IP Library Granted Patent US 11,945,151
Granted Patent B2
US 11,945,151 · App. 17/820,144 · Granted Apr 2, 2024

Additively manufacturing bio-based conductive shape memory polymer macostructure parts with highly ordered microstructures

Inventors: Jennifer Nicole Rodriguez (Fremont, CA); Eric B. Duoss (Dublin, CA); James Lewicki (Oakland, CA); Christopher Spadaccini (Oakland, CA); Thomas S. Wilson (Oakland, CA); Cheng Zhu (Livermore, CA)
Assignee: Lawrence Livermore National Security, LLC
B29C64/106B29C64/165B29C64/209B29C64/321B29C64/393B33Y70/10C08K3/046C08K7/04C08L63/00C08L91/00B29K2063/00B29K2105/124B29K2507/04B33Y10/00B33Y30/00B33Y50/02B33Y80/00C08K2201/011
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Quick Facts
Patent No.
US 11,945,151
App. No.
17/820,144
Granted
Apr 2, 2024
Kind
B2
Abstract

An additive manufacturing apparatus includes an additive manufacturing print head and a nozzle that receives a bio-based shape memory polymer material and a bio-based material. The nozzle extrudes the bio-based shape memory polymer material and the bio-based material onto a substrate to form a bio-based shape memory polymer part or product.

Claims (13)

1. An additive manufacturing method for producing a part or a product, comprising:

providing an additive manufacturing substrate;

positioning an additive manufacturing print head in operative position relative to said additive manufacturing substrate;

providing bio-based shape memory polymer additive manufacturing material in said additive manufacturing print head; and

using an additive manufacturing control system to provide movement of said additive manufacturing print head relative to said additive manufacturing substrate and to extrude said bio-based shape memory polymer additive manufacturing material from said additive manufacturing print head onto said additive manufacturing substrate to form the part or product

wherein said bio-based shape memory polymer additive manufacturing material includes components of shape memory polymer material and bio-based material and

wherein said step of providing bio-based shape memory polymer additive manufacturing material in said additive manufacturing print head comprises the steps of

adding carbon nano fibers fillers to epoxidized soy bean oil and Bisphenol A diglycidyl ether thermoset base resin to from an intermediate material,

adding acetone to said intermediate material,

sonicating said intermediate material,

mixing said intermediate material,

drying said intermediate material, and

degassing said intermediate material.

Assignments (2)
CONFIRMATORY LICENSE (SEE DOCUMENT FOR DETAILS) Recorded Sep 19, 2022
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 061468/0016 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 23, 2022
From: RODRIGUEZ, JENNIFER NICOLE; DUOSS, ERIC B.; LEWICKI, JAMES; SPADACCINI, CHRISTOPHER; WILSON, THOMAS S.; ZHU, CHENG
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 060874/0378 →
Continuity (2)
Division 15762494 · Mar 22, 2018
Related Publication 20220402194A1 · Dec 22, 2022