IP Library Granted Patent US 12,059,706
Granted Patent B2
US 12,059,706 · App. 18/100,124 · Granted Aug 13, 2024

Methods for preparing coating compositions for protecting oilfield operational components

Inventors: Greg Andrews (Wilmington, DE); George D. Andrews (Wilmington, DE); Jeff Capell (Wilmington, DE)
Assignee: S+S INDUSTRIES TECHNOLOGY LLC
B05D7/586B05D1/02B05D1/08B05D1/18B05D1/38B05D3/12B05D5/00B05D7/14B05D7/16B05D7/22B05D7/222B05D7/225B05D7/26B05D7/544B05D7/546B05D7/584C08G77/08C08G77/20C08K3/22C08K5/5425C09D5/002C09D5/082C09D5/084C09D7/20C09D7/61C09D7/62C09D7/63C09D159/00C09D163/04C09D183/04C09D183/06C23F11/18E21B33/03E21B34/04E21B34/06E21B41/00E21B43/2607B05D2202/00B05D2202/10B05D2254/00B05D2350/60B05D2401/10B05D2504/00C08G59/022C08G59/063C08K3/11C08K2003/2241C08K2003/2265C08K3/36C08K5/541C08K5/5415C08K5/5435C08K5/544C09D163/00E21B17/02E21B43/26
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Quick Facts
Patent No.
US 12,059,706
App. No.
18/100,124
Granted
Aug 13, 2024
Kind
B2
Abstract

Coating compositions for coating an oilfield operational component, and related methods, may include in some aspects a coating composition having a trifunctional silane, a silanol, and a filler. The coating composition may be applied to a surface of the oilfield operational component that is configured to be exposed to a fluid. The coating composition may be applied to at least partially cover or coat the surface. The coating composition may be configured to chemically bond with a cured primer composition that includes an epoxy.

Claims (43)

1. A method to prepare and apply a coating composition to at least a portion of a component to reduce damage to the component, the method comprising:

combining trifunctional silane, silanol fluid, titanium dioxide, and a filler;

mixing the trifunctional silane, the silanol fluid, the titanium dioxide, and the filler to obtain the coating composition, the trifunctional silane comprising from about 0.01 weight percent (wt. %) to about 20 wt. % of the coating composition, the silanol fluid comprising from about 40 wt. % to about 99 wt. % of the coating composition, and the filler comprising from about 0.01 wt. % to about 25 wt. % of the coating composition, one or more of the trifunctional silane, the silanol fluid, or the filler being operable to cure and form ethyl T-resin units, each of the ethyl T-resin units forming two or more bonds with one or more of other ethyl T-resin units, silanol fluid, or filler, the coating composition being operable to form a coating layer on a surface of the at least a portion of the component, and the coating layer operable to dissipate kinetic energy associated with an impact of particles on the surface of the component; and

spraying one or more layers of the coating composition onto the surface of the at least a portion of the component so as to define the coating layer when coated thereon.

2. The method of claim 1 , wherein the coating composition comprises from about 0.01 wt. % to about 15 wt. % titanium dioxide.

3. The method of claim 1 , wherein mixing comprises mixing the trifunctional silane, the silanol fluid, the titanium dioxide, and the filler to obtain a substantially homogeneous coating composition.

4. The method of claim 1 , wherein the component having the at least a portion coated with the coating layer on the surface exhibits a comparison factor indicative of an increased resistance to wear ranging from about 2 to about 30, the comparison factor being indicative of a first amount of time during which a portion of the coating layer wears to a first depth divided by a second amount of time during which the surface of the portion of the component without the coating layer wears to a second depth equal to the first depth.

5. The method of claim 1 , further comprising mixing a catalyst with the trifunctional silane, the silanol fluid, the titanium dioxide, and the filler, the catalyst comprising a tin catalyst.

6. The method of claim 1 , wherein the trifunctional silane is selected from the group consisting of an acetoxy silane, a ketoximino silane, an enoxy silane, an amine silane, an alkoxy silane, an alkenyl silane, ethyl triacetoxysilane, vinyl triacetoxysilane, methyl tris (methyl-ethyl-ketoximino) silane, vinyl tris (methyl-ethyl-ketoximino) silane, and any combination thereof.

7. The method of claim 1 , wherein the silanol fluid is selected from the group consisting of polydialkylated siloxane, polydimethylsiloxane, hydroxyl-terminated polydimethylsiloxane, and any combination thereof.

