Light-driven synthesis of plasmonic nanoparticles and nanomaterials
View Patent ↗In one aspect, the present disclosure pertains to methods of making various noble metal nanoprisms, e.g., gold nanoprisms. In various aspects, the methods can comprise incubating, under dark conditions, a growth solution comprising: (a) a plurality of gold seed structures; (b) a gold precursor, and (c) a photocatalytic intermediary, such that during the incubating step multiply-twinned gold seed structures in the growth solution are preferentially enlarged. The disclosed methods can comprise separating the multiply-twinned gold seed structures from the growth solution based upon the size of the gold seed structures to produce an enriched growth solution. In some aspects, the methods comprise irradiating the enriched growth solution to produce the gold nanoprisms. In some aspects, the disclosed nanoprisms comprise silver.
1. A method of making noble metal nanoprisms, the method comprising:
incubating a solution comprising a plurality of seed structures, a noble metal precursor, and a photocatalytic intermediary, wherein the plurality of seed structures are planar-twinned structures and penta-twinned structures, wherein during the incubating step the penta-twinned structures are preferentially enlarged as compared to the planar-twinned structures, and
separating the penta-twinned structures from the solution based upon the size of the penta-twinned structures to produce an enriched growth solution;
irradiating the enriched growth solution to produce the noble metal nanoprisms having an average thickness of about 10 nm to 30 nm, wherein the photocatalytic intermediary is positively charged.
2. The method of claim 1 , wherein the nanoprism does not comprise silver.
3. The method of claim 1 , wherein the noble metal is selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, gold, rhenium, and a combination thereof.
4. The method of claim 1 , wherein the noble metal precursor comprises a salt of the noble metal.
5. The method of claim 1 , wherein the incubating step is performed at an elevated temperature from about 30° C. to about 40° C.
6. The method of claim 1 , wherein the photocatalytic intermediary comprises a γ-lactam ring.
7. The method of claim 1 , wherein the photocatalytic intermediary comprises n-methyl-2-pyrrolidone.
8. The method of claim 1 , wherein the photocatalytic intermediary comprises polyvinylpyrrolidone.
9. The method of claim 1 , wherein the enriched growth solution further comprises sodium iodide.
10. The method of claim 1 , wherein the nanoprisms have a geometry selected from the group consisting of hexagonal nanoprisms and triangular nanoprisms.
11. The method of claim 1 , wherein upon introduced to the incubation step the seed structures have an average size of about 5 nm to 15 nm.
12. The method of claim 1 , wherein the irradiating step comprises irradiating with light having a wavelength from about 500 nm to 600 nm, and
wherein the nanoprisms have an average edge length of about 400 nm to 600 nm.
13. The method of claim 1 , wherein the irradiating step comprises irradiating with light having a wavelength from about 600 nm to 700 nm, and
wherein the nanoprisms have an average edge length of about 200 nm to 400 nm.
14. The method of claim 1 , wherein the nanoprisms are produced with a yield, by shape, of 80% to 95%.
15. A method of making noble metal nanoprisms, the method comprising:
incubating a solution comprising a plurality of seed structures, a noble metal precursor, and a photocatalytic intermediary, wherein the plurality of seed structures comprise planar-twinned structures and multiply-twinned structures, wherein during the incubating step the multiply-twinned structures are preferentially enlarged as compared to the planar-twinned structures,
separating the multiply-twinned structures from the solution based upon the size of the multiply-twinned structures to produce an enriched growth solution; and
irradiating the enriched growth solution to produce the noble metal nanoprisms having an average thickness of about 10 nm to 30 nm, wherein the photocatalytic intermediary is positively charged.
16. The method of claim 15 , wherein the nanoprism does not comprise silver.
17. The method of claim 15 , wherein the noble metal is selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, gold, rhenium, and a combination thereof.
18. The method of claim 15 , wherein the nanoprisms have a geometry selected from the group consisting of hexagonal nanoprisms and triangular nanoprisms.
19. The method of claim 15 , wherein upon introduced to the incubation step and seed structures have an average size of about 5 nm to 15 nm.
20. The method of claim 15 , wherein the irradiating step comprises irradiating with light having a wavelength from about 500 nm to 600 nm.