Multilayer sintered ceramic body and method of making
Disclosed is a multilayer sintered ceramic body comprising at least one first layer comprising at least one crystalline phase of YAG, wherein the at least one first layer has at least one surface; and at least one second layer comprising alumina and at least one of stabilized zirconia and partially stabilized zirconia, wherein the at least one surface of the at least one first layer comprises pores wherein the pores have a maximum size of from 0.1 to 5 um as measured by SEM, and wherein each of the at least one first layer and the at least one second layer has a coefficient of thermal expansion (CTE), wherein the CTE of the at least one first layer and the CTE of the at least one second layer differ from 0 to 0.6×10 −6 /° C. as measured in accordance with ASTM E228-17. Methods of making are also disclosed.
1 . A multilayer sintered ceramic body comprising:
at least one first layer comprising at least one crystalline phase of YAG, wherein the at least one first layer has at least one surface; and
at least one second layer comprising alumina and at least one of stabilized zirconia and partially stabilized zirconia,
wherein the at least one surface of the at least one first layer comprises pores wherein the pores have a maximum size of from 0.1 to 5 μm as measured by SEM, and wherein each of the at least one first layer and the at least one second layer has a coefficient of thermal expansion (CTE), wherein the CTE of the at least one first layer and the CTE of the at least one second layer differ from 0 to 0.6×10 −6 /° C. as measured in accordance with ASTM E228-17.
2 . The multilayer sintered ceramic body of claim 1 wherein the pores have a maximum size of 0.1 to 2 μm as measured by SEM.
3 . The multilayer sintered ceramic body as in claim 1 wherein the pores have a cumulative pore distribution of from about 2 to about 600 μm 2 /mm 2 as measured using SEM and image processing methods.
4 . The multilayer sintered ceramic body as in claim 1 wherein the at least one surface has a porosity by percentage of a total area of the at least one surface of from 0.0005 to 1% as measured by SEM.
5 . The multilayer sintered ceramic body as in claim 1 wherein the relative density of the at least one first layer and the relative density of the at least one second layer is from 99 to 100%.
6 . The multilayer sintered ceramic body as in claim 1 wherein the at least one first layer has a total impurity content of less than 25 ppm relative to the mass of the at least one first layer as measured by ICPMS.
7 . The multilayer sintered ceramic body as in claim 1 wherein the at least one first layer has an Sa of from 0.0005 to 1 μm as measured according to ISO standard 25 178-2-2012.
8 . The multilayer sintered ceramic body as in claim 1 wherein the at least one first layer has an Sz from 0.3 to 3 μm as measured according to ISO standard 25 178-2-2012.
9 . The multilayer sintered ceramic body as in claim 1 wherein the at least one first layer and the at least one second layer are contiguous.
10 . The multilayer sintered ceramic body as in claim 1 having an interface defined by the at least one first and second layers wherein the interface has an average interface line and a distance from the interface to the average interface line varies in amount from 10 to 100 μm as measured by SEM.
11 . The multilayer sintered ceramic body as in claim 1 wherein the at least one first layer has a thickness d 1 , and the at least one second layer has a thickness d 2 , wherein the thickness of the at least one second layer is from 80% to 98% of the combined thicknesses of the at least one first and second layers.
12 . A method of making a multilayer sintered ceramic body, the method comprising the steps of:
a. combining yttria and alumina powders to make a first powder mixture;
b. combining alumina and zirconia powders to make a second powder mixture, wherein the zirconia is selected from the group consisting of partially stabilized zirconia and stabilized zirconia;
c. calcining the first and second powder mixtures by applying heat to raise the temperature of the powder mixtures to a calcination temperature and maintaining the calcination temperature to perform calcination to form first and second calcined powder mixtures;
d. separately disposing the first and second calcined powder mixtures inside a volume defined by a tool set of a sintering apparatus to form at least one layer of the first calcined powder mixture and at least one layer of the second calcined powder mixture and creating vacuum conditions inside the volume;
e. applying pressure to the layers of the first and second calcined powder mixtures while heating to a sintering temperature and performing sintering to form the multilayer sintered ceramic body, wherein the at least one layer of the first calcined powder mixture upon sintering forms at least one first layer and the at least one layer of the second calcined powder mixture forms at least one second layer; and
f. lowering the temperature of the multilayer sintered ceramic body,
wherein the at least one first layer comprising at least one crystalline phase of YAG, wherein the at least one first layer has at least one surface; and at least one second layer comprising alumina and at least one of stabilized zirconia and partially stabilized zirconia,
wherein the at least one surface of the at least one first layer comprises pores wherein the pores have a maximum size from 0.1 to 5 μm as measured using SEM and image processing methods, and wherein each of the at least one first layer and the at least one second layer has a coefficient of thermal expansion (CTE), wherein the CTE of the at least one first layer and the CTE of the at least one second layer differ from 0 to 0.6×10 −6 /° C. as measured in accordance with ASTM E228-17.
13 . The method according to claim 12 , further comprising the steps of:
g. optionally annealing the multilayer sintered ceramic body by applying heat to raise the temperature of the multilayer sintered ceramic body to reach an annealing temperature, performing annealing; and
h. lowering the temperature of the annealed multilayer sintered ceramic body.
14 . The method according to claim 12 further comprising the step of:
i. machining the multilayer sintered ceramic body to create a multilayer sintered ceramic component in the shape of a dielectric window, an RF window, a focus ring, a process ring, a deposition ring, a nozzle or a gas injector, a shower head, a gas distribution plate, an etch chamber liner, a plasma source adapter, a gas inlet adapter, a diffuser, an electrostatic wafer chuck (ESC), a chuck, a puck, an ion suppressor element, a faceplate, an isolator, a spacer, and/or a protective ring in plasma processing chambers.
15 . A multilayer sintered ceramic body made by the process of claim 12 .