IP Library › Granted Patent US 8,444,759
Granted Patent B2
US 8,444,759 · App. 13/178,725 · Granted May 21, 2013

Bio-based adhesive material

Inventors: Ben Wen (Horseheads, NY); Jessica P. Zhang (Horseheads, NY)
Assignee: United Environment & Energy LLC
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Quick Facts
Patent No.
US 8,444,759
App. No.
13/178,725
Granted
May 21, 2013
Kind
B2
Abstract

A bio-based adhesive and method of making the adhesive replaces or serves as additives for asphalt, sealant, and polymers such as styrene-butadiene-styrene and atactic polypropylene in the manufacture of building or paving materials. The method includes steps of forming a mixture of oil comprising fatty acids group and optionally a powdered material; maintaining the oil-to-powdered-material weight ratio in the mixture between 1 to 0.00001 and 1 to 20; heating the mixture to a reaction temperature greater than 55 degrees Centigrade; maintaining the reaction temperature until the oil is polymerized; and, injecting air into the mixture while polymerizing the oil. The adhesive of this method comprises a renewable polymer and the powdered material.

Claims (34)

1. A method of making an adhesive material to replace asphalt in manufacturing roof shingles or pavement, the method comprising the steps of:

forming a mixture by combining:

oil comprising fatty acids; and

a powdered material operable to catalyze polymerization of the oil;

maintaining the oil-to-powdered-material weight ratio in the mixture between 1 to 0.01 and 1 to 4.9;

polymerizing the oil and creating the adhesive by:

heating the mixture to a reaction temperature greater than 100 degrees Centigrade; and

maintaining the reaction temperature until the oil is polymerized; and

injecting air into the mixture while polymerizing the oil.

2. A method of making a bio-based adhesive for a coating or to replace or serve as an additive for asphalt, sealant, or polymers in manufacturing building or paving materials, the method comprising the steps of:

forming a mixture by combining:

oil comprising fatty acids; and

a powdered material operable to catalyze polymerization of the oil;

maintaining the oil-to-powdered-material weight ratio in the mixture between 1 to 0.00001 and 1 to 20;

polymerizing the oil and creating the adhesive by:

heating the mixture to a reaction temperature greater than 55 degrees Centigrade; and

maintaining the reaction temperature until the oil is polymerized; and

injecting air into the mixture while polymerizing the oil.

3. The method of claim 2 , further comprising the steps of:

obtaining waste cooking oil; and

using the waste cooking oil as the oil in the mixture.

4. The method of claim 2 , further comprising the step of selecting the powdered material from the group consisting of fly ash, sand, cement, limestone, clay, talc, mica, alumina oxide, dolomite, gypsum, wood flour, starch, and mixtures thereof.

5. The method of claim 2 , further comprising the step of adding a catalyst to the mixture, the catalyst selected from the group consisting of cobalt, and an iron organic compound.

6. The method of claim 2 , further comprising the step of obtaining the oil from a source selected from the group consisting of a plant, an alga, an animal fat, trap grease, a process of converting wood into wood pulp, and a process of destructive distillation from dried biomass.

7. The method of claim 2 , wherein the reaction temperature is within a range of between about 130 degrees Centigrade and about 250 degrees Centigrade.

8. The method of claim 2 , further comprising the step of maintaining the oil-to-powdered-material weight ratio between 1 to 0.01 and 1 to 4.9.

9. The method of claim 2 , further comprising the steps of:

uniformly distributing the air in the mixture; and

maintaining an air to oil ratio in the mixture within a range of 0.01 to 2.0 liters of air per minute per gram of oil.

10. The method of claim 2 , further comprising the step of stirring the mixture while polymerizing the oil.

11. The method of claim 2 , wherein the step of injecting air into the mixture is performed by bubbling air into the mixture.

12. The method of claim 2 , wherein the step of injecting air into the mixture is performed by rotating the mixture in a rotary drum.

13. The method of claim 2 , further comprising the step of blending the bio-based adhesive with asphalt, a sealant, or a polymer.

14. The method of claim 13 , wherein the polymer is selected from the group consisting of styrene-butadiene-styrene, and atactic polypropylene.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 13, 2016
From: UNITED ENVIRONMENT & ENERGY LLC
To: KEW TECHNOLOGIES INC
Reel/Frame 037731/0149 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 8, 2011
From: WEN, BEN, DR.; ZHANG, JESSICA P., DR.
To: UNITED ENVIRONMENT & ENERGY LLC
Reel/Frame 026562/0139 →
Continuity (4)
Continuation In Part 13031480 · Feb 21, 2011
Continuation PCTUS2011022813 · Jan 28, 2011
Continuation In Part 12754236 · Apr 5, 2010
Related Publication 20110259239A1 · Oct 27, 2011