8. The method of claim 1 , wherein the filler is selected from the group consisting of fumed silica, glass fiber, mica, wollastonite, kaolin, phylosilicates, and any combination thereof.

9. The method of claim 1 , wherein the coating composition comprises an amount of ethyl T-resin units ranging from about 1.5 wt. % to about 5.0 wt. % of the coating composition.

10. The method of claim 1 , further comprising mixing a pigment having a preselected color with the trifunctional silane, the silanol fluid, the titanium dioxide, and the filler to obtain the coating composition, the coating composition comprising an amount of the pigment ranging from about 1.0 wt. % to about 5.0 wt. % of the coating composition.

11. The method of claim 1 , wherein the component comprises an oilfield component, and wherein the oilfield component comprises one or more of a fluid end of a fracking system, a goat head of a fracking system, a frac iron of a fracking system, or at least a portion of a pipeline.

12. The method of claim 1 , wherein the component comprises at least a portion of a pipeline.

13. A method to prepare and apply a coating composition to at least a portion of a component to reduce wear damage, the method comprising:

combining trifunctional silane, silanol fluid, titanium dioxide, and a filler;

mixing the trifunctional silane, the silanol fluid, the titanium dioxide, and the filler to obtain the coating composition, the trifunctional silane comprising from about 0.01 weight percent (wt. %) to about 20 wt. % of the coating composition, the silanol fluid comprising from about 40 wt. % to about 99 wt. % of the coating composition, and the filler comprising from about 0.01 wt. % to about 25 wt. % of the coating composition; and

applying one or more layers of the coating composition onto an interior surface of the at least a portion of the component so as to define a coating layer on the interior surface when coated thereon, the coating layer being operable to dissipate kinetic energy associated with an impact of particles on the interior surface.

14. The method of claim 13 , wherein mixing comprises mixing the trifunctional silane, the silanol fluid and the filler to obtain a substantially homogeneous coating composition.

15. The method of claim 13 , wherein the component having the at least a portion coated with the coating layer on the interior surface exhibits a comparison factor indicative of an increased resistance to wear ranging from about 2 to about 30, the comparison factor being indicative of a first amount of time during which a portion of the coating layer wears to a first depth divided by a second amount of time during which the interior surface of the portion of the component without the coating layer wears to a second depth equal to the first depth.

16. The method of claim 13 , wherein the component comprises a fracking system component selected from the group consisting of a goat head, a fluid end, and a frac iron.

17. The method of claim 13 , further comprising mixing a catalyst with the trifunctional silane, the silanol fluid, and the filler, the catalyst comprising a tin catalyst.

18. The method of claim 13 , wherein the trifunctional silane is selected from the group consisting of an acetoxy silane, a ketoximino silane, an enoxy silane, an amine silane, an alkoxy silane, an alkenyl silane, ethyl triacetoxysilane, vinyl triacetoxysilane, methyl tris (methyl-ethyl-ketoximino) silane, vinyl tris (methyl-ethyl-ketoximino) silane, and any combination thereof.

19. The method of claim 13 , wherein the silanol fluid is selected from the group consisting of polydialkylated siloxane, polydimethylsiloxane, hydroxyl-terminated polydimethylsiloxane, and any combination thereof and the filler is selected from the group consisting of fumed silica, glass fiber, mica, wollastonite, kaolin, phylosilicates, and any combination thereof.

20. The method of claim 13 , wherein the filler comprises fumed silica, and the method further comprises treating the fumed silica with a treatment agent prior to mixing the fumed silica with the coating composition, the treatment agent comprising at least one of hexamethylenedisilazane, divinyltetramethylenedisilazane, chlorosilane, or polydimethylsiloxane.

21. The method of claim 13 , wherein one or more of the trifunctional silane, the silanol fluid, or the filler are operable to cure and form ethyl T-resin units, each of the ethyl T-resin units forming two or more bonds with one or more of other ethyl T-resin units, silanol fluid, or filler, and wherein the coating composition comprises an amount of ethyl T-resin units ranging from about 1.5 wt. % to about 5.0 wt. % of the coating composition on the basis of non-solvent components.

22. The method of claim 13 , wherein the interior surface of the at least a portion of the component comprises a fluid passage positioned to be exposed to fluid flow during operation of the component.

23. The method of claim 13 , further comprising, prior to applying the one or more layers of the coating composition, applying a primer composition onto the interior surface of the at least a portion of the component so as to define a primer layer when coated thereon and cured.

24. The method of claim 13 , wherein the coating composition comprises from about 0.01 wt. % to about 15 wt. % titanium dioxide.

