Protective carbon layer for lithium (Li) metal anodes
This disclosure provides a battery including a cathode, an anode positioned opposite the cathode and a carbon interface layer. The carbon interface layer includes an electrically insulating flaky carbon layer conformally encapsulating the anode. A plurality of carbon nano-onions (CNOs) defining a plurality of interstitial pore volumes are interspersed throughout the electrically insulating flaky carbon layer. An electrolyte is in contact with the carbon interface layer and the cathode. A separator is positioned between the anode and the cathode. The electrically insulating flaky carbon layer can include graphene oxide (GO). The plurality of interstitial pore volumes can be configured to transport lithium (Li) ions between the anode and the cathode via the plurality of interstitial pore volumes in a bulk phase of the electrolyte. The carbon interface layer can be configured to inhibit growth of Li dendritic structures from the anode towards the cathode.
1. A battery comprising:
a cathode and an anode separated by a separator layer;
an electrically insulating carbon layer at least partially encapsulating the anode;
a plurality of carbon nano-onions (CNOs) defining one or more interstitial pores interspersed throughout the electrically insulating carbon layer; and
an electrolyte in contact with the electrically insulating carbon layer and the cathode.
2. The battery of claim 1 , wherein the electrically insulating carbon layer comprises graphene oxide.
3. The battery of claim 1 , wherein the one or more interstitial pores are configured to transport lithium ions between the anode and the cathode in a bulk phase of the electrolyte.
4. The battery of claim 1 , wherein the cathode further comprises a porous carbon-based structure configured to expand and contract a volume of the cathode during operational cycling of the battery.
5. The battery of claim 1 , further comprising a film, having a Young's modulus greater than approximately 6 GPa, disposed on the electrically insulating carbon layer.
6. The battery of claim 1 , wherein the electrically insulating carbon layer is configured to inhibit growth of Lithium dendritic structures from the anode.
7. The battery of claim 1 , wherein the separator layer is configured to transport lithium ions between the anode and the cathode.
8. The battery of claim 1 , wherein at least some of the plurality of CNOs have a surface area of approximately 10 m 2 /g to 90 m 2 /g.
9. The battery of claim 1 , wherein the plurality of CNOs is configured to adsorb polysulfide produced at or near the cathode.
10. The battery of claim 9 , wherein the plurality of CNOs is further configured to inhibit polysulfide anions from contacting the anode.
11. The battery of claim 1 , wherein the anode comprises a metal foil.
12. The battery of claim 1 , wherein the anode comprises a carbon-based composite structure including one or more of a plurality of carbon nano-onions or a plurality of graphene platelets fused together.
13. The battery of claim 12 , wherein the carbon-based composite structure is configured to be infiltrated by a molten lithium metal.
14. The battery of claim 13 , wherein the molten Lithium metal includes one or more Lithium-containing droplets, Lithium-containing domains, single crystalline domains, or poly-crystalline domains.
15. The battery of claim 1 , wherein the electrically insulating carbon layer comprises interlayer pi-pi bonds.
16. The battery of claim 1 , wherein the electrically insulating carbon layer includes a stack comprising two or more electrically insulating carbon films, wherein each electrically insulating carbon film is substantially flat.
17. The battery of claim 16 , wherein the stack is configured to inhibit crack growth in the anode.
18. The battery of claim 16 , wherein the stack further comprises a plurality of gap regions.
19. The battery of claim 18 , wherein the stack further comprises a binder.
20. The battery of claim 1 , wherein the electrically insulating carbon layer is configured to produce lithium hydroxide (LiOH) based on a chemical reaction with Lithium metal provided by the anode.