Cathode active material for lithium secondary battery and lithium secondary battery including the same
The cathode active material for a lithium secondary battery according to embodiments of the present invention includes a lithium-transition metal composite oxide particle including a plurality of primary particles, and the lithium-transition metal composite oxide particle includes a lithium-sulfur-containing portion formed between the primary particles. Thereby, it is possible to improve life-span properties and capacity properties by preventing the layer structure deformation of the primary particles and removing residual lithium.
1. A cathode active material for a lithium secondary battery comprising:
a lithium-transition metal composite oxide particle including a plurality of primary particles,
wherein the lithium-transition metal composite oxide particle comprises a lithium-sulfur-containing portion formed between the primary particles, and
wherein a sulfur content in the lithium-transition metal composite oxide particle measured through a carbon-sulfur (CS) analyzer is 2,000 to 7,000 ppm based on a total weight of the lithium-transition metal composite oxide particle.
2. The cathode active material for a lithium secondary battery according to claim 1 , wherein the lithium-sulfur-containing portion has a monoclinic crystal structure.
3. The cathode active material for a lithium secondary battery according to claim 1 , wherein an average sulfur signal value of the lithium-sulfur-containing portion measured through energy dispersive spectroscopy (EDS) is greater than the average sulfur signal value in the primary particles measured through the EDS.
4. The cathode active material for a lithium secondary battery according to claim 3 , wherein the average sulfur signal value of the lithium-sulfur-containing portion measured through the EDS is 1.2 to 3.8 times greater than the average sulfur signal value in the primary particles measured through the EDS.
5. The cathode active material for a lithium secondary battery according to claim 1 , wherein the lithium-sulfur-containing portion is derived from a sulfonyl-based compound represented by Structural Formula 1 below:
(In Structural Formula 1, n is 0≤n<3, R 1 and R 2 are O − , NH 2 , NH 3 + , OH, or a hydrocarbon group having 1 to 3 carbon atoms that can be substituted with a substituent, and the substituent includes a halogen, cyano group, hydroxyl group, phosphoric acid group, carboxyl group or a salt thereof).
6. The cathode active material for a lithium secondary battery according to claim 5 , wherein the hydrocarbon group included in R 1 and R 2 in Structural Formula 1 is substituted with or connected to at least one selected from the group consisting of a carbon-carbon double bond, —O—, —S—, —CO—, —OCO—, —SO—, —CO—O—, —OCO—O—, —S—CO—, —S—CO—O—, —CO—NH—, —NH—CO—O—, —NR′—,
—S—S— and —SO 2 —, and R′ is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms.
7. The cathode active material for a lithium secondary battery according to claim 5 , wherein the sulfonyl-based compound includes at least one of compounds of Formulae 1 to 3 below:
8. The cathode active material for a lithium secondary battery according to claim 1 , wherein the primary particles have a hexagonal close-packed structure.
9. The cathode active material for a lithium secondary battery according to claim 1 , wherein a content of lithium carbonate (Li 2 CO 3 ) remaining on the surface of the lithium-transition metal composite oxide particle is 2,500 ppm or less based on the total weight of the lithium-transition metal composite oxide particle, and
a content of lithium hydroxide (LiOH) remaining on the surface of the lithium-transition metal composite oxide particle is 2,000 ppm or less based on the total weight of the lithium-transition metal composite oxide particle.
10. A lithium secondary battery comprising:
a cathode comprising a cathode active material layer including the cathode active material for a lithium secondary battery according to claim 1 ; and
an anode disposed to face the cathode.