IP Library Granted Patent US 12,731,806
Granted Patent B2
US 12,731,806 · App. 18/031,751 · Granted Sep 8, 2026

Electrolyte regeneration for organic redox flow batteries based on water-soluble phenazine-based compounds

Inventors: Olga Ekkert (Hanau, DE); Evgeny Larionov (Hanau, DE); Jan Hartwig (Alezenau, DE); Eduard Baal (Offenbach, DE)
Assignee: CMBLU Energy AG
H01M8/188C01C3/12C07D241/46H01M8/04276
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Quick Facts
Patent No.
US 12,731,806
App. No.
18/031,751
Granted
Sep 8, 2026
Kind
B2
Abstract

The present invention provides a process for the regeneration of an electrolyte solution of a redox-flow battery containing at least one (preferably substituted) phenazine compound, said process comprising at least one of the following steps (a), (b) and (c): (a) treatment of the electrolyte solution to be regenerated in order to convert organic degradation compounds contained therein to a (substituted) phenazine compound; (b) removal of precipitated material from the electrolyte solution and subsequent modification of the precipitated organic degradation compounds to obtain a (substituted) phenazine compound; and (c) separation of redox active compounds other than (substituted) phenazine compounds in particular inorganic electrolytes, from an electrolyte solution containing (substituted) phenazine compounds, and/or separation of (substituted) phenazine compounds from a solution containing redox active compounds other than (substituted) phenazine compounds.

Claims (7)

1 . A process for the regeneration of an electrolyte solution of a redox-flow battery containing at least one phenazine compound, the process comprising:

treating the electrolyte solution to be regenerated to convert organic degradation compounds contained therein to a phenazine compound;

wherein the phenazine compound is selected from the group consisting of:

2 . The process of claim 1 , wherein the electrolyte solution is an aqueous solution.

3 . The process of claim 1 , wherein the electrolyte solution further contains a base, wherein the base is sodium or potassium hydroxide.

4 . The process of claim 1 , wherein the electrolyte solution is treated with an oxidizing agent.

5 . The process of claim 4 , wherein the oxidizing agent is O 2 or H 2 O 2 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 22, 2025
From: EKKERT, OLGA; LARIONOV, EVGENY; BAAL, EDUARD
To: CMBLU ENERGY AG
Reel/Frame 072323/0073 →
Continuity (1)
Related Publication 20230411662A1 · Dec 21, 2023
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