondary battery separator, nonaqueous electrolyte secondary battery member, and nonaqueous electrolyte secondary battery
A nonaqueous electrolyte secondary battery separator having excellent impact absorbency includes a polyolefin porous film having a full width W at half maximum of a peak of an MD component of not less than 30 degrees. The full width W at half maximum of the peak of the MD component is calculated from an azimuthal profile of a scattering peak on a plane obtained by wide-angle X-ray scattering measurement that is carried out by irradiating a surface of the polyolefin porous film with an X-ray from a direction vertical to the surface of the polyolefin porous film, and/or having a maximum-to-minimum intensity ratio r of not more than 3.6. The maximum-to-minimum intensity ratio r is calculated from a Fourier transformed azimuthal profile obtained by observing the surface of the polyolefin porous film by SEM.
1. A nonaqueous electrolyte secondary battery separator comprising:
a polyolefin porous film,
the polyolefin porous film satisfying any one or more of the following conditions (1) and (2):
(1) a full width W at half maximum of a peak of an MD component is not less than 30 degrees, the full width W at half maximum of the peak being calculated from an azimuthal profile of a scattering peak on a (110) plane obtained by wide-angle X-ray scattering measurement that is carried out by irradiating a surface of the polyolefin porous film with an X-ray from a direction vertical to the surface of the polyolefin porous film, wherein, assuming that, in the azimuthal profile, a peak height is a difference between a maximum scattering intensity of a peak observed in a TD and a minimum scattering intensity of a valley which is adjacent to the peak and has a lowest intensity, the full width W at half maximum of the peak is a width of the peak at a scattering intensity at which the peak height is halved; and
(2) a maximum-to-minimum intensity ratio r is not more than 3.6 in a Fourier transformed azimuthal profile obtained by observing the surface of the polyolefin porous film by a scanning electron microscope, wherein the maximum-to-minimum intensity ratio r is calculated, with use of a maximum value I max1 and a minimum value I min1 in a range of 45 degrees to 135 degrees and a maximum value I max2 and a minimum value I min2 in a range of 135 degrees to 225 degrees in the Fourier transformed azimuthal profile, by the following formula (A):
r =( I max1 /I min1 +I max2 /I min2 )/2 (A).
2. The nonaqueous electrolyte secondary battery separator according to claim 1 , wherein the polyolefin porous film satisfies the following (a) to (e):
(a) a film thickness is not less than 5 μm and less than 18 μm;
(b) an air permeability (Gurley value) per film thickness of 13 μm is 50 sec/100 cc to 200 sec/100 cc;
(c) an MD breaking elongation ratio is not less than 20% GL;
(d) an MD breaking strength is 50 MPa to 190 MPa; and
(e) a TD breaking elongation ratio is 20% GL to 300% GL.
3. The nonaqueous electrolyte secondary battery separator according to claim 1 , wherein the polyolefin porous film contains a wax component having a weight-average molecular weight of 1,000 to 4,000.
4. The nonaqueous electrolyte secondary battery separator according to claim 1 , further comprising:
a porous layer containing a resin,
the porous layer being formed on one surface or on both surfaces of the polyolefin porous film.
5. The nonaqueous electrolyte secondary battery separator according to claim 4 , wherein the resin is an aramid resin.
6. A nonaqueous electrolyte secondary battery member comprising:
a positive electrode;
the nonaqueous electrolyte secondary battery separator according to claim 1 ; and
a negative electrode,
the positive electrode, the nonaqueous electrolyte secondary battery separator, and the negative electrode being arranged in this order.
7. A nonaqueous electrolyte secondary battery comprising:
the nonaqueous electrolyte secondary battery separator according to claim 1 .