IP Library › Granted Patent US 12,564,807
Granted Patent B2
US 12,564,807 · App. 17/954,820 · Granted Mar 3, 2026

Dewatering viscous liquids with pressurized carbon dioxide

Inventors: Osei Asafu-Adjaye (Auburn, AL); Brian Via (Opelika, AL); Bhima Sastri (North Potomac, MD); Sujit Banerjee (Marietta, GA)
Assignee: AUBURN UNIVERSITY
B01D43/00B01J20/261B01J20/3425B01J20/345C13B25/00D21C11/0007D21C11/0042
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Quick Facts
Patent No.
US 12,564,807
App. No.
17/954,820
Granted
Mar 3, 2026
Kind
B2
Abstract

Methods of dewatering viscous materials are provided. The method comprises contacting the viscous material with pressurized carbon dioxide at a temperature and for a time wherein at least a fraction of water is expressed from the viscous material. Then the pressure is released, and the water expressed from the viscous material is removed to yield a dewatered product. Exemplary viscous materials that can be dewatered by the method include black liquor from wood pulping operations, wet lignin, wet super water absorbent polymers and sugar solutions. The pressurized carbon dioxide is present in subcritical or supercritical form. The method provides dewatering at reduced cost.

Claims (25)

1 . A method of dewatering a viscous material, comprising:

i) contacting the viscous material with pressurized carbon dioxide at a temperature and for a time wherein at least a fraction of water is expressed from the viscous material; and

ii) releasing the pressure and removing the water expressed from the viscous material to yield a dewatered product.

2 . The method of claim 1 , wherein the fraction of water expressed from the viscous material exceeds the solubility of water in the pressurized carbon dioxide.

3 . The method of claim 1 , wherein the viscous material has a viscosity of between about 2 and about 30,000 centipoise.

4 . The method of claim 1 , comprising contacting the viscous material with the pressurized carbon dioxide for between about 10 milliseconds and about 3 hours.

5 . The method of claim 1 , wherein the carbon dioxide is present in supercritical form.

6 . The method of claim 5 , wherein the temperature of the carbon dioxide is between about 31° C. and about 200° C.

7 . The method of claim 5 , wherein the pressure of the carbon dioxide is between about 1,080 psi and about 4,000 psi.

8 . The method of claim 1 , wherein the carbon dioxide is present in subcritical form.

9 . The method of claim 1 , wherein the viscous material has a solids content of between about 0.01% and about 95%.

10 . The method of claim 1 , wherein the viscous material is black liquor from a wood pulping operation.

11 . The method of claim 10 , wherein the black liquor has a solids content of between about 10% and about 95%.

12 . The method of claim 10 , wherein the viscous material is softwood black liquor.

13 . The method of claim 10 , wherein the viscous material is hardwood black liquor.

14 . The method of claim 1 , wherein the viscous material is wet lignin.

15 . The method of claim 14 , wherein the wet lignin has a solids content of between about 10% and about 95%.

16 . The method of claim 1 , wherein the viscous material is a mixture of a superabsorbent polymer and water.

17 . The method of claim 16 , wherein the superabsorbent polymer is sodium polyacrylate.

18 . The method of claim 1 , wherein the viscous material is a mixture of a carbohydrate and water.

19 . The method of claim 18 , wherein the mixture of a carbohydrate and water has a solids content of between about 10% and about 95%.

20 . The method of claim 18 , wherein the carbohydrate is a sugar.

21 . The method of claim 1 , wherein the carbon dioxide interacts with components of the viscous material to increase solid contents of the viscous material.

22 . The method of claim 21 , wherein the viscous material is black liquor from a wood pulping operation.

23 . The method of claim 21 wherein the viscous material is wet lignin.

Assignments (2)
CONFIRMATORY LICENSE Recorded Mar 7, 2024
From: AUBURN UNIVERSITY
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 066749/0789 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 28, 2024
From: ASAFU-ADJAYE, OSEI; VIA, BRIAN; SASTRI, BHIMA; BANERJEE, SUJIT
To: AUBURN UNIVERSITY
Reel/Frame 066592/0584 →
Continuity (2)
Provisional Application 63249847 · Sep 29, 2021
Related Publication 20230115487A1 · Apr 13, 2023
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