IP Library › Granted Patent US 12,539,649
Granted Patent B2
US 12,539,649 · App. 18/238,608 · Granted Feb 3, 2026

System and method for using a VOC free low radiant flux LED UV curable composition

Inventor: Matthew Kent Springer (Elbert, CO)
Assignee: MSI Coatings, Inc.
B29C35/0805B29C37/0067B29C70/06B29C73/02B32B3/12B32B7/12B32B15/10B32B15/20B32B21/042B32B21/06B32B21/14C08J3/24C08J3/28C08J5/04C09D5/18C09D133/08B05D3/067B05D5/00B29C2035/0827B29C37/02B29K2105/06B29K2309/08B29L2031/3097B32B2250/02B32B2255/08B32B2255/26B32B2262/101B32B2262/106B32B2307/3065B32B2603/00B32B2605/08B32B2605/12B32B2605/18
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Quick Facts
Patent No.
US 12,539,649
App. No.
18/238,608
Granted
Feb 3, 2026
Kind
B2
Abstract

The present invention generally relates to a system and method for using a volatile organic compound (VOC) free low radiant flux LED UV curable composition, and more particularly to unique and novel uses of the composition such as one or two or more of a fire retardant, clear coat, composite material, resin, top coat, improved holdout coating, a sealant coat, and combinations of the same.

Claims (49)

1 . A method of repairing at least a portion of a damaged pipe, comprising:

preparing at least a portion of the damaged pipe for repair;

arranging a composite material that is substantially saturated with a VOC free low radiant flux UV curable composition on at least a portion of the damaged pipe;

applying an energy source having a wavelength in a range from 360 nm to 420 nm and a radiant flux at a surface of the substantially saturated composite material of 100 mW/cm 2 or less to cure at least a portion of the substantially saturated composite material,

wherein the VOC free low radiant flux UV curable composition comprises:

an acrylate monomers/oligomers;

a thiol monomers/oligomers;

a photo initiator; and

a radical inhibitor.

2 . The method of claim 1 , wherein the wavelength is 390 nm.

3 . The method of claim 1 , wherein the radiant flux at the surface of the substantially saturated composite material is 50 mW/cm 2 or less.

4 . The method of claim 1 , wherein the radiant flux at the surface of the substantially saturated composite material is 25 mW/cm 2 or less.

5 . The method of claim 1 , wherein the radiant flux at the surface of the substantially saturated composite material is 10 mW/cm 2 or less.

6 . The method of claim 1 , wherein the radiant flux at the surface of the substantially saturated composite material is 5 mW/cm 2 or less.

7 . The method of claim 1 , wherein the radiant flux at the surface of the substantially saturated composite material is provided in a roll.

8 . The method of claim 1 , wherein the substantially saturated composite material is provided as a patch having one or more layers.

9 . The method of claim 1 , wherein the substantially saturated composite material is provided as a pre-impregnated composite material.

10 . The method of claim 9 , wherein the pre-impregnated composite material comprises one or more layers of a composite material.

11 . The method of claim 10 , wherein the composite material comprises one or more of a fiberglass material, cellulose fiber material, carbon fiber material, polymer fiber material, metallic fiber material, silicon carbide fiber material, and mineral fiber material.

12 . The method of claim 10 , wherein the composite material comprises a fiberglass material.

13 . The method of claim 10 , wherein the arranging of the composite material that is substantially saturated with a VOC free low radiant flux UV curable composition on at

least a portion of the damaged pipe is arranged on an interior or exterior surface of the damaged pipe.

14 . The method of claim 1 , wherein the VOC free low radiant flux UV curable composition comprises at least ninety-five (95%) percent solids.

15 . The method of claim 1 , wherein the VOC free low radiant flux UV curable composition comprises at least ninety-six (96%) percent solids.

16 . The method of claim 1 , wherein the VOC free low radiant flux UV curable composition comprises at least ninety-seven (97%) percent solids.

17 . The method of claim 1 , wherein the VOC free low radiant flux UV curable composition comprises at least ninety-eight (98%) percent solids.

18 . A method of repairing at least a portion of a damaged pipe, comprising:

preparing a portion of the pipe for repair;

applying a VOC free low radiant flux UV curable composition to a composite material to substantially saturate the composite material, wherein the composite material has internal surface, an external surface, a first end, a second end separated from the first end, and a lumen that extends from the first end to the second end;

arranging an inflatable member in the lumen of the saturated composite material;

inflating a portion of the inflatable member to expand the statured composite material to be at least substantially adjacent to an interior surface of the pipe;

applying an energy source having a wavelength in a range from 360 nm to 420 nm and a radiant flux at a surface of the saturated composite material of 100 mW/cm 2 or less to at least partially cure the saturated composite material;

wherein the VOC free low radiant flux UV curable composition comprises:

an acrylate monomers/oligomers;

a thiol monomers/oligomers;

a photo initiator; and

a radical inhibitor.

