IP Library Granted Patent US 12,674,109
Granted Patent B2
US 12,674,109 · App. 18/158,522 · Granted Jul 7, 2026

High-carbon biogenic reagents and uses thereof

Inventors: Daniel J. Despen (Oakdale, MN); James A. Mennell (Brighton, UT); Steve Filips (Mound, MN)
Assignee: Carbon Technology Holdings, LLC
C10L5/447B01J21/18C01B32/312C01B32/318C10B39/00C10B39/02C10B41/00C10B43/02C10B45/00C10B47/30C10B49/02C10B53/02C10B57/02C10B57/06C10B57/10C10L5/04C10L5/36C10L5/363C10L5/365C10L5/366C10L5/442C21B5/007C21C5/52C22B4/02H01B1/04C10L2200/0204C10L2200/025C10L2200/0469C10L2290/02C10L2290/06C10L2290/08C10L2290/145C10L2290/28C10L2290/30C10L2290/50C10L2290/52C10L2290/58C10L2290/60C21B13/0066Y02E50/10Y02E50/30Y02P10/143Y02P20/129Y02P20/145Y02W10/30Y02W10/37
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Quick Facts
Patent No.
US 12,674,109
App. No.
18/158,522
Granted
Jul 7, 2026
Kind
B2
Abstract

This invention provides processes and systems for converting biomass into high-carbon biogenic reagents that are suitable for a variety of commercial applications. Some embodiments employ pyrolysis in the presence of an inert gas to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects. The structural objects may have a structure and/or strength that derive from the feedstock, heat rate, and additives.

Claims (56)

1 . A biogenic carbon electrode composition comprising, on a dry basis:

at least about 85 wt % total carbon;

at most about 5 wt % hydrogen;

at most about 1 wt % nitrogen;

at least about 1 wt % and at most about 10 wt % oxygen;

at most about 0.5 wt % phosphorus; and

an additive selected from a metal, a metal oxide, a metal hydroxide, a metal halide, or a combination thereof;

wherein the biogenic carbon electrode composition is substantially free of fossil fuel.

2 . The biogenic carbon electrode composition of claim 1 , wherein the additive is selected from magnesium, manganese, aluminum, nickel, chromium, silicon, boron, cerium, molybdenum, phosphorus, tungsten, vanadium, iron halide, iron chloride, iron bromide, magnesium oxide, dolomite, dolomitic lime, fluorite, fluorospar, bentonite, calcium oxide, lime, or a combination thereof.

3 . The biogenic carbon electrode composition of claim 1 , wherein the total carbon consists essentially of biogenic carbon.

4 . A biogenic carbon electrode composition comprising, on a dry basis:

at least about 85 wt % total carbon;

at most about 5 wt % hydrogen;

at most about 1 wt % nitrogen;

at least about 1 wt % and at most about 10 wt % oxygen;

at most about 0.5 wt % phosphorus; and

an additive selected from an acid or a salt thereof, or a base or a salt thereof;

wherein the biogenic carbon electrode composition is substantially free of fossil fuel.

5 . The biogenic carbon electrode composition of claim 4 , wherein the additive is selected from sodium hydroxide, potassium hydroxide, magnesium oxide, hydrogen bromide, hydrogen chloride, sodium silicate, potassium permanganate, or a combination thereof.

6 . The biogenic carbon electrode composition of claim 4 , wherein the total carbon consists essentially of biogenic carbon.

7 . A method of manufacturing a metal comprising:

consuming a biogenic carbon electrode composition, wherein the biogenic carbon electrode composition comprises, on a dry basis:

at least about 85 wt % total carbon;

at most about 5 wt % hydrogen;

at most about 1 wt % nitrogen;

at least about 1 wt % and at most about 10 wt % oxygen;

at most about 0.5 wt % phosphorus; and

an additive selected from a metal, a metal oxide, a metal hydroxide, a metal halide, or a combination thereof;

wherein the biogenic carbon electrode composition is substantially free of fossil fuel.

8 . The method of claim 7 , wherein the metal is aluminum.

