IP Library Granted Patent US 11,999,907
Granted Patent B2
US 11,999,907 · App. 17/993,378 · Granted Jun 4, 2024

Hydraulic fracture composition and method

Inventors: Calder Hendrickson (Lubbock, TX); Tommy K. Thrash (Lubbock, TX); Todd Naff (Lubbock, TX)
Assignee: Aquasmart Enterprises, LLC
C09K8/805
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Quick Facts
Patent No.
US 11,999,907
App. No.
17/993,378
Granted
Jun 4, 2024
Kind
B2
Abstract

A method for improving the performance of fracturing processes in oil production fields may rely on polymer coated particles carried in the fracturing fluid. The particles may include heavy substrates, such as sand, ceramic sand, or the like coated with polymers selected to absorb water, increasing the area and volume to travel more readily with the flow of fluid without settling out, or allowing the substrate to settle out. Ultimately, the substrate may become lodged in the fissures formed by the pressure or hydraulic fracturing, resulting in propping open of the fissures for improved productivity.

Claims (41)

1. A method for producing a coated proppant particle, the method comprising:

providing a substrate, constituted as discrete particles;

providing a water soluble material as a binder;

providing a first composition containing a polymer, and formed as a first powder, wherein the substrate has a first density and the first powder has a second density, the first density being greater than the second density;

coating the substrate individually with the binder;

forming granules by coating the binder on the substrate individually with the first powder;

providing a second composition containing a flowing agent to increase flowability of the resultant granules, and formed as a second powder, wherein the second composition is selected from the group consisting of sodium aluminosilicate, fumed silica, potassium aluminosilicate, calcium aluminosilicate, silicon dioxide, calcium silicate, powdered cellulose, and whey protein; and

forming granules by coating the first powder on the substrate individually with the second powder, wherein the coated proppant particles are configured to remain suspended in a 1000 ppm CaCO3 aqueous solution for at least 30 minutes at a temperature of approximately 170° F.

2. The method of claim 1 , wherein the second composition consists of whey protein and fumed silica.

3. The method of claim 1 , wherein the second composition consists of whey protein and sodium aluminosilicate.

4. The method of claim 1 , wherein the first and second densities are selected, and the size of the granules is selected to effect sinking the polymer, by the substrate, into a fluid.

5. The method of claim 4 , wherein the fluid is moving as a carrier, characterized by a viscosity, and the polymer is selected based on its effectiveness to increase in size by absorbing the fluid.

6. The method of claim 1 , wherein the substrate is a proppant selected from the group consisting of a sand, a ceramic, and a rock product.

7. A method for producing a coated proppant particle, the method comprising:

providing a substrate, wherein the substrate is a discrete particle;

providing a water soluble binder;

providing a first composition containing a polymer, and formed as a first powder, wherein the substrate has a first density and the first powder has a second density, the first density being greater than the second density;

coating the substrate individually with the binder;

forming granules by coating the binder on the substrate individually with the first powder;

providing a second composition containing a flowing agent to increase flowability of the resultant granules, and formed as a second powder; and

forming granules by coating the first powder on the substrate individually with the second powder, wherein the coated proppant particles are configured to remain suspended in a 1000 ppm CaCO3 aqueous solution for at least 30 minutes at a temperature of approximately 170° F.

8. The method of claim 7 , wherein the second composition is selected from the group consisting of sodium aluminosilicate, fumed silica, potassium aluminosilicate, calcium aluminosilicate, silicon dioxide, calcium silicate, powdered cellulose, and whey protein.

9. The method of claim 7 , wherein the first and second densities are selected, and the size of the granules is selected to effect sinking the polymer, by the substrate, into a fluid.

10. The method of claim 9 , wherein the fluid is moving as a carrier, characterized by a viscosity, and the polymer is selected based on its effectiveness to increase in size by absorbing the fluid.

11. The method of claim 7 , wherein the second composition consists of whey protein and fumed silica.

12. The method of claim 7 , wherein the second composition consists of whey protein and sodium aluminosilicate.

13. A method for producing a coated proppant particle, the method comprising:

providing a substrate, wherein the substrate is a discrete particle;

providing a water soluble binder;

providing a first composition containing a polymer, and formed as a first powder, wherein the substrate has a first density and the first powder has a second density, the first density being greater than the second density;

coating the substrate individually with the binder;

forming granules by coating the binder on the substrate individually with the first powder;

providing a second composition containing a flowing agent to increase flowability of the resultant granules, and formed as a second powder; and

forming granules by coating the first powder on the substrate individually with the second powder, wherein the coated proppant particles are configured to remain suspended in a 1000 ppm CaCO3 aqueous solution for at least 30 minutes at approximately room temperature.

14. The method of claim 13 , wherein the second composition is selected from the group consisting of sodium aluminosilicate, fumed silica, potassium aluminosilicate, calcium aluminosilicate, silicon dioxide, calcium silicate, powdered cellulose, and whey protein.

15. The method of claim 13 , wherein the second composition consists of whey protein and fumed silica.

16. The method of claim 13 , wherein the second composition consists of whey protein and sodium aluminosilicate.

17. The method of claim 14 , wherein the first and second densities are selected, and the size of the granules is selected to effect sinking the polymer, by the substrate, into a fluid.

18. The method of claim 17 , wherein the fluid is moving as a carrier, characterized by a viscosity, and the polymer is selected based on its effectiveness to increase in size by absorbing the fluid.

19. The method of claim 13 , wherein the substrate is a proppant selected from the group consisting of a sand, a ceramic, and a rock product.

20. The method of claim 14 , wherein the second composition comprises a plurality of flowing agents, distinct from one another.

Continuity (12)
Continuation 17202774 · Mar 16, 2021
Continuation 16253934 · Jan 22, 2019
Continuation 15416950 · Jan 26, 2017
Continuation In Part 15136352 · Apr 22, 2016
Continuation In Part 15011111 · Jan 29, 2016
Continuation In Part 14171920 · Feb 4, 2014
Continuation 13418227 · Mar 12, 2012
Continuation In Part 13299288 · Nov 17, 2011
Continuation In Part 12789177 · May 27, 2010
Continuation 12324608 · Nov 26, 2008
Provisional Application 61012912 · Dec 11, 2007
Related Publication 20230159817A1 · May 25, 2023