IP Library Granted Patent US 12,656,680
Granted Patent B2
US 12,656,680 · App. 18/226,481 · Granted Jun 16, 2026

Metallization method

Inventors: Mitsuru Haga (Niigata, JP); Cong Liu (Shrewsbury, MA); James F. Cameron (Brookline, MA)
Assignees: DUPONT ELECTRONIC MATERIALS INTERNATIONAL, LLC; ROHM AND HAAS ELECTRONIC MATERIALS KK
G03F7/0045C08F212/24G03F7/038G03F7/039H10W72/01235H10W72/01255
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Quick Facts
Patent No.
US 12,656,680
App. No.
18/226,481
Granted
Jun 16, 2026
Kind
B2
Abstract

Disclosed herein is a metallization method, comprising (a) providing a photoresist layer on a first surface of a substrate, wherein the photoresist layer is formed from a photoresist composition comprising: a polymer comprising acid-labile groups; a photoacid generator; an organic phosphonic acid; and a solvent; (b) pattern-wise exposing the photoresist layer to activating radiation; (c) developing the exposed photoresist layer with a basic developer to form a photoresist pattern; and (d) after forming the photoresist pattern, plating a metal on the first surface of the substrate using the photoresist pattern as a plating mask.

Claims (16)

1 . A metallization method, comprising:

(a) providing a photoresist layer on a first surface of a substrate, wherein the photoresist layer is formed from a photoresist composition comprising: a polymer comprising acid-labile groups; a photoacid generator; an organic phosphonic acid; a solvent; and a basic compound;

(b) pattern-wise exposing the photoresist layer to activating radiation;

(c) developing the exposed photoresist layer with a basic developer to form a photoresist pattern; and

(d) after forming the photoresist pattern, plating a metal on the first surface of the substrate using the photoresist pattern as a plating mask, wherein the organic phosphonic acid is selected from the group consisting of butyl phosphonic acid, pentyl phosphonic acid, hexyl phosphonic acid, octyl phosphonic acid, n-decyl phosphonic acid, n-dodecylphosphonic acid, n-hexadecylphosphonic acid, n-hexylphosphonic acid, n-octadecylphosphonic acid, n-octylphosphonic acid, n-tetradecylphosphonic acid, phenyl phosphonic acid, benzylphosphonic acid, (4-aminobenzyl) phosphonic acid (4-aminophenyl) phosphonic acid, (4-hydroxyphenyl) phosphonic acid, benzhydryl phosphonic acid, (2-phenylethyl) phosphonic acid, 4-methoxyphenyl phosphonic acid, (pyridin-3-ylmethyl) phosphonic acid, or a combination thereof, and

wherein the basic compound is selected from the group consisting of 2,8-dimethyl-6H,12H-5,11-methanodibenzo [b,f][1,5]diazocine (Troger's Base), ethyl-3-(morpholino) propionate, 4-(p-tolyl) morpholine, or a combination thereof.

2 . The metallization method of claim 1 , wherein the photoresist pattern has an undercut profile.

3 . The metallization method of claim 1 , further comprising (e) removing the photoresist pattern after plating the metal.

4 . The metallization method of claim 1 , wherein the photoresist layer is disposed directly on a metal layer.

5 . The metallization method of claim 1 , wherein the photoresist layer has a thickness of greater than 2 microns.

6 . The metallization method of claim 1 , wherein the organic phosphonic acid is a phenyl phosphonic acid.

7 . The metallization method of claim 1 , wherein the organic phosphonic acid is present in the photoresist layer in an amount of 0.01 to 0.50 parts by weight per 100 parts of the polymer that comprises acid-labile groups.

8 . The metallization method of claim 1 , wherein the acid-labile groups are chosen from tertiary ester groups, acetal groups, or a combination thereof.

9 . The metallization method of claim 1 , wherein the polymer further comprises a repeat unit formed from a vinyl aromatic monomer.

10 . The metallization method of claim 1 , wherein the photoresist composition further comprises a basic compound having a pKa of less than 7.

11 . The metallization method of claim 10 , wherein the basic compound is selected from tertiary amine compounds.

Assignments (5)
SECURITY INTEREST Recorded Nov 3, 2025
From: QNITY ELECTRONICS, INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 073515/0243 →
SECURITY INTEREST Recorded Nov 3, 2025
From: QNITY ELECTRONICS, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 073517/0298 →
CHANGE OF NAME Recorded Oct 29, 2024
From: ROHM & HAAS ELECTRONIC MATERIALS LLC
To: DUPONT ELECTRONIC MATERIALS INTERNATIONAL, LLC
Reel/Frame 069272/0383 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 1, 2023
From: LIU, CONG; CAMERON, JAMES F.
To: ROHM AND HAAS ELECTRONIC MATERIALS LLC
Reel/Frame 064451/0131 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 31, 2023
From: HAGA, MITSURU
To: ROHM AND HAAS ELECTRONIC MATERIALS KK
Reel/Frame 064436/0412 →
Continuity (2)
Provisional Application 63392275 · Jul 26, 2022
Related Publication 20240055382A1 · Feb 15, 2024
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