Electrochemical element, method for producing same, and electrochemical device
View Patent ↗An electrochemical element includes a current collector, and an active material layer on the current collector, wherein the active material layer includes active material particles each having a lithium silicate composite particle including a lithium silicate phase and silicon particles dispersed therein, and a first coating that covers at least a portion of a surface of the lithium silicate composite particle, the first coating includes an oxide of a first element other than a non-metal element, and the active material layer has a thickness TA, and T1b<T1t, where T1b is a thickness of the first coating covering the lithium silicate composite particle at a position of 0.25 TA from the current collector surface in the active material layer, and T1t is a thickness of the first coating covering the lithium silicate composite particle at a position of 0.75 TA from the current collector surface in the active material layer.
1 . An electrochemical element comprising a current collector, and an active material layer supported on the current collector, wherein
the active material layer includes active material particles,
the active material particles each include a lithium silicate composite particle including a lithium silicate phase and silicon particles dispersed in the lithium silicate phase, and a first coating that covers at least a portion of a surface of the lithium silicate composite particle,
the first coating includes an oxide of a first element other than a non-metal element, and
the active material layer has a thickness TA, and T1b<T1t is satisfied, where
T1b is a thickness of the first coating that covers the lithium silicate composite particle at a position of 0.25TA from the surface of the current collector in the active material layer, and
T1t is a thickness of the first coating that covers the lithium silicate composite particle at a position of 0.75TA from the surface of the current collector in the active material layer.
2 . The electrochemical element of claim 1 , wherein the thickness T1b and the thickness T1t satisfy 0.02≤T1b/T1t<1.
3 . The electrochemical element of claim 1 , wherein the first element includes at least one element selected from the group consisting of Group 3 elements, Group 4 elements, Group 5 elements, and Group 6 elements of a periodic table.
4 . The electrochemical element of claim 1 , wherein the first element includes at least one selected from the group consisting of Al, Ti, Si, Zr, Mg, Nb, Ta, Sn, Ni, and Cr.
5 . The electrochemical element of claim 1 , wherein the first coating has an average thickness T1 A of 0.1 nm or more and 50 nm or less.
6 . The electrochemical element of claim 1 , wherein
Cb>Ct is satisfied, where
Cb is a concentration by atomic ratio of the first element at a position of 0.25T1 from the surface of the lithium silicate composite particle in the first coating, and
Ct is a concentration by atomic ratio of the first element at a position of 0.75T1 from the surface of the lithium silicate composite particle in the first coating.
7 . The electrochemical element of claim 6 , wherein the concentration Cb and the concentration Ct satisfy Cb/Ct>2.
8 . The electrochemical element of claim 1 , wherein the first coating further includes carbon atoms.
9 . The electrochemical element of claim 8 , wherein Rb>Rt is satisfied, where
Rb is an atomic ratio of the first element relative to the carbon atom in the first coating at a position of 0.25T1 from the surface of the lithium silicate composite particle, and
Rt is an atomic ratio of the first element relative to the carbon atom in the first coating at a position of 0.75T1 from the surface of the lithium silicate composite particle.
10 . The electrochemical element of claim 9 , wherein the atomic ratio Rb and the atomic ratio Rt satisfy Rb/Rt>1.3.
11 . The electrochemical element of claim 9 , wherein the atomic ratio Rb is 5 or more and 99 or less.
12 . The electrochemical element of claim 9 , wherein the atomic ratio Rt is 0.01 or more and 10 or less.
13 . The electrochemical element of claim 1 , wherein at least a portion of the first coating is further covered with an electrically conductive second coating including carbon atoms.
14 . The electrochemical element of claim 13 , wherein an average thickness T1 A and an average thickness T2 A satisfy the relation of 0<T2 A /T1 A <1500, where
T1 A is an average thickness of the first coating that covers at least a portion of the surface of the lithium silicate composite particle, and
T2 A is an average thickness of the electrical conductive second coating.
15 . An electrochemical device including a first electrode, a second electrode, and a separator interposed therebetween, wherein
one of the first electrode and the second electrode is composed of the electrochemical element of claim 1 .