Separator for power storage device
The purpose of the present invention is to provide a separator which is for a power storage device, and which has high strength and can be thinned. The separator for a power storage device has a microporous membrane containing polyolefin as a main component, wherein the melt tension of the microporous membrane as measured at a temperature of 230° C. is 30 mN or less, and the melt flow rate (MFR) of the microporous membrane as measured under a load of 2.16 kg and at a temperature of 230° C. is 0.9 g/10 min or less.
1. A separator for a power storage device, comprising a microporous membrane containing a polyolefin as a primary component, wherein
a melt tension of the microporous membrane measured at a temperature of 230° C. is 30 mN or less, and
a melt flow rate (MFR) of the microporous membrane measured under a load of 2.16 kg at a temperature of 230° C. is 0.9 g/10 min or less.
2. The separator for a power storage device according to claim 1 , wherein an area ratio (MD/TD) of (110) crystal peak as measured by wide-angle X-ray scattering of the microporous membrane containing a polyolefin as a primary component is 1.3 or more.
3. The separator for a power storage device according to claim 1 , wherein the polyolefin is polypropylene, and the MFR of the polypropylene measured under a load of 2.16 kg at a temperature of 230° C. is 0.3 to 0.9 g/10 min.
4. The separator for a power storage device according to claim 3 , wherein a pentad fraction of the polypropylene as measured by 13C-NMR (nuclear magnetic resonance) is 95.0% or more.
5. The separator for a power storage device according to claim 4 , wherein the pentad fraction of the polypropylene is 97.0% or more.
6. The separator for a power storage device according to claim 1 , wherein the melt tension of the microporous membrane is 20 mN to 30 mN.
7. The separator for a power storage device according to claim 1 , wherein a value (Mw/Mn) obtained by diving the weight average molecular weight (Mw) of the polypropylene by the number average molecular weight (Mn) thereof is 7 or less.
8. The separator for a power storage device according to claim 1 , wherein the polyolefin is polypropylene, the microporous membrane further comprises an elastomer, and the MFR of the polypropylene measured under a load of 2.16 kg at a temperature of 230° C. is 0.6 g/10 min or less.
9. The separator for a power storage device according to claim 8 , wherein the elastomer has a propylene structure as a repeating unit.
10. The separator for a power storage device according to claim 8 , wherein the pentad fraction of the polypropylene as measured by 13C-NMR (nuclear magnetic resonance) is 95.0% or more.
11. The separator for a power storage device according to claim 1 , wherein the separator for a power storage device has a multilayer structure comprising the microporous membrane and a microporous membrane containing polyethylene as a primary component.
12. The separator for a power storage device according to claim 11 , wherein a thickness of the multilayer structure is 18 μm or less, and the separator for a power storage device has an air permeability of 300 s/100 cc·14 μm or less, and a puncture strength of 300 gf/14 μm or more, which are calculated by converting the thickness into 14 μm.
13. A power storage device, comprising a positive electrode, a negative electrode, and the separator for a power storage device according to claim 1 laminated between the positive electrode and the negative electrode.