Composite membrane comprising highly permeable gutter layer and method for preparing same
The present disclosure relates to a composite membrane in which a rubbery polymer is introduced into a gutter layer to suppress the physical aging of the highly permeable composite membrane, and more particularly, to a composite membrane comprising a porous support layer; a gutter layer on the porous support layer; and an active layer on the gutter layer, wherein the gutter layer comprises a blend of poly(l-trimethlsilyl-l-propyne) (PTMSP) and a rubbery polymer and a method for preparing the same. The composite membrane according to the present disclosure has high permeation performance and a remarkable decline in physical aging leading to a decrease in permeability over time and thus has very high industrial applicability.
1. A composite membrane, comprising:
a porous support layer;
a gutter layer on the porous support layer; and
an active layer on the gutter layer,
wherein the gutter layer comprises a blend of poly(l-trimethylsilyl-l-propyne) (PTMSP) and a rubbery polymer,
wherein a mix ratio of the poly (l-trimethylsilyl-l-propyne) (PTMSP) and the rubbery polymer in the polymer blend ranges from 9:1 to 5:5 by weight.
2. The composite membrane according to claim 1 , wherein the porous support layer is at least one polymer selected from polysulfone, polyethersulfone, polyetherethersulfone, polyphenylsulfone, polyacrylonitrile, polyetherimide, polyimide, polyamide, polyimide-amide, polyethylene, polyethyleneterephthalate, polyetherketone, polyetheretherketone, polyurethane, nylon and polyvinylidenefluoride.
3. The composite membrane according to claim 1 , wherein the active layer is at least one polymer selected from acetylated methyl cellulose, polymers of intrinsic microporosity, thermally rearranged polymers and perfluoropolymers.
4. The composite membrane according to claim 1 , wherein the rubbery polymer is at least one polymer selected from polydimethlysiloxane (PDMS), silicone-based rubber, polybutadiene, nitrile rubber, acrylic rubber, butyl rubber, polyisoprene and poly (styrene-co-butadiene).
5. A method for preparing a composite membrane, comprising:
forming a porous support layer;
forming a gutter layer of a blend of (l-trimethylsilyl-l-propyne) (PTMSP) and rubbery polymer on the porous support layer; and
forming an active layer on the gutter layer
wherein a mix ratio of the poly (l-trimethylsilyl-l-propyne) (PTMSP) and the rubbery polymer in the polymer blend ranges from 9:1 to 5:5 by weight.
6. The method for preparing a composite membrane according to claim 5 , wherein the step of forming the gutter layer comprises preparing a mixed solution of the poly (l-trimethylsilyl-l-propyne) (PTMSP) and the rubbery polymer using an organic solvent and forming a film on water by water casting.
7. The method for preparing a composite membrane according to claim 6 , wherein the organic solvent in the step of forming the gutter layer is at least one selected from chloroform, dipropylamine, isobutanol, cyclohexene, butanol, isovaleric acid, ethylether, isoamyl alcohol, ethylacetate, pentanol, 2-pentanone, hexanol, heptanol, acetic anhydride, pentyl acetate, octanol, cyclohexane, 2-hexanone, n-butyronitrile, diethylcarbonate, cyclohexanol, heptaldehyde, t-butyl chloride, benzyl alcohol, nitromethane, diisobutyl ketone, aniline and acetophenone.
8. The method for preparing a composite membrane according to claim 6 , wherein the mixed solution in the step of forming the gutter layer comprises the poly(l-trimethylsilyl-l-propyne) (PTMSP) and the rubbery polymer in an amount ranging from 0.01 to 10 weight %.