Roofing product including bio-based asphalt mixture and methods of making the roofing product and the roofing-grade asphalt mixture
A method of forming an asphalt mixture includes mixing a polyol with a bio-source material to form a bio-asphalt. The method can further include mixing the bio-asphalt with a bitumen source different from the bio-asphalt to form an asphalt mixture. The bio-source material can include an oil, such as a vegetable oil, an animal fat, or any combination thereof. The bitumen source can include a petroleum-based asphalt. The method can further include adding a modifier, such as a fatty acid, a polycarboxylic acid, a polyacrylic acid, a polyacrylate comprising a copolymer, or any combination thereof. Moreover, a roofing grade asphalt mixture includes a bio-asphalt. The bio-asphalt includes an alkyd, wherein the alkyd is a reaction product of a polyol and a bio-source material. The roofing grade asphalt mixture further includes a bitumen source material and particles.
1. A roofing product comprising:
a base material; and
a roofing-grade asphalt mixture including:
a bio-asphalt, the bio-asphalt comprising an alkyd, the alkyd comprising a reaction product of a polyol, a bio-source material, and a modifier;
wherein the modifier includes a polycarboxylic acid comprising a phthalic acid, an isophthalic acid, a terephthalic acid, a tetrahydrophthalic acid, a naphthalene dicarboxylic acid, or any combination thereof;
a bitumen source material different from the bio-asphalt; and
particles; and
wherein the roofing grade asphalt mixture has a softening point of at least 104° C., a penetration distance of no greater than 12 dmm, and a viscosity of at least 3,000 cps at a temperature of 177° C.
2. The roofing product of claim 1 , wherein the bitumen source material has a softening point of at least 95° C. and a penetration distance no greater than 25 dmm.
3. The roofing product of claim 2 , wherein the softening point of the bitumen source material is no greater than 110° C. and the penetration distance of the bitumen source material is at least 10 dmm.
4. The roofing product of claim 1 , wherein the bitumen source material comprises a petroleum-based asphalt.
5. The roofing product of claim 1 , wherein the softening point of the roofing grade asphalt mixture is no greater than 120° C.
6. The roofing product of claim 5 , wherein the bio-source material is an oil, the oil including cooking oil, vegetable oil, an animal oil, recycled cooking oil, or any combination thereof.
7. The roofing product of claim 6 , wherein the oil includes recycled vegetable oil, recycled animal fat, any partially oxidized oil therefrom, or any combination thereof.
8. The roofing product of claim 5 , wherein the roofing-grade asphalt mixture has a total bitumen content, wherein a bio-based oxidized material is at least 5 wt % of the total bitumen content.
9. The roofing product of claim 5 , wherein the roofing-grade asphalt mixture has a bitumen content no greater than 50 wt %.
10. The roofing product of claim 5 , wherein at 177° C., the roofing-grade asphalt mixture has a viscosity of at least 3500 cps.
11. The roofing product of claim 10 , wherein at 177° C., the roofing-grade asphalt mixture has a viscosity no greater than 4500 cps.
12. The roofing product of claim 5 , wherein the particles includes limestone, talc, clay, coal fines, gypsum, calcite, fly ash, or any combination thereof.
13. The roofing product of claim 5 , wherein the base material comprises a fiberglass mat, a cellulose-based material, or a polymer.
14. The roofing product of claim 5 , wherein the roofing-grade asphalt mixture further comprises a plasticizer.
15. The roofing product of claim 5 , wherein the roofing product is in a form of a roofing shingle or a membrane-type roofing product.