19 . The method of claim 18 , wherein the composite material comprises one or more of a fiberglass material, cellulose fiber material, carbon fiber material, polymer fiber material, metallic fiber material, silicon carbide fiber material, and mineral fiber material.

20 . A method of repairing at least a portion of a damaged pipe, comprising:

preparing a portion of the pipe for repair;

applying a VOC free low radiant flux UV curable composition to a composite material to substantially saturate the composite material, wherein the composite material has internal surface, an external surface, a first end, a second end separated from the first end, and a lumen that extends from the first end to the second end;

arranging a portion of the statured composite material to be at least substantially adjacent to an interior surface of the pipe;

applying an energy source having a wavelength in a range from 360 nm to about 420 nm and a radiant flux at a surface of the saturated composite material of 100 mW/cm 2 or less to at least partially cure the saturated composite material,

wherein the VOC free low radiant flux UV curable composition comprises:

an acrylate monomers/oligomers;

a thiol monomers/oligomers;

a photo initiator; and

a radical inhibitor.

21 . The method of claim 20 , wherein the composite material comprises one or more of a fiberglass material, cellulose fiber material, carbon fiber material, polymer fiber material, metallic fiber material, silicon carbide fiber material, and mineral fiber material.

Continuity (8)
Continuation 16425400 · May 29, 2019
Continuation 15593985 · May 12, 2017
Provisional Application 62452093 · Jan 30, 2017
Provisional Application 62430125 · Dec 5, 2016
Provisional Application 62413199 · Oct 26, 2016
Provisional Application 62382968 · Sep 2, 2016
Provisional Application 62335823 · May 13, 2016
Related Publication 20230405883A1 · Dec 21, 2023
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BYK Additives & Instruments, “Food Contact BYK Regulatory Status Information Product: BYK®-1794”, Version 1.0, Sep. 5, 2017, 3 pages. [cited by applicant]
BYK Additives & Instruments, “Safety Data Sheet BYK-333”, Version 6, Mar. 8, 2017, 12 pages. [cited by applicant]
BYK Additives & Instruments, “Material Safety Data Sheet BYK-361 N”, Version 4, May 11, 2015, 9 pages. [cited by applicant]
BYK Additives & Instruments, “Material Safety Data Sheet BYK-1790”, Version 3, May 14, 2015, 9 pages. [cited by applicant]
BYK Additives & Instruments, “Material Safety Data Sheet BYK-1794”, Version 4, May 14, 2015, 10 pages. [cited by applicant]
BYK Additives & Instruments, “Safety Data Sheet BYK-UV 3575”, Version 5, Jan. 26, 2016, 12 pages. [cited by applicant]
BYK Additives & Instruments, “Material Safety Data Sheet BYK-UV 3576”, Version 5, May 11, 2015, 12 pages. [cited by applicant]
BYK Additives & Instruments, “BYK-333”, Data Sheet Issue Nov. 2012, 4 pages. [cited by applicant]
BYK Additives & Instruments, “BYK-361 N”, Data Sheet Issue Dec. 2012, 4 pages. [cited by applicant]
BYK Additives & Instruments, “BYK-1790”, Data Sheet Issue Apr. 2013, 2 pages. [cited by applicant]
BYK Additives & Instruments, “BYK-1794”, Data Sheet Issue Apr. 2016, 4 pages. [cited by applicant]
BYK Additives & Instruments, “BYK-UV 3575”, Data Sheet Issue Jan. 2013, 2 pages. [cited by applicant]
BYK Additives & Instruments, “BYK-UV 3576”, Data Sheet Issue Jan. 2013, 2 pages. [cited by applicant]
Evonik Industries, “ACEMATT® Matting Agents the optimum matting effect for your coating system”, 2 pages, ACEMATT Handling sheet, 2016. [cited by applicant]
ACEMATT®, “ACEMATT® 3600”, Product Information ACEMATT® 3600, 2 pages, Oct. 2017. [cited by applicant]
Evonik Industries, “ACEMATT® Matting agents for the coating industry Technical Overview”, 32 pages, May 2016. [cited by applicant]