25. A method to prepare and apply a coating composition to at least a portion of a component to reduce wear damage, the method comprising:

combining trifunctional silane, silanol fluid, titanium dioxide, and a filler;

mixing the trifunctional silane, the silanol fluid, the titanium dioxide, and the filler to obtain the coating composition, the coating composition operable to form a coating layer on an interior surface of the at least a portion of the component when positioned thereon, the coating layer operable to reduce wear damage to the component and operable to dissipate kinetic energy associated with an impact of particles on the interior surface of the component when the coating is positioned thereon; and

applying one or more layers of the coating composition onto the interior surface of the at least a portion of the component so as to define the coating layer when coated thereon, the component comprising one or more of a goat head, a fluid end, a frac iron, an elbow, a valve, a pump impeller, a seal, a pipeline, a pipeline segment, or a pipeline pump.

26. The method of claim 25 , wherein the component has the at least a portion coated with the coating layer on the interior surface and exhibits a comparison factor indicative of an increased resistance to wear ranging from about 2 to about 30, the comparison factor being indicative of a first amount of time during which the interior surface of a portion of the coating layer wears to a first depth divided by a second amount of time during which the interior surface of the portion of the component without the coating layer wears to a second depth equal to the first depth.

27. The method of claim 25 , wherein one or more of the trifunctional silane, the silanol fluid, or the filler are operable to cure and form ethyl T-resin units, each of the ethyl T-resin units forming two or more bonds with one or more of other ethyl T-resin units, silanol fluid, or filler.

28. The method of claim 25 , wherein applying comprises spraying two or more layers of the coating composition onto the interior surface of the at least a portion of the component.

29. A method to prepare and apply a coating composition to at least a portion of a component to reduce wear damage, the method comprising:

applying a primer composition comprising epoxy to a surface of the at least a portion of the component so as to define a primer layer when coated thereon and cured;

combining trifunctional silane, silanol fluid, titanium dioxide, and a filler;

mixing the trifunctional silane, the silanol fluid, the titanium dioxide, and the filler to obtain the coating composition, the coating composition operable to form a coating layer on the primer layer when positioned thereon, the coating layer operable to reduce wear damage to the component and operable to dissipate kinetic energy associated with an impact of particles on the surface of the component when positioned thereon; and

spraying one or more layers of the coating composition onto the primer layer so as to define the coating layer when coated thereon so that the component has the at least a portion coated with the primer layer and the one or more coating layers on the surface and exhibits a comparison factor indicative of an increased resistance to wear ranging from about 2 to about 30, the comparison factor being indicative of a first amount of time during which the surface of a portion of the one or more coating layers wears to a first depth divided by a second amount of time during which the surface of the portion of the component without the one or more coating layers wears to a second depth equal to the first depth.

30. The method of claim 29 , wherein the surface of the at least a portion of the component comprises an interior surface positioned to be exposed to fluid flow during operation.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 23, 2023
From: ANDREWS, GREG; ANDREWS, GEORGE D.; CAPELL, JEFF
To: FORMULA NO. 37, LLC
Reel/Frame 062451/0529 →
CHANGE OF NAME Recorded Jan 23, 2023
From: FORMULA NO. 37, LLC
To: S+S INDUSTRIES LLC
Reel/Frame 062460/0852 →
CHANGE OF NAME Recorded Jan 23, 2023
From: S+S INDUSTRIES LLC
To: S+S INDUSTRIES TECHNOLOGY LLC
Reel/Frame 062460/0859 →
Continuity (18)
Continuation 17882718 · Aug 8, 2022
Continuation 17804064 · May 25, 2022
Continuation 17652707 · Feb 28, 2022
Continuation 17453753 · Nov 5, 2021
Continuation 17351388 · Jun 18, 2021
Continuation 17225684 · Apr 8, 2021
Provisional Application 63198044 · Sep 25, 2020
Provisional Application 63065565 · Aug 14, 2020
Provisional Application 63065542 · Aug 14, 2020
Provisional Application 63065545 · Aug 14, 2020
Provisional Application 63065577 · Aug 14, 2020
Provisional Application 63065591 · Aug 14, 2020
Provisional Application 63008042 · Apr 10, 2020
Provisional Application 63008046 · Apr 10, 2020
Provisional Application 63008035 · Apr 10, 2020
Provisional Application 63008049 · Apr 10, 2020
Provisional Application 63008038 · Apr 10, 2020
Related Publication 20230166290A1 · Jun 1, 2023
Cited By (1)
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