9 . A method of manufacturing a metal comprising:

consuming a biogenic carbon electrode composition, wherein the biogenic carbon electrode composition, on a dry basis:

at least about 85 wt % total carbon;

at most about 5 wt % hydrogen;

at most about 1 wt % nitrogen;

at least about 1 wt % and at most about 10 wt % oxygen;

at most about 0.5 wt % phosphorus; and

an additive selected from an acid or a salt thereof, or a base or a salt thereof;

wherein the biogenic carbon electrode composition is substantially free of fossil fuel.

10 . The method of claim 9 , wherein the metal is aluminum.

11 . A lithium-ion battery comprising a biogenic carbon anode composition, wherein the biogenic carbon anode composition comprises, on a dry basis:

at least about 85 wt % total carbon;

at most about 5 wt % hydrogen;

at most about 1 wt % nitrogen;

at least about 1 wt % and at most about 10 wt % oxygen;

at most about 0.5 wt % phosphorus; and

an additive selected from a metal, a metal oxide, a metal hydroxide, a metal halide, or a combination thereof;

wherein the biogenic carbon electrode composition is substantially free of fossil fuel.

12 . A lithium-ion battery comprising a biogenic carbon anode composition, wherein the biogenic carbon anode composition comprises, on a dry basis:

at least about 85 wt % total carbon;

at most about 5 wt % hydrogen;

at most about 1 wt % nitrogen;

at least about 1 wt % and at most about 10 wt % oxygen;

at most about 0.5 wt % phosphorus; and

an additive selected from an acid or a salt thereof, or a base or a salt thereof;

wherein the biogenic carbon electrode composition is substantially free of fossil fuel.

Assignments (6)
SECURITY INTEREST Recorded Feb 5, 2025
From: CARBON TECHNOLOGY HOLDINGS, LLC
To: ALTER DOMUS (US) LLC
Reel/Frame 070114/0775 →
RELEASE OF SECURITY INTEREST Recorded Feb 4, 2025
From: FORTRESS CREDIT CORP.
To: CARBON TECHNOLOGY HOLDINGS, LLC
Reel/Frame 070608/0239 →
SECURITY INTEREST Recorded Feb 12, 2024
From: CARBON TECHNOLOGY HOLDINGS, LLC
To: FORTRESS CREDIT CORP.
Reel/Frame 066552/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 1, 2023
From: MENNELL, JAMES A.; DESPEN, DANIEL J.; FILIPS, STEVE
To: BIOGENIC REAGENTS, LLC
Reel/Frame 065424/0085 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 1, 2023
From: BIOGENIC REAGENTS, LLC
To: BIOGENIC REAGENTS VENTURES, LLC
Reel/Frame 065424/0218 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 1, 2023
From: BIOGENIC REAGENTS VENTURES, LLC
To: CARBON TECHNOLOGY HOLDINGS, LLC
Reel/Frame 065424/0316 →
Continuity (22)
Continuation 17390377 · Jul 30, 2021
Continuation 15654262 · Jul 19, 2017
Division 14548874 · Nov 20, 2014
Continuation 13446764 · Apr 13, 2012
Provisional Application 61475946 · Apr 15, 2011
Provisional Application 61475959 · Apr 15, 2011
Provisional Application 61475937 · Apr 15, 2011
Provisional Application 61475968 · Apr 15, 2011
Provisional Application 61475981 · Apr 15, 2011
Provisional Application 61476043 · Apr 15, 2011
Provisional Application 61475991 · Apr 15, 2011
Provisional Application 61475971 · Apr 15, 2011
Provisional Application 61475996 · Apr 15, 2011
Provisional Application 61475973 · Apr 15, 2011
Provisional Application 61475977 · Apr 15, 2011
Provisional Application 61476049 · Apr 15, 2011
Provisional Application 61475930 · Apr 15, 2011
Provisional Application 61475956 · Apr 15, 2011
Provisional Application 61475943 · Apr 15, 2011
Provisional Application 61476025 · Apr 15, 2011
Provisional Application 61475949 · Apr 15, 2011
Related Publication 20230159840A1 · May 25, 2023
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